Michael Fickert , Rebeca Martinez-Haya , Diego López-Alcalá , Frank Hauke , José J. Baldoví , Andreas Hirsch , Gonzalo Abellán
{"title":"Fluorination of antimonene hexagons†","authors":"Michael Fickert , Rebeca Martinez-Haya , Diego López-Alcalá , Frank Hauke , José J. Baldoví , Andreas Hirsch , Gonzalo Abellán","doi":"10.1039/d4cc03423f","DOIUrl":null,"url":null,"abstract":"<div><div>Fluorination of two-dimensional (2D) antimonene hexagons synthesized through a colloidal bottom-up approach has been explored using microwave-induced plasma and reactive ion etching fluorination strategies through the generation of CF<sub>4</sub>. The stability of the fluorine bond has been corroborated through DFT calculations. This work paves the way for further halogen-derivative modifications of heavy 2D pnictogens.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 91","pages":"Pages 13336-13339"},"PeriodicalIF":4.3000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11446181/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524022213","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Fluorination of two-dimensional (2D) antimonene hexagons synthesized through a colloidal bottom-up approach has been explored using microwave-induced plasma and reactive ion etching fluorination strategies through the generation of CF4. The stability of the fluorine bond has been corroborated through DFT calculations. This work paves the way for further halogen-derivative modifications of heavy 2D pnictogens.
期刊介绍:
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