Metal–phenolic network composites: from fundamentals to applications

IF 40.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical Society Reviews Pub Date : 2024-10-04 DOI:10.1039/D3CS00273J
Zhixing Lin, Hai Liu, Joseph J. Richardson, Wanjun Xu, Jingqu Chen, Jiajing Zhou and Frank Caruso
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Abstract

Composites with tailored compositions and functions have attracted widespread scientific and industrial interest. Metal–phenolic networks (MPNs), which are composed of phenolic ligands and metal ions, are amorphous adhesive coordination polymers that have been combined with various functional components to create composites with potential in chemistry, biology, and materials science. This review aims to provide a comprehensive summary of both fundamental knowledge and advancements in the field of MPN composites. The advantages of amorphous MPNs, over crystalline metal–organic frameworks, for fabricating composites are highlighted, including their mild synthesis, diverse interactions, and numerous intrinsic functionalities. The formation mechanisms and state-of-the-art synthesis strategies of MPN composites are summarized to guide their rational design. Subsequently, a detailed overview of the chemical interactions and structure–property relationships of composites based on different functional components (e.g., small molecules, polymers, biomacromolecules) is provided. Finally, perspectives are offered on the current challenges and future directions of MPN composites. This tutorial review is expected to serve as a fundamental guide for researchers in the field of metal–organic materials and to provide insights and avenues to enhance the performance of existing functional materials in applications across diverse fields.

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金属酚醛网络复合材料:从基础到应用。
具有定制成分和功能的复合材料引起了科学界和工业界的广泛兴趣。金属酚醛网络(MPNs)由酚配体和金属离子组成,是一种无定形的粘合配位聚合物,它与各种功能成分相结合,可制成具有化学、生物和材料科学潜力的复合材料。本综述旨在全面总结 MPN 复合材料领域的基础知识和研究进展。与晶体金属有机框架相比,非晶态多孔网络在制造复合材料方面的优势尤为突出,包括其温和的合成、多样化的相互作用以及众多的内在功能。总结了 MPN 复合材料的形成机理和最先进的合成策略,以指导其合理设计。随后,详细概述了基于不同功能成分(如小分子、聚合物、生物大分子)的复合材料的化学相互作用和结构-性能关系。最后,对 MPN 复合材料当前面临的挑战和未来发展方向进行了展望。这篇教程综述有望成为金属有机材料领域研究人员的基础指南,并为提高现有功能材料在不同领域的应用性能提供见解和途径。
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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
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