Sijia Liu, Chao Hu, Liujuan Yang, Huimin Ji, Fengyang Peng, Jiawei Zou, Qi Zhang, Yougen Tang, Haiyan Wang and Yixin Li
{"title":"A Si3N4-modified cellulose/glass fiber hybrid separator inhibiting zinc dendrites and cathode dissolution for aqueous zinc-ion batteries†","authors":"Sijia Liu, Chao Hu, Liujuan Yang, Huimin Ji, Fengyang Peng, Jiawei Zou, Qi Zhang, Yougen Tang, Haiyan Wang and Yixin Li","doi":"10.1039/D5CC02491A","DOIUrl":null,"url":null,"abstract":"<p >A sandwich-structured separator with Si<small><sub>3</sub></small>N<small><sub>4</sub></small>-modified cellulose nanofiber layers on glass fiber is designed. The modified separator inhibits zinc dendrites through the zincophilicity of Si<small><sub>3</sub></small>N<small><sub>4</sub></small> and cathode dissolution through weak interactions with VO<small><sub>2</sub></small><small><sup>+</sup></small>. Benefiting from this dual-functional design, the full cells exhibit excellent electrochemical performance at low current densities.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" 56","pages":" 10391-10394"},"PeriodicalIF":4.3000,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc02491a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A sandwich-structured separator with Si3N4-modified cellulose nanofiber layers on glass fiber is designed. The modified separator inhibits zinc dendrites through the zincophilicity of Si3N4 and cathode dissolution through weak interactions with VO2+. Benefiting from this dual-functional design, the full cells exhibit excellent electrochemical performance at low current densities.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.