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Techno-economic feasibility of alternative energy sources for community water supply in Ghana 加纳社区供水替代能源的技术经济可行性
Pub Date : 2026-06-01 Epub Date: 2026-05-23 DOI: 10.1016/j.clwat.2026.100275
Emmanuel Tabiri , Samuel Gyamfi , Bernard Aboagye , Michael Obeng
Access to clean water remains a major challenge in many developing regions where unreliable electricity supply disrupts water production and distribution. In Goaso, frequent grid instability and power outages significantly affect the reliability of the community water supply system, with adverse implications for public health and socioeconomic development. This study evaluated the techno-economic and environmental performance of four alternative energy systems for improving water supply reliability in Goaso using the HOMER optimisation model. The assessed configurations included the existing grid-only system, the solar photovoltaic (PV)-only system, the hybrid solar PV–grid system, and the hybrid solar PV–diesel generator system. The analysis incorporated a community water demand of 356 m³ /day and assessed key performance indicators including Net Present Cost (NPC), Return on Investment (ROI), payback period, operating cost, and CO₂ emissions. The existing grid-only system recorded an NPC of US$166,329 and annual CO₂ emissions of 58,692 kg. The hybrid solar PV–grid system achieved the best overall performance with an NPC of US$144,698, a payback period of 8.4 years, an ROI of 200%, and reduced annual CO₂ emissions of 36,635 kg. Although the solar PV-only system achieved zero operational CO₂ emissions, its higher infrastructure requirements increased lifecycle cost. Sensitivity analysis further showed that renewable-dominant systems are more resilient to inflation and fuel price fluctuations than fossil-fuel-dependent alternatives. Overall, the hybrid solar PV–grid system provides the most suitable balance between economic viability, environmental sustainability, and operational reliability for community water supply systems in energy-constrained regions.
在许多发展中地区,获得清洁水仍然是一项重大挑战,因为不可靠的电力供应扰乱了水的生产和分配。在果阿索,电网经常不稳定和停电严重影响社区供水系统的可靠性,对公共卫生和社会经济发展产生不利影响。本研究使用HOMER优化模型评估了四种替代能源系统在提高Goaso供水可靠性方面的技术经济和环境绩效。评估的配置包括现有的纯电网系统、纯太阳能光伏(PV)系统、混合太阳能光伏-电网系统和混合太阳能光伏-柴油发电机系统。该分析纳入了356 m³ /天的社区用水需求,并评估了净当前成本(NPC)、投资回报率(ROI)、回收期、运营成本和CO₂排放量等关键绩效指标。现有的纯电网系统的人均消费为16万6329美元,年二氧化碳排放量为5万8692 公斤。混合太阳能光伏电网系统的综合性能最好,其NPC为144,698美元,投资回收期为8.4年,投资回报率为200%,每年减少二氧化碳排放量36,635 公斤。虽然太阳能光伏系统实现了零运营二氧化碳排放,但其更高的基础设施要求增加了生命周期成本。敏感性分析进一步表明,与依赖化石燃料的替代能源相比,以可再生能源为主导的系统对通货膨胀和燃料价格波动更具弹性。总的来说,混合太阳能光伏电网系统为能源受限地区的社区供水系统提供了经济可行性、环境可持续性和运行可靠性之间最合适的平衡。
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引用次数: 0
Corrigendum to “Bibliometric review of ballast water management within the framework of the circular economy” [Clean. Water 5 (2026) 2950–2632] “循环经济框架内压载水管理的文献计量学审查”的勘误表[清洁。水5 (2026)2950-2632]
Pub Date : 2026-06-01 Epub Date: 2026-03-23 DOI: 10.1016/j.clwat.2026.100245
Dian Kurnianing Sari , Mochamad Arief Budihardjo , Annisa Sila Puspita , Fathoni Firmansyah , Ilmi Tri Zenith
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引用次数: 0
PFAS as emerging contaminants (EC): Advancement in remediation strategies, impact on environment and human health PFAS作为新出现的污染物(欧共体):补救策略的进展、对环境和人类健康的影响
Pub Date : 2026-06-01 Epub Date: 2026-05-21 DOI: 10.1016/j.clwat.2026.100274
Kundan Samal
Per- and polyfluoroalkyl substances (PFAS) are highly persistent chemicals widely used as raw materials across various industries for manufacturing everyday products. Due to the exceptional strength of the carbon-fluorine (C-F) bond, PFAS resist degradation and are frequently detected in both aquatic and terrestrial environments. They are classified as emerging contaminants (ECs) because of their ability to bioaccumulate in humans and animals, leading to increasing toxicological concerns and associated health risks. This review presents recent advancements in different treatment technologies for PFAS remediation. Adsorption using novel adsorbents and membrane-based processes remains the most established approach, while advanced technologies such as plasma treatment, sonochemical degradation and subcritical and super critical water oxidation (SCWO) show significant potential for high-efficiency destruction. Biological methods, including microbial degradation and phytoremediation, require further development to improve scalability and performance. The review also examines PFAS contamination pathways through soil, water, and air, their transfer across trophic levels in the food chain, and associated human health effects such as endocrine disruption and hormonal imbalance. Overall, this review provides an overview of emerging treatment strategies, environmental and health implications, and future directions toward sustainable PFAS management.
全氟烷基和多氟烷基物质(PFAS)是高度持久性的化学品,广泛用作制造日常产品的各种工业的原材料。由于碳-氟(C-F)键的特殊强度,PFAS抵抗降解,并且经常在水生和陆地环境中被检测到。它们被归类为新出现的污染物(ECs),因为它们能够在人类和动物体内生物积累,导致越来越多的毒理学问题和相关的健康风险。本文综述了PFAS修复的不同处理技术的最新进展。使用新型吸附剂和膜基工艺的吸附仍然是最成熟的方法,而等离子体处理、声化学降解、亚临界和超临界水氧化(SCWO)等先进技术则显示出高效破坏的巨大潜力。生物方法,包括微生物降解和植物修复,需要进一步发展,以提高可扩展性和性能。该审查还审查了PFAS通过土壤、水和空气的污染途径,它们在食物链中跨营养水平的转移,以及相关的人类健康影响,如内分泌干扰和激素失衡。总体而言,本文综述了新兴的治疗策略、环境和健康影响以及可持续PFAS管理的未来方向。
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引用次数: 0
Microplastic removal efficiency and polymer characterization in coastal wastewater treatment plants using FTIR spectroscopy 滨海污水处理厂微塑料去除效率及聚合物表征
Pub Date : 2026-03-01 Epub Date: 2026-01-08 DOI: 10.1016/j.clwat.2026.100205
Vyoma Jani , Abeeb Oyelere , Basant Bhatt , Jianqiao Song , Kaushik Venkiteshwaran , Alexandra Stenson , Shenghua Wu
Microplastic (MP) pollution in wastewater is a growing concern due to its environmental persistence and ecological toxicity. However, critical data on MPs in the Gulf Coast region of the United States is lacking. This study assessed MP concentrations, polymer types, and removal efficiencies in four wastewater treatment plants (WWTPs) with distinct treatment technologies in the Gulf Coast region. Influent and effluent samples were collected from facilities in Alabama, Mississippi, and Florida, and processed using sequential filtration, peroxide digestion, density separation, and analyzed using Fourier-transform infrared (FTIR) microscopy. Results revealed that total MP concentrations ranged from 3472 ± 2012 particles/m³ in influent to 1372 ± 1740 particles/m³ in effluent, with the wide variability reflecting differences among treatment systems and seasonal sampling conditions. Polyethylene terephthalate (PET) 37 % and Polystyrene (PS) 27 % were the most abundant polymers identified, followed by Polyethylene (PE) 21 % and Polypropylene (PP) 13 %. Polymer-specific removal varied by density and the treatment plant’s removal technology. PET and PS showed high removal (>80 %) at sites with advanced filtration or lagoon-wetland systems, whereas PE and PP exhibited lower removal efficiencies (<60 %). Seasonal trends showed higher loads and weaker removal in winter, while summer had lower loads, with over 90 % removal. This study highlights the influence of polymer type and treatment technology on MP removal and underscores the importance of tailored strategies for MP removal.
废水中的微塑料污染因其环境持久性和生态毒性而日益受到关注。然而,关于美国墨西哥湾沿岸地区国会议员的关键数据是缺乏的。本研究评估了墨西哥湾沿岸地区采用不同处理技术的四个污水处理厂(WWTPs)的MP浓度、聚合物类型和去除效率。从阿拉巴马州、密西西比州和佛罗里达州的设施中收集进水和出水样本,使用顺序过滤、过氧化物消解、密度分离进行处理,并使用傅里叶变换红外(FTIR)显微镜进行分析。结果表明,总MP浓度范围从进水3472 ± 2012颗粒/m³ 到出水1372 ± 1740颗粒/m³ ,差异很大,反映了处理系统和季节采样条件的差异。聚对苯二甲酸乙二醇酯(PET) 37 %和聚苯乙烯(PS) 27 %是最丰富的聚合物,其次是聚乙烯(PE) 21 %和聚丙烯(PP) 13 %。聚合物特异性去除因密度和处理厂的去除技术而异。在高级过滤或泻湖-湿地系统中,PET和PS的去除率较高(>80 %),而PE和PP的去除率较低(<60 %)。季节性趋势表现为冬季负荷较高,去除率较弱,夏季负荷较低,去除率在90% %以上。本研究强调了聚合物类型和处理技术对MP去除的影响,并强调了定制MP去除策略的重要性。
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引用次数: 0
GIS-driven insights into seasonal water quality shifts: The Ganga River’s journey through Patna’s urban drains (Bihar, India) 地理信息系统驱动的季节性水质变化洞察:恒河流经巴特那城市排水沟的旅程(印度比哈尔邦)
Pub Date : 2026-03-01 Epub Date: 2026-01-03 DOI: 10.1016/j.clwat.2026.100203
Bhawana Raj , Avinash Dass , Umesh Kumar Singh , Rajesh Kumar Ranjan
The Ganga River is not only the lifeline for millions in northern India, providing essential water for agriculture, domestic use, and industry, but also holds immense cultural and ecological significance. However, rapid urbanization and unregulated waste discharge have led to escalating pollution, making it crucial to assess the river’s health and irrigation suitability. The current study intended to assess the impact of different drains on the Ganga River at Patna, India, and to evaluate the suitability of Ganga River water quality for irrigation. GIS-driven methods were employed to spatially map water quality indices and visualize pollution hotspots, providing a comprehensive spatial assessment of water quality variations along the river. Multivariate statistical techniques, including Principal Component Analysis (PCA) and Pearson Correlation Matrix (PCM), were used to identify contamination sources, and distinguish between geogenic and anthropogenic influences. A total of 20 samples each were collected during the summer and winter seasons of 2022 and 2023, respectively. The physicochemical parameters were examined, including alkalinity, turbidity, chloride (Cl-), pH, electrical conductivity (EC), total dissolved solids (TDS), DO, Na+, K+, PO43-, NO3-, SO42-, Ca2+, and Mg2+. Also, the water quality index (WQI) and irrigation indices such as the Sodium Adsorption Ratio (SAR), Sodium percentage (%Na), and Kelly’s Ratio (KR) were calculated to assess the suitability of river water for agricultural use. This study provides critical scientific insight into the water quality of the Ganga River at Patna, supporting researchers and policymakers in formulating targeted, drain-specific water management strategies for the Patna stretch of the River Ganga.
恒河不仅是印度北部数百万人的生命线,为农业、家庭和工业提供必要的水,而且具有巨大的文化和生态意义。然而,快速的城市化和不受管制的废物排放导致污染加剧,因此评估河流的健康和灌溉适宜性至关重要。目前的研究旨在评估不同排水渠对印度巴特那恒河的影响,并评估恒河水质是否适合灌溉。采用gis驱动的方法对水质指数进行空间映射,并对污染热点进行可视化,提供了沿江水质变化的综合空间评价。多元统计技术,包括主成分分析(PCA)和Pearson相关矩阵(PCM),用于识别污染源,并区分地质和人为影响。在2022年夏季和2023年冬季分别采集了20份样本。考察了理化参数,包括碱度、浊度、氯离子(Cl-)、pH、电导率(EC)、总溶解固形物(TDS)、DO、Na+、K+、PO43-、NO3-、SO42-、Ca2+和Mg2+。通过计算水质指数(WQI)和灌溉指标(如钠吸附比(SAR)、钠百分比(%Na)和凯利比(KR))来评价河流水的农业适宜性。这项研究为恒河巴特那段的水质提供了重要的科学见解,支持研究人员和决策者为恒河巴特那段制定有针对性的、具体的排水管理战略。
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引用次数: 0
Microplastics in South Africa’s bottled water: Risk metrics and potential health impact 南非瓶装水中的微塑料:风险指标和潜在的健康影响
Pub Date : 2026-03-01 Epub Date: 2026-02-19 DOI: 10.1016/j.clwat.2026.100226
David O. Omole, Kagiso Moima, Neo Matsietsa
Microplastic pollution has emerged as a major environmental and public health concern due to its persistence, ubiquity, and potential toxicity. Widely consumed globally, bottled water has been identified as a significant pathway of human exposure. This study presents one of the first systematic investigations of microplastic contamination in bottled water sold in South Africa. It also advocates for a globally acceptable standard method for detecting microplastics and the need for microplastic limits to be included in drinking water quality standards. Six samples of the leading brands of bottled water in South Africa were purchased randomly from four provinces. The samples were analysed using optical microscopy, Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDS). Microplastics were detected in all samples, with concentrations ranging from 5.0 to 25.0 particles per litre, and a mean concentration of 14.8 ± 7.8 particles per litre across all samples. Fibres (77 %) and fragments (14 %) dominated morphologically, while polyethylene terephthalate (PET) and polypropylene (PP) were the most common polymers identified. Risk indices indicated moderate contamination, with Estimated Daily Intake (EDI) values for adults equal 1.152 particles/kg body weight/day, whereas children have an EDI of 4.400 particles/kg body weight/day. The results confirm bottled water as a consistent source of microplastic exposure, highlight regulatory and public health gaps in South Africa, and call for urgent monitoring, mitigation strategies, and consumer awareness.
微塑料污染由于其持久性、普遍性和潜在毒性,已成为一个主要的环境和公共卫生问题。瓶装水在全球广泛消费,已被确定为人类接触的重要途径。这项研究提出了在南非销售的瓶装水中微塑料污染的第一个系统调查之一。它还倡导采用一种全球可接受的检测微塑料的标准方法,并呼吁将微塑料限量纳入饮用水质量标准。从南非四个省随机购买了六个主要品牌的瓶装水样品。采用光学显微镜、傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM-EDS)对样品进行分析。在所有样品中检测到微塑料,浓度范围为每升5.0至25.0颗粒,所有样品的平均浓度为每升14.8 ± 7.8颗粒。纤维(77 %)和碎片(14 %)在形态上占主导地位,而聚对苯二甲酸乙二醇酯(PET)和聚丙烯(PP)是最常见的聚合物。风险指数显示污染程度中等,成人每日摄入量(EDI)为1.152颗粒/公斤体重/天,而儿童的EDI为4400颗粒/公斤体重/天。研究结果证实,瓶装水一直是微塑料接触的来源,强调了南非在监管和公共卫生方面的差距,并呼吁紧急监测、缓解战略和提高消费者意识。
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引用次数: 0
Comparative hydrogeochemical characterization and environmental controls on groundwater quality, irrigation suitability, and health risk across northern and coastal hydrological settings of Bangladesh 在孟加拉国北部和沿海水文环境中,比较水文地球化学特征和地下水质量、灌溉适宜性和健康风险的环境控制
Pub Date : 2026-03-01 Epub Date: 2025-12-18 DOI: 10.1016/j.clwat.2025.100194
Iffat Ara , Rubaiatul Islam Zerin , Laila Anjum Eva , Md. Kamrul Hossain , Mahmuda Hossain Mou , Akib Javed , Shahin Ali , Md. Anisul Kabir , Md Masud Parves Rana
Groundwater is a vital resource that supports human health, ecosystems, and agriculture, and its quality varies across Bangladesh due to differing geology, land use, and environmental pressures. This study aims to conduct a comparative hydrogeochemical characterization and assess the environmental controls affecting groundwater quality, irrigation suitability, and human health risks across northern (Dinajpur) and coastal (Barisal) hydrological settings in Bangladesh. Groundwater data were obtained from the Bangladesh Water Development Board (BWDB), covering 27 monitoring wells in Dinajpur and 24 in Barisal. Multivariate statistical analyses revealed that groundwater quality in Barisal is primarily influenced by salinity-related factors (EC, TDS, and Major Ions like Na+, Cl-), reflecting coastal saline intrusion. In contrast, Dinajpur samples were associated with parameters like SAR, Si+, PO43-, ORP, I⁻, CaCO3, and B, indicating geogenic influences from silicate weathering, carbonate dissolution, and fertilizer inputs from agriculture. The Water Quality Index (WQI) results showed that in Barisal, 20.83 % of sites were excellent and 18 % unsuitable for drinking, whereas in Dinajpur, 64.29 % were excellent with no unfit sites. For irrigation suitability, Barisal had 75 % excellent and 4.17 % severely affected areas, while 44.44 % excellent and 14.81 % severely affected sites were observed in Dinajpur. Health risk assessment revealed significantly higher Hazard Index (HI) values in Barishal across all age groups compared to Dinajpur, indicating elevated potential health risks in the coastal region. Children were identified as the most vulnerable group, exhibiting higher HI values than males and females in both Barishal (HI = 0.38–57.29) and Dinajpur (HI = 0.34–4.41). The Pearson Correlation analysis indicated that in Dinajpur, environmental variables demonstrated negligible correlations with groundwater quality (WQI: r = –0.18–0.19; IWQI: NDVI r = 0.25, LST r = –0.20). Similarly, Barishal had negligible correlations, with the Water Quality Index (WQI) revealing a little link with NDVI and NDWI, respectively (r = 0.17–0.24), whilst the Integrated Water Quality Index (IWQI) indicated minimal impact across all indices (r = –0.03–0.19). Overall, the study highlights regional variations in groundwater quality and health risks, emphasizing the necessity for location-specific water resource management strategies.
地下水是支持人类健康、生态系统和农业的重要资源,由于地质、土地利用和环境压力的不同,孟加拉国各地的地下水质量各不相同。本研究旨在进行水文地球化学特征的比较,并评估影响孟加拉国北部(Dinajpur)和沿海(Barisal)水文环境的地下水质量、灌溉适宜性和人类健康风险的环境控制。地下水数据是从孟加拉国水开发委员会获得的,包括Dinajpur的27口监测井和Barisal的24口监测井。多元统计分析表明,Barisal地下水水质主要受盐度相关因子(EC、TDS以及Na+、Cl-等主要离子)的影响,反映了沿海盐入侵。相比之下,Dinajpur样品与SAR、Si+、PO43-、ORP、I -毒血症、CaCO3和B等参数相关,表明硅酸盐风化、碳酸盐溶解和农业肥料投入对地质因素的影响。水质指数(WQI)结果表明,Barisal有20.83 %的水质优良,18 %的水质不适宜饮用;Dinajpur有64.29 %的水质优良,没有不适宜饮用的水质。在灌溉适宜性方面,Barisal为75% %优,4.17% %重度受灾,而Dinajpur为44.44% %优,14.81 %重度受灾。健康风险评估显示,与迪纳杰普尔相比,巴里沙尔所有年龄组的危害指数(HI)值明显更高,表明沿海地区的潜在健康风险较高。在Barishal (HI = 0.38-57.29)和Dinajpur (HI = 0.34-4.41),儿童的HI值均高于男性和女性,被确定为最弱势群体。Pearson相关分析表明,在Dinajpur,环境变量与地下水质量的相关性可以忽略不计(WQI: r = -0.18-0.19;IWQI: NDVI r = 0.25,LST r = -0.20)。同样,Barishal的相关性可以忽略不计,水质指数(WQI)分别与NDVI和NDWI有一点联系(r = 0.17-0.24),而综合水质指数(IWQI)表明所有指数的影响最小(r = -0.03-0.19)。总体而言,该研究强调了地下水质量和健康风险的区域差异,强调了制定因地制宜的水资源管理战略的必要性。
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引用次数: 0
Arsenic in groundwater: Exploring its origins, human interventions, and sustainable paths forward 地下水中的砷:探讨其来源、人为干预和可持续发展的途径
Pub Date : 2026-03-01 Epub Date: 2025-12-24 DOI: 10.1016/j.clwat.2025.100199
Debojyoti Mishra , Kamalesh Sen , Soumya Kundu , Naba Kumar Mondal
Arsenic (As) contamination in groundwater has emerged as a global environmental concern, posing severe metabolic and health hazards to humans. Its widespread occurrence in aquifers, especially across South and Southeast Asia, highlights the growing threat to safe drinking water. While the contamination largely originates from geogenic sources, anthropogenic influences have increasingly contributed to its persistence in the ‘21st century’, according to the recent insights of literature. Present study presents an integrated overview of the chemical profile, sources, and hydrogeochemical behaviour of arsenic in groundwater. It outlines the mobilization mechanisms and summarizes key quantification techniques applied in groundwater studies. A dedicated section addresses the adverse health impacts of arsenic exposure, including major exposure routes, dermatological effects, and systemic disorders. Regional hydrogeology in India demonstrates that Himalayan River systems transport arsenic-bearing minerals downstream, enriching alluvial aquifers and exacerbating contamination. Prolonged exposure leads to skin lesions, pulmonary diseases, and carcinogenic outcomes, posing a major public health burden. The paper further highlights sustainable mitigation strategies such as adsorption, ion exchange, and membrane-based technologies to curb arsenic toxicity. Attaining arsenic-safe groundwater remains a critical challenge; however, sustainable remediation and management practices are pivotal to achieving the United Nations Sustainable Development Goals (SDG-3 and SDG-6), ensuring clean water and good health for all.
地下水中的砷污染已成为一个全球性的环境问题,对人类的代谢和健康造成严重危害。它在含水层中的广泛存在,特别是在南亚和东南亚,突出了对安全饮用水的日益严重的威胁。根据最近文献的见解,虽然污染主要来自地质来源,但人为影响越来越多地导致其在“21世纪”持续存在。本研究对地下水中砷的化学特征、来源和水文地球化学行为进行了综合综述。概述了地下水的动员机制,总结了地下水研究中应用的关键量化技术。专门的一节论述了砷接触对健康的不利影响,包括主要接触途径、皮肤病影响和全身疾病。印度的区域水文地质表明,喜马拉雅河系统向下游输送含砷矿物,使冲积含水层富集,加剧了污染。长期接触会导致皮肤损伤、肺部疾病和致癌后果,造成重大的公共卫生负担。本文进一步强调了可持续的缓解策略,如吸附、离子交换和基于膜的技术来抑制砷的毒性。获得砷安全的地下水仍然是一项重大挑战;然而,可持续的补救和管理做法对于实现联合国可持续发展目标(可持续发展目标3和6)至关重要,可确保人人享有清洁用水和良好健康。
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引用次数: 0
Development of zinc oxide-charcoal-polyacrylic nanocomposite hydrogels for enhanced dye degradation under direct sunlight irradiation and antibacterial applications 氧化锌-炭-聚丙烯酸纳米复合水凝胶的研制及其在日光直射下增强染料降解和抗菌应用
Pub Date : 2026-03-01 Epub Date: 2026-02-09 DOI: 10.1016/j.clwat.2026.100219
Alam S.M. Nur , Souvik Biswas Soumma , Zhumpa Rani Saha , Md. Mahfuzur Rahman , Dipta Das , Mahbub Hasan Rownok , Marzia Sultana , Maria Rhaman Mitu , Tafsir Ahmed Nayef , Md. Tanvir Islam , Sk. Faijus Sadekin , Ashaduzzaman Md.
Hydrogels with enhanced photocatalytic activity have emerged as promising materials for wastewater treatment and antimicrobial applications. Nanocomposite hydrogels were synthesized using zinc oxide, charcoal, and polyacrylic acid (PAA) through free radical polymerization. These hydrogels were tested for their photocatalytic activity by degrading rhodamine B under direct sunlight and UV-Vis irradiation. The prepared samples were characterized using various techniques, including X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), Thermogravimetric Analysis (TGA), and point of zero charge analysis (pHpzc). EDX analysis confirmed the presence of elemental components, while the XRD pattern and FTIR spectrum indicated the successful incorporation of zinc oxide and charcoal into the PAA chains. TGA analysis revealed that the hydrogel containing zinc oxide exhibited better thermal stability than the hydrogel composed solely of charcoal and PAA. SEM imaging showed porous network within the hydrogels. The combination of zinc oxide and charcoal improved electron flow under both sunlight and UV-Vis light, significantly enhancing the degradation of dye molecules. Additionally, the surface functional groups present on the charcoal increased the hydrogel’s dye adsorption capacity. The effectiveness of dye degradation was influenced by factors such as pH, initial dye concentration, and the amount of zinc oxide content in the hydrogel. The hydrogel containing 1 g of zinc oxide achieved a maximum rhodamine B degradation of 78.33 % under sunlight and 92.54 % under UV-Vis irradiation. Furthermore, the hydrogels containing zinc oxide demonstrated strong antibacterial activity against both Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria. The zinc oxide-charcoal-PAA nanocomposite hydrogels exhibited strong antibacterial properties and effective sunlight-driven photocatalytic degradation of dyes, highlighting their potential application in treating textile wastewater.
具有增强光催化活性的水凝胶已成为污水处理和抗菌应用的有前途的材料。以氧化锌、活性炭和聚丙烯酸为原料,通过自由基聚合法制备了纳米复合水凝胶。通过在阳光直射和紫外-可见照射下降解罗丹明B,测试了这些水凝胶的光催化活性。利用x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、扫描电镜(SEM)、能量色散x射线光谱(EDX)、热重分析(TGA)和零电荷点分析(pHpzc)等技术对制备的样品进行了表征。EDX分析证实了元素成分的存在,而XRD和FTIR谱图表明氧化锌和木炭成功掺入PAA链中。TGA分析表明,含氧化锌的水凝胶比仅含活性炭和PAA的水凝胶具有更好的热稳定性。扫描电镜成像显示水凝胶内部有多孔网络。氧化锌与木炭的结合改善了在日光和UV-Vis光下的电子流,显著增强了染料分子的降解。此外,活性炭表面的官能团增加了水凝胶对染料的吸附能力。染料降解效果受pH、初始染料浓度、水凝胶中氧化锌含量等因素的影响。含有1 g氧化锌的水凝胶在日光和紫外-可见照射下对罗丹明B的最大降解率分别为78.33 %和92.54 %。此外,氧化锌水凝胶对革兰氏阳性菌(金黄色葡萄球菌)和革兰氏阴性菌(大肠杆菌)均表现出较强的抗菌活性。氧化锌-炭- paa纳米复合水凝胶具有较强的抗菌性能和对染料的光催化降解效果,在纺织废水处理中具有潜在的应用前景。
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引用次数: 0
Bio-based chitosan-grafted microcrystalline cellulose as an adsorbent for efficient removal of chromium and cadmium from simulated wastewater 生物基壳聚糖接枝微晶纤维素作为吸附剂对模拟废水中铬和镉的高效去除
Pub Date : 2026-03-01 Epub Date: 2026-02-14 DOI: 10.1016/j.clwat.2026.100222
M.H. Rahaman , Md. Rakibul Islam , Md. Aminur Rahman , Md. Hafizul Islam , Sabrina Afrin , S.M. Nur Alam , Tasrina Rabia Choudhury , M. Safiur Rahman
Heavy metals such as Chromium (Cr) and Cadmium (Cd) are highly toxic elements detected in industrial wastewater. In this work, a bio-based composite adsorbent composed of chitosan (CS) and CS-grafted microcrystalline cellulose (MCC) is utilized for the removal of Cr and Cd from simulated wastewater. CS, MCC, CS grafted MCC (CS-g-MCC), and the CS/CS-g-MCC composite were prepared and inspected using Fourier Transform Infrared spectroscopy (FTIR), Scanning Electron Microscope (SEM), and Wide-angle X-ray diffraction (WAXD) analysis. Metal ion concentrations before and after adsorption by the CS/CS-g-MCC composite were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES), and removal efficiencies for total chromium and cadmium were reported. Batch adsorption experiments were conducted to examine the effects of pH, contact time, adsorbent dosage, and initial metal concentration. The adsorption kinetics were adequately described by the pseudo-second-order model, indicating that chemisorption may contribute to the uptake process. Equilibrium data were analyzed using Langmuir and Freundlich isotherm models to provide comparative insight into adsorption behavior, yielding estimated maximum adsorption capacities of approximately 46 mg/g for CrTotal and 74 mg/g for Cd²⁺ under the tested conditions. Interference studies showed that PO₄³⁻ significantly suppressed CrTotal uptake, while Cd²⁺ adsorption was less affected by competing ions. Regeneration experiments over four adsorption–desorption cycles using (NH₄)₂SO₄ demonstrated reasonable short-term reusability, although gradual performance decline was observed. Overall, the CS/CS-g-MCC composite shows promise as a bio-based adsorbent for heavy-metal removal, while further studies are required to strengthen equilibrium modeling and long-term stability assessment.
铬(Cr)和镉(Cd)等重金属是工业废水中检测到的剧毒元素。利用壳聚糖(CS)和壳聚糖接枝微晶纤维素(MCC)组成的生物基复合吸附剂去除模拟废水中的Cr和Cd。制备了CS、MCC、CS接枝MCC (CS-g-MCC)和CS/CS-g-MCC复合材料,并采用傅里叶变换红外光谱(FTIR)、扫描电镜(SEM)和广角x射线衍射(WAXD)分析对其进行了表征。采用电感耦合等离子体发射光谱法(ICP-OES)测定了CS/CS-g- mcc复合材料吸附前后的金属离子浓度,并报道了对总铬和总镉的去除效率。通过批量吸附实验考察了pH、接触时间、吸附剂用量、初始金属浓度等因素对吸附效果的影响。拟二级吸附模型充分描述了吸附动力学,表明化学吸附可能参与了吸附过程。使用Langmuir和Freundlich等温模型分析平衡数据,以提供对吸附行为的比较了解,得出在测试条件下,CrTotal的最大吸附容量约为46 mg/g, Cd 2⁺的最大吸附容量约为74 mg/g。干扰研究表明,PO₄³⁻能明显抑制CrTotal的摄取,而Cd²⁺的吸附受竞争离子的影响较小。使用(NH₄)2 SO₄进行4次吸附-解吸循环的再生实验表明,尽管性能逐渐下降,但短期内可重复使用。综上所述,CS/CS-g- mcc复合材料有望成为一种去除重金属的生物基吸附剂,但还需要进一步的研究来加强平衡建模和长期稳定性评估。
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