Pub Date : 2026-06-01Epub Date: 2026-05-23DOI: 10.1016/j.clwat.2026.100275
Emmanuel Tabiri , Samuel Gyamfi , Bernard Aboagye , Michael Obeng
Access to clean water remains a major challenge in many developing regions where unreliable electricity supply disrupts water production and distribution. In Goaso, frequent grid instability and power outages significantly affect the reliability of the community water supply system, with adverse implications for public health and socioeconomic development. This study evaluated the techno-economic and environmental performance of four alternative energy systems for improving water supply reliability in Goaso using the HOMER optimisation model. The assessed configurations included the existing grid-only system, the solar photovoltaic (PV)-only system, the hybrid solar PV–grid system, and the hybrid solar PV–diesel generator system. The analysis incorporated a community water demand of 356 m³ /day and assessed key performance indicators including Net Present Cost (NPC), Return on Investment (ROI), payback period, operating cost, and CO₂ emissions. The existing grid-only system recorded an NPC of US$166,329 and annual CO₂ emissions of 58,692 kg. The hybrid solar PV–grid system achieved the best overall performance with an NPC of US$144,698, a payback period of 8.4 years, an ROI of 200%, and reduced annual CO₂ emissions of 36,635 kg. Although the solar PV-only system achieved zero operational CO₂ emissions, its higher infrastructure requirements increased lifecycle cost. Sensitivity analysis further showed that renewable-dominant systems are more resilient to inflation and fuel price fluctuations than fossil-fuel-dependent alternatives. Overall, the hybrid solar PV–grid system provides the most suitable balance between economic viability, environmental sustainability, and operational reliability for community water supply systems in energy-constrained regions.
{"title":"Techno-economic feasibility of alternative energy sources for community water supply in Ghana","authors":"Emmanuel Tabiri , Samuel Gyamfi , Bernard Aboagye , Michael Obeng","doi":"10.1016/j.clwat.2026.100275","DOIUrl":"10.1016/j.clwat.2026.100275","url":null,"abstract":"<div><div>Access to clean water remains a major challenge in many developing regions where unreliable electricity supply disrupts water production and distribution. In Goaso, frequent grid instability and power outages significantly affect the reliability of the community water supply system, with adverse implications for public health and socioeconomic development. This study evaluated the techno-economic and environmental performance of four alternative energy systems for improving water supply reliability in Goaso using the HOMER optimisation model. The assessed configurations included the existing grid-only system, the solar photovoltaic (PV)-only system, the hybrid solar PV–grid system, and the hybrid solar PV–diesel generator system. The analysis incorporated a community water demand of 356 m³ /day and assessed key performance indicators including Net Present Cost (NPC), Return on Investment (ROI), payback period, operating cost, and CO₂ emissions. The existing grid-only system recorded an NPC of US$166,329 and annual CO₂ emissions of 58,692 kg. The hybrid solar PV–grid system achieved the best overall performance with an NPC of US$144,698, a payback period of 8.4 years, an ROI of 200%, and reduced annual CO₂ emissions of 36,635 kg. Although the solar PV-only system achieved zero operational CO₂ emissions, its higher infrastructure requirements increased lifecycle cost. Sensitivity analysis further showed that renewable-dominant systems are more resilient to inflation and fuel price fluctuations than fossil-fuel-dependent alternatives. Overall, the hybrid solar PV–grid system provides the most suitable balance between economic viability, environmental sustainability, and operational reliability for community water supply systems in energy-constrained regions.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"6 ","pages":"Article 100275"},"PeriodicalIF":0.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148178022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-06-01Epub Date: 2026-03-23DOI: 10.1016/j.clwat.2026.100245
Dian Kurnianing Sari , Mochamad Arief Budihardjo , Annisa Sila Puspita , Fathoni Firmansyah , Ilmi Tri Zenith
{"title":"Corrigendum to “Bibliometric review of ballast water management within the framework of the circular economy” [Clean. Water 5 (2026) 2950–2632]","authors":"Dian Kurnianing Sari , Mochamad Arief Budihardjo , Annisa Sila Puspita , Fathoni Firmansyah , Ilmi Tri Zenith","doi":"10.1016/j.clwat.2026.100245","DOIUrl":"10.1016/j.clwat.2026.100245","url":null,"abstract":"","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"6 ","pages":"Article 100245"},"PeriodicalIF":0.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148178145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-06-01Epub Date: 2026-05-21DOI: 10.1016/j.clwat.2026.100274
Kundan Samal
Per- and polyfluoroalkyl substances (PFAS) are highly persistent chemicals widely used as raw materials across various industries for manufacturing everyday products. Due to the exceptional strength of the carbon-fluorine (C-F) bond, PFAS resist degradation and are frequently detected in both aquatic and terrestrial environments. They are classified as emerging contaminants (ECs) because of their ability to bioaccumulate in humans and animals, leading to increasing toxicological concerns and associated health risks. This review presents recent advancements in different treatment technologies for PFAS remediation. Adsorption using novel adsorbents and membrane-based processes remains the most established approach, while advanced technologies such as plasma treatment, sonochemical degradation and subcritical and super critical water oxidation (SCWO) show significant potential for high-efficiency destruction. Biological methods, including microbial degradation and phytoremediation, require further development to improve scalability and performance. The review also examines PFAS contamination pathways through soil, water, and air, their transfer across trophic levels in the food chain, and associated human health effects such as endocrine disruption and hormonal imbalance. Overall, this review provides an overview of emerging treatment strategies, environmental and health implications, and future directions toward sustainable PFAS management.
{"title":"PFAS as emerging contaminants (EC): Advancement in remediation strategies, impact on environment and human health","authors":"Kundan Samal","doi":"10.1016/j.clwat.2026.100274","DOIUrl":"10.1016/j.clwat.2026.100274","url":null,"abstract":"<div><div>Per- and polyfluoroalkyl substances (PFAS) are highly persistent chemicals widely used as raw materials across various industries for manufacturing everyday products. Due to the exceptional strength of the carbon-fluorine (C-F) bond, PFAS resist degradation and are frequently detected in both aquatic and terrestrial environments. They are classified as emerging contaminants (ECs) because of their ability to bioaccumulate in humans and animals, leading to increasing toxicological concerns and associated health risks. This review presents recent advancements in different treatment technologies for PFAS remediation. Adsorption using novel adsorbents and membrane-based processes remains the most established approach, while advanced technologies such as plasma treatment, sonochemical degradation and subcritical and super critical water oxidation (SCWO) show significant potential for high-efficiency destruction. Biological methods, including microbial degradation and phytoremediation, require further development to improve scalability and performance. The review also examines PFAS contamination pathways through soil, water, and air, their transfer across trophic levels in the food chain, and associated human health effects such as endocrine disruption and hormonal imbalance. Overall, this review provides an overview of emerging treatment strategies, environmental and health implications, and future directions toward sustainable PFAS management.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"6 ","pages":"Article 100274"},"PeriodicalIF":0.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148178023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-01-08DOI: 10.1016/j.clwat.2026.100205
Vyoma Jani , Abeeb Oyelere , Basant Bhatt , Jianqiao Song , Kaushik Venkiteshwaran , Alexandra Stenson , Shenghua Wu
Microplastic (MP) pollution in wastewater is a growing concern due to its environmental persistence and ecological toxicity. However, critical data on MPs in the Gulf Coast region of the United States is lacking. This study assessed MP concentrations, polymer types, and removal efficiencies in four wastewater treatment plants (WWTPs) with distinct treatment technologies in the Gulf Coast region. Influent and effluent samples were collected from facilities in Alabama, Mississippi, and Florida, and processed using sequential filtration, peroxide digestion, density separation, and analyzed using Fourier-transform infrared (FTIR) microscopy. Results revealed that total MP concentrations ranged from 3472 ± 2012 particles/m³ in influent to 1372 ± 1740 particles/m³ in effluent, with the wide variability reflecting differences among treatment systems and seasonal sampling conditions. Polyethylene terephthalate (PET) 37 % and Polystyrene (PS) 27 % were the most abundant polymers identified, followed by Polyethylene (PE) 21 % and Polypropylene (PP) 13 %. Polymer-specific removal varied by density and the treatment plant’s removal technology. PET and PS showed high removal (>80 %) at sites with advanced filtration or lagoon-wetland systems, whereas PE and PP exhibited lower removal efficiencies (<60 %). Seasonal trends showed higher loads and weaker removal in winter, while summer had lower loads, with over 90 % removal. This study highlights the influence of polymer type and treatment technology on MP removal and underscores the importance of tailored strategies for MP removal.
{"title":"Microplastic removal efficiency and polymer characterization in coastal wastewater treatment plants using FTIR spectroscopy","authors":"Vyoma Jani , Abeeb Oyelere , Basant Bhatt , Jianqiao Song , Kaushik Venkiteshwaran , Alexandra Stenson , Shenghua Wu","doi":"10.1016/j.clwat.2026.100205","DOIUrl":"10.1016/j.clwat.2026.100205","url":null,"abstract":"<div><div>Microplastic (MP) pollution in wastewater is a growing concern due to its environmental persistence and ecological toxicity. However, critical data on MPs in the Gulf Coast region of the United States is lacking. This study assessed MP concentrations, polymer types, and removal efficiencies in four wastewater treatment plants (WWTPs) with distinct treatment technologies in the Gulf Coast region. Influent and effluent samples were collected from facilities in Alabama, Mississippi, and Florida, and processed using sequential filtration, peroxide digestion, density separation, and analyzed using Fourier-transform infrared (FTIR) microscopy. Results revealed that total MP concentrations ranged from 3472 ± 2012 particles/m³ in influent to 1372 ± 1740 particles/m³ in effluent, with the wide variability reflecting differences among treatment systems and seasonal sampling conditions. Polyethylene terephthalate (PET) 37 % and Polystyrene (PS) 27 % were the most abundant polymers identified, followed by Polyethylene (PE) 21 % and Polypropylene (PP) 13 %. Polymer-specific removal varied by density and the treatment plant’s removal technology. PET and PS showed high removal (>80 %) at sites with advanced filtration or lagoon-wetland systems, whereas PE and PP exhibited lower removal efficiencies (<60 %). Seasonal trends showed higher loads and weaker removal in winter, while summer had lower loads, with over 90 % removal. This study highlights the influence of polymer type and treatment technology on MP removal and underscores the importance of tailored strategies for MP removal.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100205"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145926079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Ganga River is not only the lifeline for millions in northern India, providing essential water for agriculture, domestic use, and industry, but also holds immense cultural and ecological significance. However, rapid urbanization and unregulated waste discharge have led to escalating pollution, making it crucial to assess the river’s health and irrigation suitability. The current study intended to assess the impact of different drains on the Ganga River at Patna, India, and to evaluate the suitability of Ganga River water quality for irrigation. GIS-driven methods were employed to spatially map water quality indices and visualize pollution hotspots, providing a comprehensive spatial assessment of water quality variations along the river. Multivariate statistical techniques, including Principal Component Analysis (PCA) and Pearson Correlation Matrix (PCM), were used to identify contamination sources, and distinguish between geogenic and anthropogenic influences. A total of 20 samples each were collected during the summer and winter seasons of 2022 and 2023, respectively. The physicochemical parameters were examined, including alkalinity, turbidity, chloride (Cl-), pH, electrical conductivity (EC), total dissolved solids (TDS), DO, Na+, K+, PO43-, NO3-, SO42-, Ca2+, and Mg2+. Also, the water quality index (WQI) and irrigation indices such as the Sodium Adsorption Ratio (SAR), Sodium percentage (%Na), and Kelly’s Ratio (KR) were calculated to assess the suitability of river water for agricultural use. This study provides critical scientific insight into the water quality of the Ganga River at Patna, supporting researchers and policymakers in formulating targeted, drain-specific water management strategies for the Patna stretch of the River Ganga.
{"title":"GIS-driven insights into seasonal water quality shifts: The Ganga River’s journey through Patna’s urban drains (Bihar, India)","authors":"Bhawana Raj , Avinash Dass , Umesh Kumar Singh , Rajesh Kumar Ranjan","doi":"10.1016/j.clwat.2026.100203","DOIUrl":"10.1016/j.clwat.2026.100203","url":null,"abstract":"<div><div>The Ganga River is not only the lifeline for millions in northern India, providing essential water for agriculture, domestic use, and industry, but also holds immense cultural and ecological significance. However, rapid urbanization and unregulated waste discharge have led to escalating pollution, making it crucial to assess the river’s health and irrigation suitability. The current study intended to assess the impact of different drains on the Ganga River at Patna, India, and to evaluate the suitability of Ganga River water quality for irrigation. GIS-driven methods were employed to spatially map water quality indices and visualize pollution hotspots, providing a comprehensive spatial assessment of water quality variations along the river. Multivariate statistical techniques, including Principal Component Analysis (PCA) and Pearson Correlation Matrix (PCM), were used to identify contamination sources, and distinguish between geogenic and anthropogenic influences. A total of 20 samples each were collected during the summer and winter seasons of 2022 and 2023, respectively. The physicochemical parameters were examined, including alkalinity, turbidity, chloride (Cl<sup>-</sup>), pH, electrical conductivity (EC), total dissolved solids (TDS), DO, Na<sup>+</sup>, K<sup>+</sup>, PO<sub>4</sub><sup>3-</sup>, NO<sub>3</sub><sup>-</sup>, SO<sub>4</sub><sup>2-</sup>, Ca<sup>2+</sup>, and Mg<sup>2+</sup>. Also, the water quality index (WQI) and irrigation indices such as the Sodium Adsorption Ratio (SAR), Sodium percentage (%Na), and Kelly’s Ratio (KR) were calculated to assess the suitability of river water for agricultural use. This study provides critical scientific insight into the water quality of the Ganga River at Patna, supporting researchers and policymakers in formulating targeted, drain-specific water management strategies for the Patna stretch of the River Ganga.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100203"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145926080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-02-19DOI: 10.1016/j.clwat.2026.100226
David O. Omole, Kagiso Moima, Neo Matsietsa
Microplastic pollution has emerged as a major environmental and public health concern due to its persistence, ubiquity, and potential toxicity. Widely consumed globally, bottled water has been identified as a significant pathway of human exposure. This study presents one of the first systematic investigations of microplastic contamination in bottled water sold in South Africa. It also advocates for a globally acceptable standard method for detecting microplastics and the need for microplastic limits to be included in drinking water quality standards. Six samples of the leading brands of bottled water in South Africa were purchased randomly from four provinces. The samples were analysed using optical microscopy, Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDS). Microplastics were detected in all samples, with concentrations ranging from 5.0 to 25.0 particles per litre, and a mean concentration of 14.8 ± 7.8 particles per litre across all samples. Fibres (77 %) and fragments (14 %) dominated morphologically, while polyethylene terephthalate (PET) and polypropylene (PP) were the most common polymers identified. Risk indices indicated moderate contamination, with Estimated Daily Intake (EDI) values for adults equal 1.152 particles/kg body weight/day, whereas children have an EDI of 4.400 particles/kg body weight/day. The results confirm bottled water as a consistent source of microplastic exposure, highlight regulatory and public health gaps in South Africa, and call for urgent monitoring, mitigation strategies, and consumer awareness.
{"title":"Microplastics in South Africa’s bottled water: Risk metrics and potential health impact","authors":"David O. Omole, Kagiso Moima, Neo Matsietsa","doi":"10.1016/j.clwat.2026.100226","DOIUrl":"10.1016/j.clwat.2026.100226","url":null,"abstract":"<div><div>Microplastic pollution has emerged as a major environmental and public health concern due to its persistence, ubiquity, and potential toxicity. Widely consumed globally, bottled water has been identified as a significant pathway of human exposure. This study presents one of the first systematic investigations of microplastic contamination in bottled water sold in South Africa. It also advocates for a globally acceptable standard method for detecting microplastics and the need for microplastic limits to be included in drinking water quality standards. Six samples of the leading brands of bottled water in South Africa were purchased randomly from four provinces. The samples were analysed using optical microscopy, Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDS). Microplastics were detected in all samples, with concentrations ranging from 5.0 to 25.0 particles per litre, and a mean concentration of 14.8 ± 7.8 particles per litre across all samples. Fibres (77 %) and fragments (14 %) dominated morphologically, while polyethylene terephthalate (PET) and polypropylene (PP) were the most common polymers identified. Risk indices indicated moderate contamination, with Estimated Daily Intake (EDI) values for adults equal 1.152 particles/kg body weight/day, whereas children have an EDI of 4.400 particles/kg body weight/day. The results confirm bottled water as a consistent source of microplastic exposure, highlight regulatory and public health gaps in South Africa, and call for urgent monitoring, mitigation strategies, and consumer awareness.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100226"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2025-12-18DOI: 10.1016/j.clwat.2025.100194
Iffat Ara , Rubaiatul Islam Zerin , Laila Anjum Eva , Md. Kamrul Hossain , Mahmuda Hossain Mou , Akib Javed , Shahin Ali , Md. Anisul Kabir , Md Masud Parves Rana
Groundwater is a vital resource that supports human health, ecosystems, and agriculture, and its quality varies across Bangladesh due to differing geology, land use, and environmental pressures. This study aims to conduct a comparative hydrogeochemical characterization and assess the environmental controls affecting groundwater quality, irrigation suitability, and human health risks across northern (Dinajpur) and coastal (Barisal) hydrological settings in Bangladesh. Groundwater data were obtained from the Bangladesh Water Development Board (BWDB), covering 27 monitoring wells in Dinajpur and 24 in Barisal. Multivariate statistical analyses revealed that groundwater quality in Barisal is primarily influenced by salinity-related factors (EC, TDS, and Major Ions like Na+, Cl-), reflecting coastal saline intrusion. In contrast, Dinajpur samples were associated with parameters like SAR, Si+, PO43-, ORP, I⁻, CaCO3, and B, indicating geogenic influences from silicate weathering, carbonate dissolution, and fertilizer inputs from agriculture. The Water Quality Index (WQI) results showed that in Barisal, 20.83 % of sites were excellent and 18 % unsuitable for drinking, whereas in Dinajpur, 64.29 % were excellent with no unfit sites. For irrigation suitability, Barisal had 75 % excellent and 4.17 % severely affected areas, while 44.44 % excellent and 14.81 % severely affected sites were observed in Dinajpur. Health risk assessment revealed significantly higher Hazard Index (HI) values in Barishal across all age groups compared to Dinajpur, indicating elevated potential health risks in the coastal region. Children were identified as the most vulnerable group, exhibiting higher HI values than males and females in both Barishal (HI = 0.38–57.29) and Dinajpur (HI = 0.34–4.41). The Pearson Correlation analysis indicated that in Dinajpur, environmental variables demonstrated negligible correlations with groundwater quality (WQI: r = –0.18–0.19; IWQI: NDVI r = 0.25, LST r = –0.20). Similarly, Barishal had negligible correlations, with the Water Quality Index (WQI) revealing a little link with NDVI and NDWI, respectively (r = 0.17–0.24), whilst the Integrated Water Quality Index (IWQI) indicated minimal impact across all indices (r = –0.03–0.19). Overall, the study highlights regional variations in groundwater quality and health risks, emphasizing the necessity for location-specific water resource management strategies.
地下水是支持人类健康、生态系统和农业的重要资源,由于地质、土地利用和环境压力的不同,孟加拉国各地的地下水质量各不相同。本研究旨在进行水文地球化学特征的比较,并评估影响孟加拉国北部(Dinajpur)和沿海(Barisal)水文环境的地下水质量、灌溉适宜性和人类健康风险的环境控制。地下水数据是从孟加拉国水开发委员会获得的,包括Dinajpur的27口监测井和Barisal的24口监测井。多元统计分析表明,Barisal地下水水质主要受盐度相关因子(EC、TDS以及Na+、Cl-等主要离子)的影响,反映了沿海盐入侵。相比之下,Dinajpur样品与SAR、Si+、PO43-、ORP、I -毒血症、CaCO3和B等参数相关,表明硅酸盐风化、碳酸盐溶解和农业肥料投入对地质因素的影响。水质指数(WQI)结果表明,Barisal有20.83 %的水质优良,18 %的水质不适宜饮用;Dinajpur有64.29 %的水质优良,没有不适宜饮用的水质。在灌溉适宜性方面,Barisal为75% %优,4.17% %重度受灾,而Dinajpur为44.44% %优,14.81 %重度受灾。健康风险评估显示,与迪纳杰普尔相比,巴里沙尔所有年龄组的危害指数(HI)值明显更高,表明沿海地区的潜在健康风险较高。在Barishal (HI = 0.38-57.29)和Dinajpur (HI = 0.34-4.41),儿童的HI值均高于男性和女性,被确定为最弱势群体。Pearson相关分析表明,在Dinajpur,环境变量与地下水质量的相关性可以忽略不计(WQI: r = -0.18-0.19;IWQI: NDVI r = 0.25,LST r = -0.20)。同样,Barishal的相关性可以忽略不计,水质指数(WQI)分别与NDVI和NDWI有一点联系(r = 0.17-0.24),而综合水质指数(IWQI)表明所有指数的影响最小(r = -0.03-0.19)。总体而言,该研究强调了地下水质量和健康风险的区域差异,强调了制定因地制宜的水资源管理战略的必要性。
{"title":"Comparative hydrogeochemical characterization and environmental controls on groundwater quality, irrigation suitability, and health risk across northern and coastal hydrological settings of Bangladesh","authors":"Iffat Ara , Rubaiatul Islam Zerin , Laila Anjum Eva , Md. Kamrul Hossain , Mahmuda Hossain Mou , Akib Javed , Shahin Ali , Md. Anisul Kabir , Md Masud Parves Rana","doi":"10.1016/j.clwat.2025.100194","DOIUrl":"10.1016/j.clwat.2025.100194","url":null,"abstract":"<div><div>Groundwater is a vital resource that supports human health, ecosystems, and agriculture, and its quality varies across Bangladesh due to differing geology, land use, and environmental pressures. This study aims to conduct a comparative hydrogeochemical characterization and assess the environmental controls affecting groundwater quality, irrigation suitability, and human health risks across northern (Dinajpur) and coastal (Barisal) hydrological settings in Bangladesh. Groundwater data were obtained from the Bangladesh Water Development Board (BWDB), covering 27 monitoring wells in Dinajpur and 24 in Barisal. Multivariate statistical analyses revealed that groundwater quality in Barisal is primarily influenced by salinity-related factors (EC, TDS, and Major Ions like Na<sup>+</sup>, Cl<sup>-</sup>), reflecting coastal saline intrusion. In contrast, Dinajpur samples were associated with parameters like SAR, Si<sup>+</sup>, PO<sub>4</sub><sup>3-</sup>, ORP, I⁻, CaCO<sub>3</sub>, and B, indicating geogenic influences from silicate weathering, carbonate dissolution, and fertilizer inputs from agriculture. The Water Quality Index (WQI) results showed that in Barisal, 20.83 % of sites were excellent and 18 % unsuitable for drinking, whereas in Dinajpur, 64.29 % were excellent with no unfit sites. For irrigation suitability, Barisal had 75 % excellent and 4.17 % severely affected areas, while 44.44 % excellent and 14.81 % severely affected sites were observed in Dinajpur. Health risk assessment revealed significantly higher Hazard Index (HI) values in Barishal across all age groups compared to Dinajpur, indicating elevated potential health risks in the coastal region. Children were identified as the most vulnerable group, exhibiting higher HI values than males and females in both Barishal (HI = 0.38–57.29) and Dinajpur (HI = 0.34–4.41). The Pearson Correlation analysis indicated that in Dinajpur, environmental variables demonstrated negligible correlations with groundwater quality (WQI: r = –0.18–0.19; IWQI: NDVI r = 0.25, LST r = –0.20). Similarly, Barishal had negligible correlations, with the Water Quality Index (WQI) revealing a little link with NDVI and NDWI, respectively (r = 0.17–0.24), whilst the Integrated Water Quality Index (IWQI) indicated minimal impact across all indices (r = –0.03–0.19). Overall, the study highlights regional variations in groundwater quality and health risks, emphasizing the necessity for location-specific water resource management strategies.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100194"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145841127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Arsenic (As) contamination in groundwater has emerged as a global environmental concern, posing severe metabolic and health hazards to humans. Its widespread occurrence in aquifers, especially across South and Southeast Asia, highlights the growing threat to safe drinking water. While the contamination largely originates from geogenic sources, anthropogenic influences have increasingly contributed to its persistence in the ‘21st century’, according to the recent insights of literature. Present study presents an integrated overview of the chemical profile, sources, and hydrogeochemical behaviour of arsenic in groundwater. It outlines the mobilization mechanisms and summarizes key quantification techniques applied in groundwater studies. A dedicated section addresses the adverse health impacts of arsenic exposure, including major exposure routes, dermatological effects, and systemic disorders. Regional hydrogeology in India demonstrates that Himalayan River systems transport arsenic-bearing minerals downstream, enriching alluvial aquifers and exacerbating contamination. Prolonged exposure leads to skin lesions, pulmonary diseases, and carcinogenic outcomes, posing a major public health burden. The paper further highlights sustainable mitigation strategies such as adsorption, ion exchange, and membrane-based technologies to curb arsenic toxicity. Attaining arsenic-safe groundwater remains a critical challenge; however, sustainable remediation and management practices are pivotal to achieving the United Nations Sustainable Development Goals (SDG-3 and SDG-6), ensuring clean water and good health for all.
{"title":"Arsenic in groundwater: Exploring its origins, human interventions, and sustainable paths forward","authors":"Debojyoti Mishra , Kamalesh Sen , Soumya Kundu , Naba Kumar Mondal","doi":"10.1016/j.clwat.2025.100199","DOIUrl":"10.1016/j.clwat.2025.100199","url":null,"abstract":"<div><div>Arsenic (As) contamination in groundwater has emerged as a global environmental concern, posing severe metabolic and health hazards to humans. Its widespread occurrence in aquifers, especially across South and Southeast Asia, highlights the growing threat to safe drinking water. While the contamination largely originates from geogenic sources, anthropogenic influences have increasingly contributed to its persistence in the ‘21st century’, according to the recent insights of literature. Present study presents an integrated overview of the chemical profile, sources, and hydrogeochemical behaviour of arsenic in groundwater. It outlines the mobilization mechanisms and summarizes key quantification techniques applied in groundwater studies. A dedicated section addresses the adverse health impacts of arsenic exposure, including major exposure routes, dermatological effects, and systemic disorders. Regional hydrogeology in India demonstrates that Himalayan River systems transport arsenic-bearing minerals downstream, enriching alluvial aquifers and exacerbating contamination. Prolonged exposure leads to skin lesions, pulmonary diseases, and carcinogenic outcomes, posing a major public health burden. The paper further highlights sustainable mitigation strategies such as adsorption, ion exchange, and membrane-based technologies to curb arsenic toxicity. Attaining arsenic-safe groundwater remains a critical challenge; however, sustainable remediation and management practices are pivotal to achieving the United Nations Sustainable Development Goals (SDG-3 and SDG-6), ensuring clean water and good health for all.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100199"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145884812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-02-09DOI: 10.1016/j.clwat.2026.100219
Alam S.M. Nur , Souvik Biswas Soumma , Zhumpa Rani Saha , Md. Mahfuzur Rahman , Dipta Das , Mahbub Hasan Rownok , Marzia Sultana , Maria Rhaman Mitu , Tafsir Ahmed Nayef , Md. Tanvir Islam , Sk. Faijus Sadekin , Ashaduzzaman Md.
Hydrogels with enhanced photocatalytic activity have emerged as promising materials for wastewater treatment and antimicrobial applications. Nanocomposite hydrogels were synthesized using zinc oxide, charcoal, and polyacrylic acid (PAA) through free radical polymerization. These hydrogels were tested for their photocatalytic activity by degrading rhodamine B under direct sunlight and UV-Vis irradiation. The prepared samples were characterized using various techniques, including X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), Thermogravimetric Analysis (TGA), and point of zero charge analysis (pHpzc). EDX analysis confirmed the presence of elemental components, while the XRD pattern and FTIR spectrum indicated the successful incorporation of zinc oxide and charcoal into the PAA chains. TGA analysis revealed that the hydrogel containing zinc oxide exhibited better thermal stability than the hydrogel composed solely of charcoal and PAA. SEM imaging showed porous network within the hydrogels. The combination of zinc oxide and charcoal improved electron flow under both sunlight and UV-Vis light, significantly enhancing the degradation of dye molecules. Additionally, the surface functional groups present on the charcoal increased the hydrogel’s dye adsorption capacity. The effectiveness of dye degradation was influenced by factors such as pH, initial dye concentration, and the amount of zinc oxide content in the hydrogel. The hydrogel containing 1 g of zinc oxide achieved a maximum rhodamine B degradation of 78.33 % under sunlight and 92.54 % under UV-Vis irradiation. Furthermore, the hydrogels containing zinc oxide demonstrated strong antibacterial activity against both Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria. The zinc oxide-charcoal-PAA nanocomposite hydrogels exhibited strong antibacterial properties and effective sunlight-driven photocatalytic degradation of dyes, highlighting their potential application in treating textile wastewater.
{"title":"Development of zinc oxide-charcoal-polyacrylic nanocomposite hydrogels for enhanced dye degradation under direct sunlight irradiation and antibacterial applications","authors":"Alam S.M. Nur , Souvik Biswas Soumma , Zhumpa Rani Saha , Md. Mahfuzur Rahman , Dipta Das , Mahbub Hasan Rownok , Marzia Sultana , Maria Rhaman Mitu , Tafsir Ahmed Nayef , Md. Tanvir Islam , Sk. Faijus Sadekin , Ashaduzzaman Md.","doi":"10.1016/j.clwat.2026.100219","DOIUrl":"10.1016/j.clwat.2026.100219","url":null,"abstract":"<div><div>Hydrogels with enhanced photocatalytic activity have emerged as promising materials for wastewater treatment and antimicrobial applications. Nanocomposite hydrogels were synthesized using zinc oxide, charcoal, and polyacrylic acid (PAA) through free radical polymerization. These hydrogels were tested for their photocatalytic activity by degrading rhodamine B under direct sunlight and UV-Vis irradiation. The prepared samples were characterized using various techniques, including X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), Thermogravimetric Analysis (TGA), and point of zero charge analysis (pH<sub>pzc</sub>). EDX analysis confirmed the presence of elemental components, while the XRD pattern and FTIR spectrum indicated the successful incorporation of zinc oxide and charcoal into the PAA chains. TGA analysis revealed that the hydrogel containing zinc oxide exhibited better thermal stability than the hydrogel composed solely of charcoal and PAA. SEM imaging showed porous network within the hydrogels. The combination of zinc oxide and charcoal improved electron flow under both sunlight and UV-Vis light, significantly enhancing the degradation of dye molecules. Additionally, the surface functional groups present on the charcoal increased the hydrogel’s dye adsorption capacity. The effectiveness of dye degradation was influenced by factors such as pH, initial dye concentration, and the amount of zinc oxide content in the hydrogel. The hydrogel containing 1 g of zinc oxide achieved a maximum rhodamine B degradation of 78.33 % under sunlight and 92.54 % under UV-Vis irradiation. Furthermore, the hydrogels containing zinc oxide demonstrated strong antibacterial activity against both Gram-positive (<em>Staphylococcus aureus</em>) and Gram-negative (<em>Escherichia coli</em>) bacteria. The zinc oxide-charcoal-PAA nanocomposite hydrogels exhibited strong antibacterial properties and effective sunlight-driven photocatalytic degradation of dyes, highlighting their potential application in treating textile wastewater.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100219"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-02-14DOI: 10.1016/j.clwat.2026.100222
M.H. Rahaman , Md. Rakibul Islam , Md. Aminur Rahman , Md. Hafizul Islam , Sabrina Afrin , S.M. Nur Alam , Tasrina Rabia Choudhury , M. Safiur Rahman
Heavy metals such as Chromium (Cr) and Cadmium (Cd) are highly toxic elements detected in industrial wastewater. In this work, a bio-based composite adsorbent composed of chitosan (CS) and CS-grafted microcrystalline cellulose (MCC) is utilized for the removal of Cr and Cd from simulated wastewater. CS, MCC, CS grafted MCC (CS-g-MCC), and the CS/CS-g-MCC composite were prepared and inspected using Fourier Transform Infrared spectroscopy (FTIR), Scanning Electron Microscope (SEM), and Wide-angle X-ray diffraction (WAXD) analysis. Metal ion concentrations before and after adsorption by the CS/CS-g-MCC composite were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES), and removal efficiencies for total chromium and cadmium were reported. Batch adsorption experiments were conducted to examine the effects of pH, contact time, adsorbent dosage, and initial metal concentration. The adsorption kinetics were adequately described by the pseudo-second-order model, indicating that chemisorption may contribute to the uptake process. Equilibrium data were analyzed using Langmuir and Freundlich isotherm models to provide comparative insight into adsorption behavior, yielding estimated maximum adsorption capacities of approximately 46 mg/g for CrTotal and 74 mg/g for Cd²⁺ under the tested conditions. Interference studies showed that PO₄³⁻ significantly suppressed CrTotal uptake, while Cd²⁺ adsorption was less affected by competing ions. Regeneration experiments over four adsorption–desorption cycles using (NH₄)₂SO₄ demonstrated reasonable short-term reusability, although gradual performance decline was observed. Overall, the CS/CS-g-MCC composite shows promise as a bio-based adsorbent for heavy-metal removal, while further studies are required to strengthen equilibrium modeling and long-term stability assessment.
铬(Cr)和镉(Cd)等重金属是工业废水中检测到的剧毒元素。利用壳聚糖(CS)和壳聚糖接枝微晶纤维素(MCC)组成的生物基复合吸附剂去除模拟废水中的Cr和Cd。制备了CS、MCC、CS接枝MCC (CS-g-MCC)和CS/CS-g-MCC复合材料,并采用傅里叶变换红外光谱(FTIR)、扫描电镜(SEM)和广角x射线衍射(WAXD)分析对其进行了表征。采用电感耦合等离子体发射光谱法(ICP-OES)测定了CS/CS-g- mcc复合材料吸附前后的金属离子浓度,并报道了对总铬和总镉的去除效率。通过批量吸附实验考察了pH、接触时间、吸附剂用量、初始金属浓度等因素对吸附效果的影响。拟二级吸附模型充分描述了吸附动力学,表明化学吸附可能参与了吸附过程。使用Langmuir和Freundlich等温模型分析平衡数据,以提供对吸附行为的比较了解,得出在测试条件下,CrTotal的最大吸附容量约为46 mg/g, Cd 2⁺的最大吸附容量约为74 mg/g。干扰研究表明,PO₄³⁻能明显抑制CrTotal的摄取,而Cd²⁺的吸附受竞争离子的影响较小。使用(NH₄)2 SO₄进行4次吸附-解吸循环的再生实验表明,尽管性能逐渐下降,但短期内可重复使用。综上所述,CS/CS-g- mcc复合材料有望成为一种去除重金属的生物基吸附剂,但还需要进一步的研究来加强平衡建模和长期稳定性评估。
{"title":"Bio-based chitosan-grafted microcrystalline cellulose as an adsorbent for efficient removal of chromium and cadmium from simulated wastewater","authors":"M.H. Rahaman , Md. Rakibul Islam , Md. Aminur Rahman , Md. Hafizul Islam , Sabrina Afrin , S.M. Nur Alam , Tasrina Rabia Choudhury , M. Safiur Rahman","doi":"10.1016/j.clwat.2026.100222","DOIUrl":"10.1016/j.clwat.2026.100222","url":null,"abstract":"<div><div>Heavy metals such as Chromium (Cr) and Cadmium (Cd) are highly toxic elements detected in industrial wastewater. In this work, a bio-based composite adsorbent composed of chitosan (CS) and CS-grafted microcrystalline cellulose (MCC) is utilized for the removal of Cr and Cd from simulated wastewater. CS, MCC, CS grafted MCC (CS-g-MCC), and the CS/CS-g-MCC composite were prepared and inspected using Fourier Transform Infrared spectroscopy (FTIR), Scanning Electron Microscope (SEM), and Wide-angle X-ray diffraction (WAXD) analysis. Metal ion concentrations before and after adsorption by the CS/CS-g-MCC composite were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES), and removal efficiencies for total chromium and cadmium were reported. Batch adsorption experiments were conducted to examine the effects of pH, contact time, adsorbent dosage, and initial metal concentration. The adsorption kinetics were adequately described by the pseudo-second-order model, indicating that chemisorption may contribute to the uptake process. Equilibrium data were analyzed using Langmuir and Freundlich isotherm models to provide comparative insight into adsorption behavior, yielding estimated maximum adsorption capacities of approximately 46 mg/g for Cr<sup>Total</sup> and 74 mg/g for Cd²⁺ under the tested conditions. Interference studies showed that PO₄³⁻ significantly suppressed Cr<sup>Total</sup> uptake, while Cd²⁺ adsorption was less affected by competing ions. Regeneration experiments over four adsorption–desorption cycles using (NH₄)₂SO₄ demonstrated reasonable short-term reusability, although gradual performance decline was observed. Overall, the CS/CS-g-MCC composite shows promise as a bio-based adsorbent for heavy-metal removal, while further studies are required to strengthen equilibrium modeling and long-term stability assessment.</div></div>","PeriodicalId":100257,"journal":{"name":"Cleaner Water","volume":"5 ","pages":"Article 100222"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}