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Magnetic properties of high-entropy alloy nanostructures: general discussion 高熵合金纳米结构的磁性能:一般讨论。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2026-02-05 DOI: 10.1039/D5FD90065D
Stephan Barcikowski, Brian Cantor, Varun Chaudhary, Sheng Dai, Tushar Gupta, Andrea Kirsch, Tim Kunzmann, Chih-Heng Lee, Alfred Ludwig, Nicola Morley, Alexandre Nominé, Dierk Raabe, Natalia F. Shkodich and Dongsheng Wen
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引用次数: 0
Advanced structural characterization of high-entropy alloy nanostructures: general discussion 高熵合金纳米结构的高级结构表征:一般性讨论。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2026-01-27 DOI: 10.1039/D5FD90064F
Damien Alloyeau, Hakim Amara, Stephan Barcikowski, Florent Calvo, Marta Campolucci, Brian Cantor, Sheng Dai, Arne De Landsheere, Maria Letizia De Marco, Sae Dieb, Alexander S. Eggeman, Jonathan Ruiz Esquius, Andrea Kirsch, Henrik H. Kristoffersen, Syrine Krouna, Chih-Heng Lee, Tong Li, Alfred Ludwig, Jaysen Nelayah, Tobias Mølgaard Nielsen, Micha Polak, Natalia Pukhareva, Jan Rossmeisl, Wolfgang Schuhmann, Conrard Giresse Tetsassi Feugmo, Jyotishraj Thoudam, Michael Widom and Dongshuang Wu
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引用次数: 0
Application of high-entropy alloy nanostructures in electrocatalysis: general discussion 高熵合金纳米结构在电催化中的应用:综述。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2026-01-22 DOI: 10.1039/D5FD90063H
Damien Alloyeau, Stephan Barcikowski, Brian Cantor, Sheng Dai, Sae Dieb, Arne De Landsheere, Maria Letizia De Marco, Alexander S. Eggeman, Henrik H. Kristoffersen, Tim Kunzmann, Chih-Heng Lee, Menglong Liu, Alfred Ludwig, Hossein Mahdavi, Andy Mount, Tobias Mølgaard Nielsen, Micha Polak, Christoph Rehbock, Jan Rossmeisl, Jonathan Ruiz Esquius, Wolfgang Schuhmann, Carsten Schwandt, Anurag Sharma, Natalia F. Shkodich, Robert Stuckert, Conrard Giresse Tetsassi Feugmo, Felix Thelen, Jyotishraj Thoudam and Dongshuang Wu
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引用次数: 0
Synthesizing high-entropy alloy nanoparticles: general discussion 高熵合金纳米颗粒的合成:综述。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2026-01-21 DOI: 10.1039/D5FD90062J
Damien Alloyeau, Hakim Amara, Stephan Barcikowski, Marta Campolucci, Brian Cantor, Varun Chaudhary, Sheng Dai, Arne De Landsheere, Alexander S. Eggeman, Mark Feaviour, Larissa M. Feitosa, Divyansh Gautam, Tushar Gupta, Andrew L. Hector, J. Sharath Kumar, Chih-Heng Lee, Tong Li, Alfred Ludwig, Jette K. Mathiesen, Andrew R. Mount, Megumi Mukoyoshi, Tobias Mølgaard Nielsen, Micha Polak, Christoph Rehbock, Jonathan Ruiz Esquius, Wolfgang Schuhmann, Anurag Sharma, Robert Stuckert, Felix Thelen, Jyotishraj Thoudam and Robert Weatherup
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引用次数: 0
Concluding remarks: Achievements, challenges, and trajectories for high-entropy alloy nanoparticles 结束语:高熵合金纳米颗粒的成就、挑战和发展轨迹。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2026-01-14 DOI: 10.1039/D5FD00123D
Dierk Raabe
<p >The field of high-entropy alloy nanoparticles (HEA-NPs) had to move and indeed has moved beyond the early enthusiasm of simply “mixing five or more elements and hoping the configurational entropy will do some magic” in terms of chemical and physical properties. What the 2025 <em>Faraday Discussion</em> made clear is that, at the nanoscale, entropy is often a minor player. Phase stability, structure, and functional properties are instead dominated by kinetics, surface reconstruction, defects, segregation, decomposition, and – more often than we like to admit – (unnoticed) interstitial contamination (C, O, N, H, B, S) picked up during synthesis and during particle exposure to “real-world” environments. Bulk HEAs can still “hide” a bit behind their mostly metastable single-phase character and complex diffusion mechanisms, and often even exploit these features to their advantage, but nanoparticles have no such luxury. Their huge surface-to-volume ratio, rapid synthesis pathways, and exposure to harsh operational environments reveal the true thermodynamic and kinetic transient features of most reported compositions. We see decomposition, demixing, surface reconstruction, and dynamic ensemble behaviour that have in part little to do with the ideal solid-solution picture painted a decade ago. These profound differences between bulk HEAs and nanosized ones provide opportunities to be embraced and exploited for well-targeted and theory-guided development steps. The community therefore should feel encouraged to pivot. Instead of chasing ever more complex average compositions, we must focus on what really governs the usually transient features and stability of these particles, particularly at the surface and their dynamical states in real environments, and how we can deliberately exploit kinetic barriers, short-range ordering, defects and their chemical decoration, and surface dynamics to achieve emergent properties unattainable in conventional nanoscale alloys. Theory and simulation must leave the <em>O</em>(<em>N</em><small><sup>3</sup></small>) constraints of traditional DFT behind and embrace large-scale, accurate machine-learning potentials and property-driven screening of the astronomical configuration space. Synthesis has to become far more chemically aware and reproducible, with rigorous control (and transparent reporting) of interstitials, decomposition and decay kinetics when the particles are used. And finally, functional validation can no longer rely on post-mortem snapshots; we need genuine <em>operando</em> insight into displaced reaction features, ordering, dynamical reconstruction, composition, and dynamics of those atomic clusters that actually do the catalytic or magnetic work. If we accept that HEA nanoparticles are inherently kinetically highly variable, defect-rich, surface-dominated objects, then more adequate design metrics need to be found, going beyond the so far primarily used single mean-field metric of configurational (bulk)
高熵合金纳米颗粒(HEA-NPs)领域必须改变,而且确实已经超越了早期的热情,即简单地“混合五种或五种以上的元素,希望构型熵能在化学和物理性质方面创造一些奇迹”。2025年的法拉第讨论清楚地表明,在纳米尺度上,熵通常是一个次要角色。相反,相稳定性、结构和功能特性主要受动力学、表面重构、缺陷、偏析、分解以及(通常比我们愿意承认的)在合成和粒子暴露于“现实世界”环境中获得的(未被注意到的)间隙污染(C、O、N、H、B、S)的影响。大块HEAs仍然可以“隐藏”在它们大部分亚稳的单相特性和复杂的扩散机制背后,甚至经常利用这些特性来发挥它们的优势,但纳米颗粒没有这样的奢侈。它们巨大的表面体积比,快速的合成途径,以及暴露在恶劣的操作环境中,揭示了大多数已报道的组合物的真实热力学和动力学瞬态特征。我们看到的分解、解混、表面重建和动态系综行为,在一定程度上与十年前描绘的理想固溶体图景没有什么关系。大块HEAs和纳米级HEAs之间的这些深刻差异为有针对性和理论指导的开发步骤提供了机会。因此,应该鼓励社区转向。与其追求更复杂的平均成分,我们必须专注于真正控制这些颗粒的通常瞬态特征和稳定性的因素,特别是在真实环境中的表面和它们的动态状态,以及我们如何有意识地利用动力学障碍、短程有序、缺陷及其化学修饰和表面动力学来实现传统纳米级合金无法实现的新特性。理论和模拟必须摆脱传统DFT的0 (N3)约束,并拥抱大规模、准确的机器学习潜力和属性驱动的天文构型空间筛选。合成必须变得更加具有化学意识和可重复性,并在使用颗粒时对间隙、分解和衰变动力学进行严格控制(和透明报告)。最后,功能验证不能再依赖于事后快照;我们需要对置换反应的特征,排序,动态重建,组成,以及那些实际起催化或磁性作用的原子团簇的动力学有真正的歌剧般的洞察力。如果我们接受HEA纳米颗粒本质上是动力学高度可变的、缺陷丰富的、表面主导的物体,那么就需要找到更充分的设计指标,而不是迄今为止主要使用的单一平均场构型(体积)熵指标。这可能为真正的纳米粒子多功能性和现实世界的稳定性开辟一条更系统、更现实、更全面的设计途径。在2025年法拉第讨论会上发表的论文表明,沿着这条路线发展的机会可能潜伏在磁性活性催化剂、贵金属贫电催化剂或集耐腐蚀性、热稳定性和高活性于一体的材料领域。前面的道路是艰巨的,但更可持续的催化和磁性应用的潜在回报是很高的。这可以归结为,现在是时候停止将高熵纳米粒子仅仅视为“小型化”的体HEAs,而开始将它们视为真正迷人的新材料了。
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引用次数: 0
Commercially available technical lignins: general discussion 市售技术木质素:一般性讨论。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2026-01-02 DOI: 10.1039/D5FD90058A
Nassim Afiouni, Amponsah Preko Appiah, Katalin Barta, Veronica Calado, Claudia Crestini, Peter J. Deuss, Matteo Gigli, Chamseddine Guizani, Fatima Ezzahra Khallouk, Wojciech Krasodomski, Heiko Lange, Jean-Pierre Lindner, Pia Löser, Michelle Muzzio, Mojgan Nejad, Antonio Ovejero-Pérez, Arulselvan Ponnudurai, Semiu Abolore Rasaq, Camila A. Rezende, Roberto Rinaldi, Joseph S. M. Samec, Philipp Schäfer, Sibylle M. K. Schwartmann, Seema Singh, Nicholas J. Westwood, Malin Wohlert, Natasha Wrathall, Yulun Zheng and Shida Zuo
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引用次数: 0
Preface: High-entropy alloy nanostructures: from theory to application 前言:高熵合金纳米结构:从理论到应用。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2025-12-23 DOI: 10.1039/D5FD90050F
Jette Katja Mathiesen and Stephan Barcikowski

Few areas of materials science have evolved as rapidly and dynamically as high-entropy alloys (HEAs). What began just two decades ago as a bold idea – first articulated by Brian Cantor and Jien-Wei Yeh – that chemical complexity itself could stabilise materials, has grown into a thriving research field spanning structural, functional, and catalytic applications. The Faraday Discussions ‘High-entropy alloy nanostructures: from theory to application’, held at the Royal Society of Chemistry in London, brought together researchers from across the world to examine a fundamental question at the heart of this concept: with multicomponent alloys now within reach, do they truly deliver beyond simpler systems, or does complexity risk obscuring purpose?

材料科学中很少有领域像高熵合金(HEAs)那样发展得如此迅速和动态。20年前,Brian Cantor和Jien-Wei Yeh首先提出了一个大胆的想法,即化学复杂性本身可以稳定材料,现在已经发展成为一个跨越结构、功能和催化应用的蓬勃研究领域。在伦敦皇家化学学会举行的法拉第讨论“高熵合金纳米结构:从理论到应用”汇集了来自世界各地的研究人员来研究这个概念核心的一个基本问题:随着多组分合金现在已经可以实现,它们是否真的能超越更简单的系统,或者复杂性是否会掩盖目的?
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引用次数: 0
Strategies for compatibilisation of extracted lignin properties with commercial applications: general discussion 萃取木质素特性与商业应用的相容性策略:一般讨论。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2025-12-22 DOI: 10.1039/D5FD90059J
Agnieszka Brandt-Talbot, Veronica Calado, Isaac Castellan, Claudia Crestini, Luigi Galluccio, Matteo Gigli, Chamseddine Guizani, Yevgen Karpichev, Heiko Lange, Jean-Pierre Lindner, Mojgan Nejad, Verónica Nicolau, Arulselvan Ponnudurai, Narayanan Rajagopalan, Roberto Rinaldi, Joseph S. M. Samec, Michael Schroeter, Nicholas J. Westwood, Malin Wohlert and Yulun Zheng
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引用次数: 0
Lignin stabilisation and degradation in lignocellulosic fractionation processes: general discussion 木质纤维素分馏过程中木质素的稳定和降解:一般讨论。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2025-12-18 DOI: 10.1039/D5FD90057C
Nassim Afiouni, Amponsah Preko Appiah, Katalin Barta, Agnieszka Brandt-Talbot, Veronica Calado, Isaac Castellan, Claudia Crestini, André M. da Costa Lopes, Peter J. Deuss, Luigi Galluccio, Matteo Gigli, Chamseddine Guizani, Cynthia Syn Yi Hu, Martin Klajmon, Heiko Lange, Jean-Pierre Lindner, Mojgan Nejad, Arulselvan Ponnudurai, Semiu Abolore Rasaq, Camila Alves Rezende, Roberto Rinaldi, Joseph S. M. Samec, Sibylle M. K. Schwartmann, Massimo Sgarzi, Seema Singh, Raphaela Süss, Nicholas J. Westwood and Ling-Ping Xiao
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引用次数: 0
Native lignin solvation and extraction: general discussion 天然木质素的溶剂化和萃取:一般讨论。
IF 3.1 3区 化学 Q2 Chemistry Pub Date : 2025-12-18 DOI: 10.1039/D5FD90056E
Nassim Afiouni, Amponsah Preko Appiah, Dimitris S. Argyropoulos, Agnieszka Brandt-Talbot, Pieter C. A. Bruijnincx, Veronica Calado, Claudia Crestini, André M. da Costa Lopes, Peter J. Deuss, Lucie Diéval, Juan C. Domínguez, Thomas Elder, Luigi Galluccio, Matteo Gigli, Chamseddine Guizani, Martin Klajmon, Wojciech Krasodomski, Heiko Lange, Jean-Pierre Lindner, Zixuan Liu, Jessica Luzardo, Mojgan Nejad, Arulselvan Ponnudurai, Narayanan Rajagopalan, Semiu Abolore Rasaq, Roberto Rinaldi, Joseph S. M. Samec, Massimo Sgarzi, Seema Singh, Nicholas J. Westwood and Malin Wohlert
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引用次数: 0
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Faraday Discussions
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