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Water corrosion behavior of CLF-1 steel in Experimental Advanced Superconducting Tokamak (EAST) magnetic field environment CLF-1钢在实验先进超导托卡马克(EAST)磁场环境中的水腐蚀行为
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-06-10 DOI: 10.1016/j.nme.2026.102158
Shu-Feng Zhang , Yi-Ming Lyu , Ye Li , Shang-Ming Chen , Lei Peng , Ming Wang , Shan-Liang Zheng
The magnetic field environment influences both the corrosion characteristics of metallic materials in water and the transport processes of corrosion products. Fusion reactor magnetic fields, characterized by their high strength and unique configuration, necessitate an evaluation of their impact on the corrosion of structural materials, particularly the piping materials in water-cooled blanket systems. Such evaluation is essential for investigating the generation, transport, and distribution mechanisms of activated corrosion products and for ensuring the safe operation of fusion reactors. In the absence of an operating fusion reactor, water corrosion experiments can be conducted within the magnetic field of a Tokamak device with a similar configuration to mimic and study these mechanisms. In this work, corrosion experiments were performed on CLF-1 steel in a solution of 1 wt% H2O2 + 0.1 wt% NaCl for durations of 2 h, 12 h, and 24 h under the magnetic field environment of the EAST (Experimental Advanced Superconducting Tokamak). Comparative experiments were conducted without a magnetic field. The localized corrosion of CLF-1 steel in solution and the general corrosion in pressurized water both fall under electrochemical corrosion. This model experiment will provide a reference for the study of corrosion products in fusion reactors. Analysis of the sample morphology and corrosion products composition revealed that under the EAST magnetic field, the corrosion products around corrosion pits tended to exhibit a nearly circular distribution on the sample surface, whereas in the absence of the field, the corrosion products showed a striated distribution. The magnetic field distribution at the C-port of the EAST device, where the samples were located, was simulated using ANSYS software. The simulation indicated that the magnetic field at the C-port is predominantly toroidal, and its direction during the corrosion experiments was nearly perpendicular to the sample surface. These results suggest that the Lorentz force and the magnetic gradient force induced by the EAST magnetic field alter the migration of ions and paramagnetic substances, respectively, thereby modifying the distribution characteristics of the corrosion products.
磁场环境既影响金属材料在水中的腐蚀特性,也影响腐蚀产物的输运过程。核聚变反应堆磁场以其高强度和独特的形态为特点,有必要对其对结构材料腐蚀的影响进行评估,特别是对水冷毯系统中管道材料的腐蚀。这种评估对于研究活性腐蚀产物的产生、传输和分布机制以及确保聚变反应堆的安全运行是必不可少的。在没有核聚变反应堆运行的情况下,可以在具有类似配置的托卡马克装置的磁场中进行水腐蚀实验,以模拟和研究这些机制。在这项工作中,在EAST(实验先进超导托卡马克)的磁场环境下,对CLF-1钢在1wt % H2O2 + 0.1 wt% NaCl的溶液中进行了2小时、12小时和24小时的腐蚀实验。对比实验在没有磁场的情况下进行。CLF-1钢在溶液中的局部腐蚀和在加压水中的一般腐蚀都属于电化学腐蚀。该模型实验将为聚变反应堆腐蚀产物的研究提供参考。对样品形貌和腐蚀产物组成的分析表明,在EAST磁场作用下,腐蚀坑周围的腐蚀产物在样品表面呈近圆形分布,而在无磁场作用下,腐蚀产物呈条状分布。利用ANSYS软件模拟了样品所在的EAST装置c口的磁场分布。模拟结果表明,c口处的磁场以环形为主,且在腐蚀实验过程中磁场方向几乎垂直于试样表面。这些结果表明,东磁场诱导的洛伦兹力和磁梯度力分别改变了离子和顺磁性物质的迁移,从而改变了腐蚀产物的分布特征。
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引用次数: 0
Dissolution of unirradiated MOX fuel in the presence of magnetite and chukanovite 未辐照的MOX燃料在磁铁矿和楚卡云母存在下的溶解
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-05-26 DOI: 10.1016/j.nme.2026.102148
M. Saleh , E. Darwish , M. Hedberg , P.L. Tam , K. Spahiu , C. Ekberg
In all European concepts for deep geological repositories of spent nuclear fuel, massive canisters with cast iron inserts are designed to prevent early interaction between the spent nuclear fuel and groundwater. Should a canister breach occur, corrosion of the fuel would take place at repository depths of several hundred meters where the surrounding groundwater is generally anoxic. The radiation field surrounding the fuel alters local redox conditions through water radiolysis. Under such conditions, fuel corrosion is anticipated to proceed simultaneously with anoxic iron corrosion. When all iron is corroded, iron corrosion products will be present for very long times in the near field of a repository and thus buffer the redox conditions in the near field. By using a MOX fuel pellet with an extremely high alpha field, we can test the effects of iron corrosion products on fuel dissolution considering that the very old fuel they will contact in the repository has orders of magnitude lower alpha dose rates.
In this study, two leaching experiments were conducted on unirradiated MOX fuel pellets containing 10 wt% plutonium (specific alpha activity: 1.79 GBq/g) under an argon atmosphere in simulated granitic groundwater representative of the Forsmark site in Sweden. The experiments were performed in the presence of magnetite and synthesized chukanovite to assess their influence on the corrosion and leaching behaviour of the unirradiated MOX fuel. A strong inhibiting effect on fuel dissolution was noted for chukanovite, while magnetite could not counteract the radiolytic dissolution of the unirradiated MOX pellet.
在欧洲所有关于乏核燃料深层地质储存库的概念中,设计了带有铸铁嵌套的巨大罐,以防止乏核燃料与地下水之间的早期相互作用。如果储罐破裂,燃料的腐蚀将发生在储存库几百米深的地方,那里周围的地下水通常是缺氧的。燃料周围的辐射场通过水的辐射分解改变了局部氧化还原条件。在这种条件下,预计燃料腐蚀与缺氧铁腐蚀同时进行。当所有铁都被腐蚀时,铁腐蚀产物将在储存库的近场存在很长时间,从而缓冲近场的氧化还原条件。通过使用具有极高α场的MOX燃料球团,我们可以测试铁腐蚀产物对燃料溶解的影响,考虑到它们将在储存库中接触的非常旧的燃料具有低几个数量级的α剂量率。在这项研究中,对含有10 wt%钚(比α活度:1.79 GBq/g)的未辐照MOX燃料颗粒在氩气气氛下在瑞典Forsmark遗址的模拟花岗岩地下水中进行了两次浸出实验。实验在磁铁矿和合成楚卡云母存在的情况下进行,以评估它们对未辐照的MOX燃料的腐蚀和浸出行为的影响。楚卡云母对燃料溶解有较强的抑制作用,而磁铁矿不能抵消未辐照的MOX球团的放射性溶解。
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引用次数: 0
Change of the Bidirectional Reflectance Distribution Function for the Metal First Wall exposed in EAST 东暴露金属首壁双向反射分布函数的变化
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-05-15 DOI: 10.1016/j.nme.2026.102141
Yefan Zhu , Rong Yan , Chuannan Xuan , Yuming Liu , Zhaohui Wang , Lei Mu , Wei Zheng , Shumei Xiao , Zengjie Li , Chunyu He , Junling Chen , Pengfei Zi
Optical diagnostics is an important method for obtaining basic parameters and operational conditions of the plasma in the tokamak. The bidirectional reflectance distribution function (BRDF) of the wall will have a degradation during the plasma experiment, which will then affect the signal-to-noise ratio of optical diagnostics. Studying the BRDF change of the metal first wall could help to understand the change of wall reflection level and its possible influence on optical diagnostics. Two molybdenum-titanium-zirconium (TZM) first wall tiles with different levels of impurity deposition after exposure in EAST for one experimental campaign operation were analyzed. The surface morphology and elemental composition were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray Photoelectron Spectroscopy (XPS). The BRDF value of the samples was also measured. The results show that after about 7426 plasma pulses, the peak BRDF value of the material decreased by about two orders of magnitude, and the BRDF curve exhibits asymmetry about the specular direction. The SEM observations showed that the microscopic spherical-like structures of the deposited layer are responsible for the shadowing and masking effects, thus accounting for the asymmetry observed in the BRDF curve. The EDS results indicated that the introduction of non-metallic components within the deposition layer will introduce the degradation of the BRDF value. These findings provide valuable references for analyzing wall reflectance behavior in EAST and other tokamaks.
光学诊断是获得托卡马克等离子体基本参数和运行条件的重要手段。等离子体实验过程中,壁的双向反射分布函数(BRDF)会发生衰减,从而影响光学诊断的信噪比。研究金属第一壁的BRDF变化有助于了解壁反射水平的变化及其对光学诊断的可能影响。分析了两种不同程度的钼钛锆(TZM)首墙砖在EAST暴露后的杂质沉积情况。采用扫描电镜(SEM)、x射线能谱(EDS)和x射线光电子能谱(XPS)对其表面形貌和元素组成进行了表征。测定了样品的BRDF值。结果表明,经过7426次等离子体脉冲后,材料的峰值BRDF值下降了约2个数量级,BRDF曲线在镜面方向上呈现不对称性。SEM观察表明,沉积层的微观球形结构是遮蔽和遮蔽效应的原因,从而解释了BRDF曲线中观察到的不对称性。EDS结果表明,在沉积层内引入非金属成分会导致BRDF值的降低。这些发现为分析EAST和其他托卡马克的壁面反射特性提供了有价值的参考。
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引用次数: 0
Analytical description of the creep rate of zirconium alloys under irradiation 辐照下锆合金蠕变速率的解析描述
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-05-29 DOI: 10.1016/j.nme.2026.102149
Andrew Rusinko
This paper presents a mathematical model for irradiation creep in zirconium alloys. The model is based on the Synthetic Theory of irreversible deformation. By analyzing the mechanisms governing time‑dependent deformation under irradiation at temperatures where thermal creep is only weakly expressed, a new term that accounts for the influence of flux on the steady‑state creep rate is introduced into the basic equations of the Synthetic Theory. As an example, diagrams are constructed for the steady‑state creep of a zirconium alloy as a function of applied stress at different temperatures and irradiation fluxes. The modeled curves, which agree well with the experimental data, show, in particular, that the irradiation creep rate is lower than the corresponding thermal creep rate at high stresses.
本文建立了锆合金辐照蠕变的数学模型。该模型基于不可逆变形综合理论。通过分析在热蠕变仅弱表达的温度下辐照下随时间变形的控制机制,在综合理论的基本方程中引入了一个解释通量对稳态蠕变速率影响的新术语。作为一个例子,构建了锆合金在不同温度和辐照通量下作为外加应力函数的稳态蠕变图。模型曲线与实验数据吻合较好,特别是在高应力下,辐照蠕变速率低于相应的热蠕变速率。
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引用次数: 0
Steam oxidation of 316Nb Stainless-Steel from 850°C to 1350°C: kinetics and thermodynamic analysis 316Nb不锈钢从850°C到1350°C的蒸汽氧化:动力学和热力学分析
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-05-23 DOI: 10.1016/j.nme.2026.102144
M. Barrachin , S. Guilbert , L. Laborde , P. Lacôte , A. Viretto
This paper presents a comprehensive study on the steam oxidation behaviour of 316Nb stainless steel at temperatures ranging from 850°C to 1350°C. The oxidation process formed complex, multilayered scales on the 316Nb samples. The outermost layer, primarily composed of iron oxides (magnetite and wüstite), was non-adherent and brittle. At temperatures above 1150°C, an intermediate layer containing oxygen, iron, and chromium was observed. The innermost layer exhibited a porous, fine-grained structure of oxidic particles embedded in a metallic Fe-Ni matrix. The oxidation kinetics can be approximated by a parabolic law after an initial incubation period, with 316Nb demonstrating superior resistance to steam oxidation compared to 304L stainless steel below 1200°C. Above this temperature, both alloys exhibited similar oxidation behaviour. A key insight from this study is the absence of catastrophic oxidation in 316Nb, despite its significant molybdenum content.
本文对316Nb不锈钢在850 ~ 1350℃温度范围内的蒸汽氧化行为进行了全面研究。氧化过程在316Nb样品上形成复杂的多层鳞片。最外层主要由氧化铁(磁铁矿和钨铁铁矿)组成,不粘附且易碎。在1150°C以上的温度下,观察到含有氧、铁和铬的中间层。最内层呈现出嵌入金属Fe-Ni基体的多孔、细粒氧化颗粒结构。在初始潜伏期后,氧化动力学可以近似为抛物线定律,在1200°C以下,与304L不锈钢相比,316Nb表现出更强的抗蒸汽氧化能力。在此温度以上,两种合金表现出相似的氧化行为。这项研究的一个关键见解是,尽管316Nb的钼含量很高,但它没有发生灾难性氧化。
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引用次数: 0
Assessment of interatomic potentials for 1/2 <111> screw dislocation properties in tungsten and molybdenum 钨和钼中1/2螺位错性质的原子间电位评价
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-06-03 DOI: 10.1016/j.nme.2026.102151
Wei-shu Yang , Chang-jie Ding , Zi-qiang Wang , Xiao-lin Li , Xiang-yan Li , Yan-ge Zhang , Yi-chun Xu , C.S. Liu , Xuebang Wu
In this work, we systematically evaluated 27 W and 19 Mo interatomic potentials focusing on bulk and screw dislocation properties. The bulk properties primarily include: elastic constants, bulk modulus, shear modulus, Poisson’s ratio, and stacking fault energy; and the screw dislocation properties mainly consist of: differential displacement map of core structure, Peierls energy barrier, and Peierls stress. We identified six W potentials and three Mo potentials that are suitable for screw dislocation simulations. The computational efficiency of these selected potentials was subsequently benchmarked. Finally, considering both accuracy and computational efficiency, we employed three representative interatomic potentials to investigate the effect of temperature on screw dislocation motion. The critical resolved shear stress for dislocation motion decreases with increasing temperature and is accompanied by enhanced cross-slip propensity. This work offers a reference for selecting appropriate interatomic potentials in molecular dynamics simulations to investigate screw dislocation properties in W and Mo.
在这项工作中,我们系统地评估了27w和19mo原子间电位,重点是体积和螺位错性质。体性能主要包括:弹性常数、体模量、剪切模量、泊松比和层错能;螺位错性能主要包括:芯结构的微分位移图、Peierls能垒和Peierls应力。我们确定了适合螺位错模拟的6个W势和3个Mo势。随后对这些选定电位的计算效率进行基准测试。最后,考虑到精度和计算效率,我们采用三个具有代表性的原子间势来研究温度对螺位错运动的影响。位错运动的临界分解剪应力随温度的升高而减小,并伴有交叉滑移倾向的增强。这为在分子动力学模拟中选择合适的原子间势来研究W和Mo的螺位错特性提供了参考。
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引用次数: 0
Corrigendum to “Measurement of residual stresses in surrogate coated nuclear fuel particles using ring-core focussed ion beam digital image correlation” [Nucl. Mater. Energy 36 (2023) 101470] “用环核聚焦离子束数字图像相关法测量替代包覆核燃料颗粒中的残余应力”的勘误表[核]。板牙。能源36 (2023)101470]
IF 2.8 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-03-26 DOI: 10.1016/j.nme.2026.102108
Alexander J. Leide, Thomas A. Haynes, Nassia Tzelepi, John Payne, Matthew Jordan, Steven Knol, Jan A. Vreeling, Mark Davies, David T. Goddard, Manuel J. Pfeifenberger, Markus Alfreider, Daniel Kiener, Dong Liu
{"title":"Corrigendum to “Measurement of residual stresses in surrogate coated nuclear fuel particles using ring-core focussed ion beam digital image correlation” [Nucl. Mater. Energy 36 (2023) 101470]","authors":"Alexander J. Leide,&nbsp;Thomas A. Haynes,&nbsp;Nassia Tzelepi,&nbsp;John Payne,&nbsp;Matthew Jordan,&nbsp;Steven Knol,&nbsp;Jan A. Vreeling,&nbsp;Mark Davies,&nbsp;David T. Goddard,&nbsp;Manuel J. Pfeifenberger,&nbsp;Markus Alfreider,&nbsp;Daniel Kiener,&nbsp;Dong Liu","doi":"10.1016/j.nme.2026.102108","DOIUrl":"10.1016/j.nme.2026.102108","url":null,"abstract":"","PeriodicalId":56004,"journal":{"name":"Nuclear Materials and Energy","volume":"47 ","pages":"Article 102108"},"PeriodicalIF":2.8,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148539540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of tensile behavior of additive manufacturing Z2CN19-10 steel via single-stress small punch test 增材制造Z2CN19-10钢单应力小冲孔拉伸性能研究
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-06-04 DOI: 10.1016/j.nme.2026.102155
Yaxin Li , Rongcheng Wang , Huan Sheng Lai , Huanchun Wu , Sixiong Zeng , Quan Wen
With the advancement of wire arc additive manufacturing (WAAM) technology, the use of WAAM materials has become increasingly widespread. However, these materials normally exhibit anisotropic characteristics, which pose significant challenges in the examination of their mechanical properties due to the limited volume of material available in some cases. Z2CN19-10 is newly developed to prevent corrosion cracking in nuclear power plants. This study investigated the tensile behavior of WAAM Z2CN19-10 steel using uniaxial tensile tests (UTTs), small punch tests (SPTs), and single-stress small punch tests (SS-SPTs). Additionally, the microstructure was characterized using metallographic microscopy (MM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The UTT results indicated that WAAM Z2CN19-10 steel exhibited significantly anisotropic in tensile elongation. Relationships between UTT and SS-SPT results were established to determine the tensile properties of WAAM Z2CN19-10 steel via SS-SPTs. Fracture surface analysis revealed that the morphologies of UTT and SPT specimens displayed distinctly different characteristics, while similarities were observed between UTT and SS-SPT specimens.
随着电弧增材制造(WAAM)技术的进步,WAAM材料的应用越来越广泛。然而,这些材料通常表现出各向异性的特性,这在某些情况下,由于可用材料的数量有限,对其机械性能的检查构成了重大挑战。Z2CN19-10是为防止核电站腐蚀开裂而新开发的。本研究采用单轴拉伸试验(UTTs)、小冲孔试验(SPTs)和单应力小冲孔试验(SS-SPTs)研究了WAAM Z2CN19-10钢的拉伸行为。利用金相显微镜(MM)、扫描电镜(SEM)和电子背散射衍射(EBSD)对其微观结构进行了表征。UTT结果表明,WAAM Z2CN19-10钢的拉伸伸长率具有明显的各向异性。建立了UTT和SS-SPT结果之间的关系,通过SS-SPT测定WAAM Z2CN19-10钢的拉伸性能。断口形貌分析表明,UTT和SPT试样的形貌特征明显不同,而UTT和SS-SPT试样具有相似性。
{"title":"Investigation of tensile behavior of additive manufacturing Z2CN19-10 steel via single-stress small punch test","authors":"Yaxin Li ,&nbsp;Rongcheng Wang ,&nbsp;Huan Sheng Lai ,&nbsp;Huanchun Wu ,&nbsp;Sixiong Zeng ,&nbsp;Quan Wen","doi":"10.1016/j.nme.2026.102155","DOIUrl":"10.1016/j.nme.2026.102155","url":null,"abstract":"<div><div>With the advancement of wire arc additive manufacturing (WAAM) technology, the use of WAAM materials has become increasingly widespread. However, these materials normally exhibit anisotropic characteristics, which pose significant challenges in the examination of their mechanical properties due to the limited volume of material available in some cases. Z2CN19-10 is newly developed to prevent corrosion cracking in nuclear power plants. This study investigated the tensile behavior of WAAM Z2CN19-10 steel using uniaxial tensile tests (UTTs), small punch tests (SPTs), and single-stress small punch tests (SS-SPTs). Additionally, the microstructure was characterized using metallographic microscopy (MM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The UTT results indicated that WAAM Z2CN19-10 steel exhibited significantly anisotropic in tensile elongation. Relationships between UTT and SS-SPT results were established to determine the tensile properties of WAAM Z2CN19-10 steel via SS-SPTs. Fracture surface analysis revealed that the morphologies of UTT and SPT specimens displayed distinctly different characteristics, while similarities were observed between UTT and SS-SPT specimens.</div></div>","PeriodicalId":56004,"journal":{"name":"Nuclear Materials and Energy","volume":"47 ","pages":"Article 102155"},"PeriodicalIF":2.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148241469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental evaluation of magnetic shielding effectiveness in strong static magnetic fields 强静态磁场下磁屏蔽效能的实验评价
IF 2.7 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 DOI: 10.1016/j.nme.2026.102147
Th. Wegner, C. von Sehren, T. Przykopp, W7-X Team
Magnetic shielding is crucial for the reliable operation of electronic and electromechanical components in environments with strong magnetic fields. In this work, the shielding performance of ferromagnetic materials is experimentally investigated for static magnetic fields in the range of 20 to 150 mT. Motivated by the extension of the laser blow-off system at the Wendelstein 7-X stellarator, systematic measurements are carried out to examine the influence of material type, thickness and orientation relative to the external magnetic field. Cuboid-shaped enclosures made of pure iron and high-permeability metal with thicknesses between 3 mm and 6 mm are studied. Mu-metal provides superior shielding at low field strengths below approximately 70 mT, while pure iron exhibits better performance at higher fields. Increasing material thickness and employing multiple layers enhance shielding effectiveness across the entire field range. Under optimized conditions, a reduction of the external magnetic field by up to 75% is achieved.
磁屏蔽对于电子和机电元件在强磁场环境中可靠运行至关重要。本文通过实验研究了铁磁材料在20 ~ 150mt静磁场下的屏蔽性能。在Wendelstein 7-X仿星器激光吹散系统的扩展推动下,进行了系统的测量,研究了材料类型、厚度和相对于外磁场的方向对屏蔽性能的影响。研究了由纯铁和高渗透性金属制成的长方体外壳,厚度在3毫米到6毫米之间。在约70 mT以下的低场强下,金属钼具有优越的屏蔽性能,而纯铁在高场强下具有更好的屏蔽性能。增加材料厚度和采用多层增强屏蔽效能在整个领域范围内。在优化条件下,外部磁场减少了75%。
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引用次数: 0
Research on the migration behavior of corrosion products of CLF-1 steel in magnetic fields CLF-1钢腐蚀产物在磁场中的迁移行为研究
IF 2.8 2区 物理与天体物理 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2026-06-01 Epub Date: 2026-06-11 DOI: 10.1016/j.nme.2026.102160
Yuxin Xiao, Yi-Ming Lyu, Ye Li, Ning Liu, Jiejie Li, Shu-Feng Zhang, Shan-Liang Zheng
CLF-1 steel, a candidate material for cooling water pipes in fusion reactors, is not only corroded by cooling water producing corrosion products (CPs), but is also exposed to strong magnetic fields during service. Activated corrosion products (ACPs) are formed when CPs are irradiated by neutrons. ACPs are among the most serious sources of radiation risk. Strong magnetic fields in fusion reactors may affect the migration behavior of these ACPs, making the safety assessment of fusion reactors more challenging. The aim of this work is therefore to investigate the migration behavior of the corrosion products of CLF-1 steel in magnetic fields. To obtain the corrosion products, corrosion experiments were performed in a solution of 1 wt% H2O2 and 0.1 wt% NaCl for 24 h. Migration experiments were performed on the corrosion products at different magnetic field strengths. The influence of magnetic fields on the migration behavior of corrosion products was experimentally observed for the first time. The XRD analysis reveals that the CPs are mixtures of multiple components. The same migration experiments were further performed for each of the main components of the corrosion products. The results indicate that, in the range of 200–1000 Gs, regarding quantity and migration distance of particles affected by the magnetic fields, Fe3O4 is the largest; in the range of 3000–8000 Gs, the quantity and migration distance of the particles affected by the magnetic fields, from highest to lowest, is FeCr2O4 > CPs > Fe2O3 > Cr2O3, and the migration direction is mainly determined by the magnetic field gradient. In order to reveal the physical mechanism behind this phenomenon, the magnetic behaviors of corrosion products and the main components of the corrosion products were analyzed with a vibrating sample magnetometer. Analysis of the magnetization versus applied magnetic field curves indicates that the quantity and migration distance of the migrating particles affected by magnetic fields are positively correlated with their magnetization under the same magnetic field conditions. At 300 K, the magnetic response of the corrosion products exhibits weak ferromagnetism. The initial magnetic susceptibility of the corrosion products is higher than that of Fe2O3 and FeCr2O4 due to the presence of Fe3O4. In this study, the migration of reduced activation steel corrosion products affected by the magnetic fields was observed for the first time. Future work should further focus on the migration behavior of corrosion products in the actual magnetic fields of fusion reactors, which is important for the safety assessment of activated corrosion products in the fusion reactor environments.
CLF-1钢是核聚变反应堆冷却水管道的候选材料,它不仅会受到冷却水产生的腐蚀产物(CPs)的腐蚀,而且在使用过程中还会暴露在强磁场中。活化腐蚀产物(ACPs)是由中子照射CPs形成的。acp是最严重的辐射危险源之一。核聚变反应堆中的强磁场可能影响这些acp的迁移行为,使核聚变反应堆的安全性评估更具挑战性。因此,本工作的目的是研究CLF-1钢的腐蚀产物在磁场中的迁移行为。为了获得腐蚀产物,在1 wt% H2O2和0.1 wt% NaCl的溶液中进行腐蚀实验,并对腐蚀产物在不同磁场强度下进行迁移实验。本文首次通过实验观察了磁场对腐蚀产物迁移行为的影响。XRD分析表明,CPs是多种组分的混合物。对腐蚀产物的每个主要组分进一步进行了相同的迁移实验。结果表明:在200 ~ 1000 g范围内,受磁场影响的粒子数量和迁移距离以Fe3O4最大;在3000 ~ 8000gs范围内,受磁场影响颗粒的数量和迁移距离由高到低依次为FeCr2O4 >; CPs > Fe2O3 > Cr2O3,迁移方向主要由磁场梯度决定。为了揭示这一现象背后的物理机制,利用振动样品磁强计分析了腐蚀产物和腐蚀产物主要成分的磁性行为。磁化强度与外加磁场曲线的分析表明,在相同的磁场条件下,受磁场影响的迁移颗粒的数量和迁移距离与其磁化强度呈正相关。在300 K时,腐蚀产物的磁响应表现为弱铁磁性。由于Fe3O4的存在,腐蚀产物的初始磁化率高于Fe2O3和FeCr2O4。本研究首次观察到磁场对还原活化钢腐蚀产物迁移的影响。今后的工作应进一步关注腐蚀产物在聚变反应堆实际磁场中的迁移行为,这对聚变反应堆环境中活性腐蚀产物的安全性评估具有重要意义。
{"title":"Research on the migration behavior of corrosion products of CLF-1 steel in magnetic fields","authors":"Yuxin Xiao,&nbsp;Yi-Ming Lyu,&nbsp;Ye Li,&nbsp;Ning Liu,&nbsp;Jiejie Li,&nbsp;Shu-Feng Zhang,&nbsp;Shan-Liang Zheng","doi":"10.1016/j.nme.2026.102160","DOIUrl":"10.1016/j.nme.2026.102160","url":null,"abstract":"<div><div>CLF-1 steel, a candidate material for cooling water pipes in fusion reactors, is not only corroded by cooling water producing corrosion products (CPs), but is also exposed to strong magnetic fields during service. Activated corrosion products (ACPs) are formed when CPs are irradiated by neutrons. ACPs are among the most serious sources of radiation risk. Strong magnetic fields in fusion reactors may affect the migration behavior of these ACPs, making the safety assessment of fusion reactors more challenging. The aim of this work is therefore to investigate the migration behavior of the corrosion products of CLF-1 steel in magnetic fields. To obtain the corrosion products, corrosion experiments were performed in a solution of 1 wt% H<sub>2</sub>O<sub>2</sub> and 0.1 wt% NaCl for 24 h. Migration experiments were performed on the corrosion products at different magnetic field strengths. The influence of magnetic fields on the migration behavior of corrosion products was experimentally observed for the first time. The XRD analysis reveals that the CPs are mixtures of multiple components. The same migration experiments were further performed for each of the main components of the corrosion products. The results indicate that, in the range of 200–1000 Gs, regarding quantity and migration distance of particles affected by the magnetic fields, Fe<sub>3</sub>O<sub>4</sub> is the largest; in the range of 3000–8000 Gs, the quantity and migration distance of the particles affected by the magnetic fields, from highest to lowest, is FeCr<sub>2</sub>O<sub>4</sub> &gt; CPs &gt; Fe<sub>2</sub>O<sub>3</sub> &gt; Cr<sub>2</sub>O<sub>3</sub>, and the migration direction is mainly determined by the magnetic field gradient. In order to reveal the physical mechanism behind this phenomenon, the magnetic behaviors of corrosion products and the main components of the corrosion products were analyzed with a vibrating sample magnetometer. Analysis of the magnetization versus applied magnetic field curves indicates that the quantity and migration distance of the migrating particles affected by magnetic fields are positively correlated with their magnetization under the same magnetic field conditions. At 300 K, the magnetic response of the corrosion products exhibits weak ferromagnetism. The initial magnetic susceptibility of the corrosion products is higher than that of Fe<sub>2</sub>O<sub>3</sub> and FeCr<sub>2</sub>O<sub>4</sub> due to the presence of Fe<sub>3</sub>O<sub>4</sub>. In this study, the migration of reduced activation steel corrosion products affected by the magnetic fields was observed for the first time. Future work should further focus on the migration behavior of corrosion products in the actual magnetic fields of fusion reactors, which is important for the safety assessment of activated corrosion products in the fusion reactor environments.</div></div>","PeriodicalId":56004,"journal":{"name":"Nuclear Materials and Energy","volume":"47 ","pages":"Article 102160"},"PeriodicalIF":2.8,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148539539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Nuclear Materials and Energy
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