Haruka Koshino, Zi Lang Goo, Kunihisa Sugimoto, Tomoyuki Mochida
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Solvent-Free Photochemical Formation of Cubane-type Ru Complexes from Organometallic Ionic Liquids with Cyanoborate Anions
Coordination compounds, including cage compounds, are typically synthesized via solution reactions. Here, we report the solvent-free, quantitative conversion of organometallic ionic liquids (ILs) containing alkyltricyanoborate anions into solid tetraalkyl cubane-type tetranuclear Ru complexes upon UV irradiation. Furthermore, we elucidated the diverse packing structures of the octyl derivative.
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