{"title":"镍催化α-卤代硼酸盐还原偶联获得内邻双（硼酸）酯","authors":"Huiyuan Wang, Shanya Lu, Dong Wang, Tao XU","doi":"10.1039/d5cc01841b","DOIUrl":null,"url":null,"abstract":"1,2-Bis(boronate) esters have emerged as valuable synthetic building blocks due to the versatile reactivity of their two C-B bonds. Herein, we report a nickel-catalyzed reductive coupling reaction of α-haloboronates for constructing the symmetric and unsymmetric targets with a broad substrate scope and excellent functional group tolerance.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"53 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nickel-Catalyzed Reductive Coupling of α-Haloboronates to Access Internal Vicinal Bis(boronate) Esters\",\"authors\":\"Huiyuan Wang, Shanya Lu, Dong Wang, Tao XU\",\"doi\":\"10.1039/d5cc01841b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"1,2-Bis(boronate) esters have emerged as valuable synthetic building blocks due to the versatile reactivity of their two C-B bonds. Herein, we report a nickel-catalyzed reductive coupling reaction of α-haloboronates for constructing the symmetric and unsymmetric targets with a broad substrate scope and excellent functional group tolerance.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"53 1\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc01841b\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc01841b","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Nickel-Catalyzed Reductive Coupling of α-Haloboronates to Access Internal Vicinal Bis(boronate) Esters
1,2-Bis(boronate) esters have emerged as valuable synthetic building blocks due to the versatile reactivity of their two C-B bonds. Herein, we report a nickel-catalyzed reductive coupling reaction of α-haloboronates for constructing the symmetric and unsymmetric targets with a broad substrate scope and excellent functional group tolerance.
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