Mechanical properties of Sn-58Bi, In-3Ag and SAC305 solders measured with fine diameter specimens

T. Hisada, I. Shohji, Yasuharu Yamada, K. Toriyama, M. Ueno
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Abstract

Lead-free solders such as SnAg or SnAgCu is widely used for flip chip joining. As a result of higher melting temperature and higher elastic modulus of the lead-free solders compared to eutectic SnPb solder, defect of crack or damage in low-k dielectric layers under bond pad for flip chip joining in the semiconductor chip became a serious issue. The crack or damage is caused by mismatch of coefficient of thermal expansion (CTE) between chip and chip carrier substrate after chip join reflow. Various low melting temperature solders have been investigated and proposed as alternatives to SnAg or SnAgCu solders. Mechanical properties including creep properties are important factors as well as melting temperature for stress relief in micro joints and low-k layers. In this paper, the authors report measurement results of creep properties with fine-diameter-specimens (0.5 mm in diameter) of two low melting temperature solders (Sn-58Bi and In-3Ag) and conventional lead-free solder (Sn-3.0Ag-0.5Cu). The measurement matrix consists of four different strain rates and three different temperatures. The stress component n and the constant A in Norton's creep law were derived for each solder alloy.
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用细径试样测定Sn-58Bi、In-3Ag和SAC305焊料的力学性能
无铅焊料(如SnAg或SnAgCu)广泛用于倒装芯片连接。由于与共晶SnPb焊料相比,无铅焊料具有更高的熔化温度和更高的弹性模量,因此半导体芯片中用于倒装连接的键垫下低k介电层的裂纹或损伤缺陷成为一个严重的问题。芯片连接回流后,由于芯片与芯片载体衬底之间的热膨胀系数(CTE)不匹配而产生裂纹或损伤。人们研究并提出了各种低熔点焊料作为SnAg或SnAgCu焊料的替代品。蠕变等力学性能和熔化温度是影响微节理和低k层应力消除的重要因素。在本文中,作者报告了两种低温焊料(Sn-58Bi和In- 3ag)和常规无铅焊料(Sn-3.0Ag-0.5Cu)的细径试样(直径0.5 mm)蠕变性能的测量结果。测量矩阵由四种不同的应变速率和三种不同的温度组成。推导了各焊料合金的应力分量n和诺顿蠕变定律常数A。
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