A Facile and Cost Effective Synthesis of Biomass-Supported Palladium Nanoparticles Using Sodium Hypophosphite for Catalytic Dechlorination of Chlorobenzene

J. Omajali
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Abstract

Although molecular hydrogen is very useful in environmentally clean technology, its usage also comes with some associated hazards and hence the need to use hydrogen donor compounds such as sodium hypophosphite in the generation of hydrogen as electron donor. In this study, sodium hypophosphite was utilized as a source of hydrogen and as an electron donor in the biogenic reduction of palladium onto the surface of bacterial cells (aerobic and anaerobic bacteria) to produce bio-nanoparticles with potential in the dehalogenation of chlorinated pollutants like chlorobenzene. The purpose of this paper is to provide a facile and cost effective approach to the synthesis of biogenic nanoparticles using sodium hypophosphite as a hydrogen donor compound. this to investigate the use of sodium ) as a simple and cost-effective source of for the catalytic synthesis of palladium (Pd) nano-catalysts supported on bacteria and the subsequent application in reductive dehalogenation of chlorobenzene.
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次亚磷酸钠催化氯苯脱氯制备生物质负载钯纳米颗粒
虽然分子氢在环境清洁技术中非常有用,但它的使用也带来了一些相关的危害,因此需要使用氢供体化合物,如次亚磷酸钠在氢的生成中作为电子供体。在本研究中,次亚磷酸钠被用作氢源和电子供体,用于在细菌细胞(好氧和厌氧细菌)表面上进行钯的生物还原,以产生具有去除氯苯等氯化污染物的潜力的生物纳米颗粒。本文的目的是提供一种简单而经济有效的方法来合成生物源纳米颗粒,利用次磷酸钠作为氢供体化合物。本研究旨在研究使用钠作为一种简单而经济的源来催化合成细菌负载的钯(Pd)纳米催化剂以及随后在氯苯还原脱卤中的应用。
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