Low Temperature, Fast Copper–to–Copper Bonding Enabled by Microwave-Induced Interfacial Field Amplification

IF 4.7 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2026-09-22 Epub Date: 2026-09-10 DOI:10.1021/acsaelm.6c01533
Min Kim, Taehun Jeon, Kyungmin Shin, Gyohyuk Gu, Byeonghun Lee, Hoesung Ha, Ohhyuk Kwon, Jongseon Seo, Jong Kyung Park, Hyunsang Hwang
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Abstract

Copper–to–copper (Cu−Cu) bonding has emerged as a promising solution for realizing high-density vertical chip stacking for next-generation 3D integration. However, conventional Cu−Cu bonding generally requires a high thermal budget of ∼300 °C for 1 h, which can cause wafer warpage and compromise device performance. Here, a microwave annealing (MWA)-based Cu−Cu bonding technique is proposed to enable bonding with the substrate maintained at a low temperature of 150 °C and a short bonding time of 3 min. The MWA-bonded samples exhibit electrically and mechanically stable bonding characteristics, with a shear strength of 30–32 MPa and a specific contact resistance of ∼10−7 Ω·cm2. The microwave field is amplified within the nanoscale air gap between the two facing copper surfaces, localizing energy via discharge at the Cu−Cu interface. This localized energy is believed to drive the rapid elimination of the interfacial gap between the Cu−Cu surfaces, allowing rapid bonding while keeping the substrate at a low temperature. Compared to thermocompression (TC) bonding under comparable pressure and an N2 atmosphere, MWA reduces the bonding temperature by 150 °C while shortening the process time 20-fold. Overall, this study presents a low thermal budget Cu−Cu bonding approach enabled by an MWA strategy, offering a compelling alternative for advanced packaging.

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微波诱导界面场放大实现低温、快速铜对铜键合
铜对铜(Cu−Cu)键合已成为实现下一代3D集成高密度垂直芯片堆叠的有前途的解决方案。然而,传统的Cu−Cu键合通常需要1小时~ 300°C的高热预算,这可能导致晶圆翘曲并影响器件性能。本文提出了一种基于微波退火(MWA)的Cu−Cu键合技术,可以在150°C的低温和3 min的短时间内与衬底键合。mwa结合的样品表现出电和机械稳定的结合特性,剪切强度为30-32 MPa,比接触电阻为~ 10−7 Ω·cm2。微波场在两个铜表面之间的纳米级气隙内被放大,通过Cu−Cu界面处的放电将能量局部化。这种局域能量被认为可以快速消除Cu - Cu表面之间的界面间隙,从而在保持衬底低温的同时实现快速键合。与同等压力和N2气氛下的热压(TC)键合相比,MWA将键合温度降低了150°C,同时将工艺时间缩短了20倍。总体而言,本研究提出了一种由MWA策略实现的低热预算Cu - Cu键合方法,为先进封装提供了令人信服的替代方案。
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊介绍: ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric. Indexed/​Abstracted: Web of Science SCIE Scopus CAS INSPEC Portico
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