Effect of Nano-catalyst on Microwave-Assisted Co-pyrolysis Oil of Chelly Seed and Date Seed Waste

IF 3.7 3区 化学 Q2 CHEMISTRY, APPLIED Topics in Catalysis Pub Date : 2026-08-04 DOI:10.1007/s11244-026-02332-y
Firas Al Oqaili, Mustafa Al Dulaimi, Muhsin Jaber Jweeg, Oday I. Abdullah, Husam Talib Hamzah, Veluru Sridevi, Thamer Adnan Abdullah
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Abstract

One of the best ways to deal with solid waste is microwave-assisted pyrolysis. Extraction of valuable oils from date seed (DS) and Chelly seeds (CS) by MW-assisted catalytic co-pyrolysis has demonstrated encouraging results in this field of study. The CaO Nano catalyst served as the susceptor, while graphite was employed as the catalyst. A 1:1 CS: DS ratio was used as the feedstock. The production yields of oil (37.04 to 50.20 wt%), gas (38.14 to 28.39 wt%), and the char level (24.807 to 21.4 wt%) were different between the two groups when comparing co-pyrolysis with and without a CaO nano-catalyst. The average heating rate, feedstock conversion, and product yields concerning the nano-catalyst were all examined. The rate without the catalyst was 20.17.0 °C/min, but it climbed to 24.17.0 °C/min with the catalyst. The analysis focused on the synergistic impacts on product yields, average heating rates, and conversion factors. An increase in oil output is one prominent effect of co-pyrolysis synergy. Another is increased char and gas production when a CaO nano-catalyst is used. In addition, FTIR, NMR, and GC–MS were used to examine the oil produced during the catalytic co-pyrolysis of CS by DS. The catalyst facilitated the formation of aliphatic molecules, aromatic compounds, amides, and alkenes through co-pyrolysis.

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纳米催化剂对微波辅助共热解樱桃籽和枣籽废油的影响
处理固体废物的最佳方法之一是微波辅助热解。mw辅助催化共热解法从枣子籽(DS)和雪莉籽(CS)中提取有价油脂,在这一领域的研究取得了令人鼓舞的成果。CaO纳米催化剂作为电纳,石墨作为催化剂。以1:1的CS: DS比例为原料。在加CaO纳米催化剂和不加CaO纳米催化剂的情况下,两组共热解的产油率(37.04 ~ 50.20 wt%)、气率(38.14 ~ 28.39 wt%)和焦炭含量(24.807 ~ 21.4 wt%)存在差异。考察了纳米催化剂的平均升温速率、原料转化率和产品收率。无催化剂时反应速率为20.17.0°C/min,有催化剂时反应速率为24.17.0°C/min。分析的重点是协同效应对产品收率、平均加热速率和转换系数的影响。原油产量的增加是共热解协同作用的一个突出效果。另一个是当使用氧化钙纳米催化剂时,增加了炭和气体的产量。此外,利用FTIR、NMR和GC-MS对DS催化CS共热解过程中生成的油进行了表征。催化剂通过共热解促进了脂肪族分子、芳香族化合物、酰胺和烯烃的形成。
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来源期刊
Topics in Catalysis
Topics in Catalysis 化学-物理化学
CiteScore
5.70
自引率
5.60%
发文量
197
审稿时长
2 months
期刊介绍: Topics in Catalysis publishes topical collections in all fields of catalysis which are composed only of invited articles from leading authors. The journal documents today’s emerging and critical trends in all branches of catalysis. Each themed issue is organized by renowned Guest Editors in collaboration with the Editors-in-Chief. Proposals for new topics are welcome and should be submitted directly to the Editors-in-Chief. The publication of individual uninvited original research articles can be sent to our sister journal Catalysis Letters. This journal aims for rapid publication of high-impact original research articles in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis.
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