功能性金属有机框架衍生的电化学储能电极材料:综述。

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-10-21 DOI:10.1039/d4cc04086d
Basree , Arif Ali , Khusboo Kumari , Musheer Ahmad , Ganesh Chandra Nayak
{"title":"功能性金属有机框架衍生的电化学储能电极材料:综述。","authors":"Basree ,&nbsp;Arif Ali ,&nbsp;Khusboo Kumari ,&nbsp;Musheer Ahmad ,&nbsp;Ganesh Chandra Nayak","doi":"10.1039/d4cc04086d","DOIUrl":null,"url":null,"abstract":"<div><div>Pristine metal–organic frameworks (MOFs) are built through self-assembly of electron rich organic linkers and electron deficient metal nodes <em>via</em> coordinate bond. Due to the unique properties of MOFs like highly tunable frameworks, huge specific surface areas, flexible chemical composition, flexible structures and a large volume of pores, they are being used to design the electrode materials for electrochemical energy storage devices. As per the literature, MOFs (including manganese, nickel, copper, and cobalt-based zeolitic imidazolate frameworks (ZIFs), University of Oslo (UiO) MOFs, Hong Kong University of Science and Technology (HKUST) MOFs and isoreticular MOFs (IRMOFs)) have attracted much attention in the field of supercapacitors (SCs)/batteries. According to their dimensionality such as 1D, 2D and 3D, pristine MOFs are mainly used as SC materials. Highly porous materials and their composites are capable for intercalation of metal ions (Na<sup>+</sup>/Li<sup>+</sup>). Moreover, the supramolecular features (π⋯π, C–H⋯π, hydrogen bond interactions) of redox stable MOFs provide better insight for electrochemical stability. So, this review provides an in-depth analysis of pure MOFs and MOF derived composites (MOF composites and MOF derived porous carbon) as electrode materials and also discusses their metal ion charge storage mechanism. Finally, we provide our perspectives on the current issues and future opportunities for supercapacitor materials.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 91","pages":"Pages 13292-13313"},"PeriodicalIF":4.3000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review\",\"authors\":\"Basree ,&nbsp;Arif Ali ,&nbsp;Khusboo Kumari ,&nbsp;Musheer Ahmad ,&nbsp;Ganesh Chandra Nayak\",\"doi\":\"10.1039/d4cc04086d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Pristine metal–organic frameworks (MOFs) are built through self-assembly of electron rich organic linkers and electron deficient metal nodes <em>via</em> coordinate bond. Due to the unique properties of MOFs like highly tunable frameworks, huge specific surface areas, flexible chemical composition, flexible structures and a large volume of pores, they are being used to design the electrode materials for electrochemical energy storage devices. As per the literature, MOFs (including manganese, nickel, copper, and cobalt-based zeolitic imidazolate frameworks (ZIFs), University of Oslo (UiO) MOFs, Hong Kong University of Science and Technology (HKUST) MOFs and isoreticular MOFs (IRMOFs)) have attracted much attention in the field of supercapacitors (SCs)/batteries. According to their dimensionality such as 1D, 2D and 3D, pristine MOFs are mainly used as SC materials. Highly porous materials and their composites are capable for intercalation of metal ions (Na<sup>+</sup>/Li<sup>+</sup>). Moreover, the supramolecular features (π⋯π, C–H⋯π, hydrogen bond interactions) of redox stable MOFs provide better insight for electrochemical stability. So, this review provides an in-depth analysis of pure MOFs and MOF derived composites (MOF composites and MOF derived porous carbon) as electrode materials and also discusses their metal ion charge storage mechanism. Finally, we provide our perspectives on the current issues and future opportunities for supercapacitor materials.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"60 91\",\"pages\":\"Pages 13292-13313\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734524022274\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524022274","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

原始金属有机框架(MOFs)是由富电子有机连接体和缺电子金属节点通过配位键自组装而成。由于 MOFs 具有高度可调框架、巨大比表面积、灵活的化学成分、柔性结构和大量孔隙等独特性质,因此正被用于设计电化学储能设备的电极材料。根据文献记载,MOFs(包括锰、镍、铜和钴基沸石咪唑啉框架(ZIFs)、奥斯陆大学(UiO)MOFs、香港科技大学(HKUST)MOFs 和异构 MOFs(IRMOFs))在超级电容器(SCs)/电池领域备受关注。根据一维、二维和三维等不同维度,原始 MOFs 主要用作超级电容器材料。高多孔材料及其复合材料能够插层金属离子(Na+/Li+)。此外,氧化还原稳定 MOFs 的超分子特征(π⋯π、C-H⋯π、氢键相互作用)能更好地揭示其电化学稳定性。因此,本综述深入分析了作为电极材料的纯 MOF 和 MOF 衍生复合材料(MOF 复合材料和 MOF 衍生多孔碳),并讨论了它们的金属离子电荷存储机制。最后,我们对超级电容器材料的当前问题和未来机遇提出了自己的看法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review
Pristine metal–organic frameworks (MOFs) are built through self-assembly of electron rich organic linkers and electron deficient metal nodes via coordinate bond. Due to the unique properties of MOFs like highly tunable frameworks, huge specific surface areas, flexible chemical composition, flexible structures and a large volume of pores, they are being used to design the electrode materials for electrochemical energy storage devices. As per the literature, MOFs (including manganese, nickel, copper, and cobalt-based zeolitic imidazolate frameworks (ZIFs), University of Oslo (UiO) MOFs, Hong Kong University of Science and Technology (HKUST) MOFs and isoreticular MOFs (IRMOFs)) have attracted much attention in the field of supercapacitors (SCs)/batteries. According to their dimensionality such as 1D, 2D and 3D, pristine MOFs are mainly used as SC materials. Highly porous materials and their composites are capable for intercalation of metal ions (Na+/Li+). Moreover, the supramolecular features (π⋯π, C–H⋯π, hydrogen bond interactions) of redox stable MOFs provide better insight for electrochemical stability. So, this review provides an in-depth analysis of pure MOFs and MOF derived composites (MOF composites and MOF derived porous carbon) as electrode materials and also discusses their metal ion charge storage mechanism. Finally, we provide our perspectives on the current issues and future opportunities for supercapacitor materials.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
期刊最新文献
Enhanced NH3-SCR Activity of Cu-SAPO-34 by Regulating Si Distribution via an Interzeolite Conversion Strategy Sandwich-like Heterometallic Fe7Sn6 Oxo Cluster Constructed by Tessellation of Anderson-like {Fe7} Wheel for Near-infrared Photothermal Conversion Cobalt Catalysed Cross-Dedydrogenative Coupling of Indoles: A Photoinduced Ligand to Metal Charge Transfer Process The electrochemical ion membrane system (EIMs) enhanced light reactions of photosynthesis with intermittent electrical stimulation AgOTf-catalyzed cascade annulation of 5-hexyn-1-ols and aldehydes: Enabling the diastereoselective synthesis of [6,6,6]-trioxa-fused ketals and hexahydro-2H-chromenes
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1