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Research on the inversion method of vertical airflow motion in complex phase layered clouds 复杂相层状云中垂直气流运动的反演方法研究
IF 4.4 2区 地球科学 Q1 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.atmosres.2026.108843
Yun Yuan, Huige Di, Jiale Wang, Dengxin Hua
The vertical airflow velocity directly governs the growth and development of clouds. Accurately retrieving this velocity represents one of the pivotal and challenging aspects in cloud dynamics research. Unfortunately, no existing method can precisely retrieve the continuous vertical airflow velocity within clouds. To tackle this problem, this study assesses the feasibility of employing particles at the left end of the power spectrum as tracer particles by incorporating the intensity and critical threshold of tracer spectral points. Through an analysis of the impacts of turbulence, wind shear, and beam width on particles in various phases, the spectral width threshold is further established. Ultimately, the applicable conditions for the small particle tracing method are clearly defined. Additionally, based on power spectrum skewness and temperature, a method for retrieving vertical airflow velocity through spectral separation in a bimodal structure is proposed. The combination of these two methods can overcome the limitations inherent in single retrieval method and yield the vertical airflow velocity within the cloud's vertical structure under specific conditions.
垂直气流速度直接支配着云的生长和发展。准确地检索这个速度是云动力学研究中关键和具有挑战性的方面之一。遗憾的是,目前还没有一种方法可以精确地获取云内连续垂直气流速度。为了解决这一问题,本研究通过结合示踪谱点的强度和临界阈值,评估了采用功率谱左端粒子作为示踪粒子的可行性。通过分析湍流、风切变和光束宽度对不同阶段粒子的影响,进一步建立了谱宽阈值。最后明确了小颗粒示踪法的适用条件。在此基础上,提出了一种基于功率谱偏度和温度的双峰结构垂直气流速度提取方法。这两种方法的结合可以克服单一检索方法固有的局限性,得到特定条件下云的垂直结构内的垂直气流速度。
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引用次数: 0
Navigating climate challenges: harnessing energy, eco-innovation, and climate policy in achieving sustainable development goals 应对气候挑战:利用能源、生态创新和气候政策实现可持续发展目标
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2025-12-31 DOI: 10.1016/j.gr.2025.12.004
Huangxin Chen , Li Zhang , Stefania Pinzon , Meijin Chen , Bin Chen
Carbon emissions cause climate change, a danger to society and the environment. Despite efforts, the US remains one of the largest carbon dioxide emitters, which may lead to rising seas, increased natural disasters, and ecological catastrophes. Therefore, we need policies that are immediately effective in preventing carbon emissions. In this perspective, this study scrutinizes the role of Energy Transition (ET), Eco-Innovation (EINO), Globalization (GN), Sustainable Consumption (SC), and Climate Policy Uncertainty (CPU) on CO2 emissions and Load Capacity Factor (LCF) from 1980 to 2019. Utilizing cutting-edge econometric techniques includes dynamic Autoregressive Distributed Lag (ARDL) simulations and Cumulative Fourier Frequency Domain Causality (CFFDC). The results indicate that EINO reduces emissions, while ET and CPU provide short-term reductions. Conversely, GN and SC shortly upsurge emissions, though SC behaves differently under CFFDC analysis. The study also divulges bidirectional causality among most variables, with GN and SC significantly impacting LCF in specific models. These findings underscore the importance of implementing targeted policies, such as carbon taxes, incentives for renewable energy adoption, and stringent emissions regulations, to achieve Sustainable Development Goals (SDGs) 7 and 13. In conclusion, such policy measures are critical for the United States to contribute effectively to global efforts to combat climate change.
碳排放导致气候变化,对社会和环境构成威胁。尽管做出了努力,但美国仍然是最大的二氧化碳排放国之一,这可能导致海平面上升,自然灾害和生态灾难增加。因此,我们需要立即有效防止碳排放的政策。在这一视角下,本研究考察了1980 - 2019年能源转型(ET)、生态创新(EINO)、全球化(GN)、可持续消费(SC)和气候政策不确定性(CPU)对二氧化碳排放和负荷能力因子(LCF)的影响。利用尖端的计量经济学技术,包括动态自回归分布滞后(ARDL)模拟和累积傅立叶频域因果关系(CFFDC)。结果表明,EINO减少排放,而ET和CPU提供短期减排。相反,GN和SC很快就会增加排放,尽管SC在CFFDC分析下表现不同。该研究还揭示了大多数变量之间的双向因果关系,在特定模型中,GN和SC显著影响LCF。这些发现强调了实施有针对性的政策(如碳税、可再生能源采用激励措施和严格的排放法规)对实现可持续发展目标7和13的重要性。总而言之,这些政策措施对于美国有效地为应对气候变化的全球努力作出贡献至关重要。
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引用次数: 0
Designing landslide mitigation strategies through developing knowledge aware deep learning model integrated explainable artificial intelligence 通过开发集成可解释人工智能的知识感知深度学习模型设计滑坡缓解策略
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2025-12-27 DOI: 10.1016/j.pce.2025.104266
Inzamam Ul Haq , Habibullah , Shafiq Ahmed , Swapan Talukdar , Mansoor Ahmad , Md Sarfaraz Asgher , Imran Khan , G.V. Ramana
Landslides are a recurrent and damaging hazard in the Pir Panjal Range of Jammu and Kashmir, India, where steep slopes, fragile lithology and rapid human interventions coincide. This study develops an integrated landslide susceptibility mapping framework that combines machine learning (ML), deep learning (DL) and explainable artificial intelligence (XAI) to support risk-informed planning. An inventory of 1105 landslides and eighteen conditioning factors trains four ML models: Random Forest (RF), Support Vector Machine (SVM), Gradient Boosting Machine (GBM) and Categorical Boosting (CatBoost), evaluated with five-fold stratified cross-validation and a held-out test set. In parallel, a Bayesian-optimised DL model, in which a Variational Autoencoder (VAE) learns latent features that are classified by a Multilayer Perceptron (MLP), captures complex non-linear controls on slope failure. The best performing models achieve an area under the receiver operating characteristic curve (AUC-ROC) of about 0.96 and overall accuracy close to 0.90 on validation data, indicating high discriminatory skill. Spatially, High and Very High susceptibility zones together occupy roughly one quarter of the range and are concentrated in tehsils such as Gool Gulabgarh, Ramban, Thathri and Banihal, which emerge as hotspots for intervention. XAI diagnostics highlight vegetation condition, monsoon rainfall, lineament density and drainage density as dominant controls on susceptibility, while counterfactual experiments show that realistic improvements in vegetation cover, surface drainage and slope management can shift many locations from high to lower risk classes. The framework therefore provides accurate, interpretable and useful susceptibility maps for land-use regulation, infrastructure planning and landslide mitigation in data-constrained mountain environments.
在印度查谟和克什米尔的Pir Panjal山脉,陡峭的山坡、脆弱的岩性和快速的人为干预同时发生,山体滑坡是一个经常性的破坏性灾害。本研究开发了一个集成的滑坡易感性测绘框架,该框架结合了机器学习(ML)、深度学习(DL)和可解释的人工智能(XAI),以支持风险知情规划。1105个滑坡和18个调节因素的清单训练了四种ML模型:随机森林(RF)、支持向量机(SVM)、梯度增强机(GBM)和分类增强(CatBoost),并通过五倍分层交叉验证和持续测试集进行评估。与此同时,贝叶斯优化DL模型,其中变分自编码器(VAE)学习由多层感知器(MLP)分类的潜在特征,捕获斜坡破坏的复杂非线性控制。表现最好的模型在验证数据上的受试者工作特征曲线下面积(AUC-ROC)约为0.96,总体准确率接近0.90,表明具有较高的区分能力。在空间上,高易感区和极高易感区共同占据了大约四分之一的范围,集中在古尔古拉加尔、拉姆班、塔特里和巴尼哈尔等地区,这些地区成为干预的热点。XAI诊断强调植被条件、季风降雨、地形密度和排水密度是影响易感性的主要控制因素,而反事实实验表明,在植被覆盖、地表排水和斜坡管理方面的现实改进可以将许多地点从高风险等级转移到低风险等级。因此,该框架为数据有限的山地环境中的土地使用管制、基础设施规划和滑坡缓解提供了准确、可解释和有用的易感性地图。
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引用次数: 0
Water circulation, redox, and productivity dynamics shaped late Ediacaran ecosystems: Insights from trace elements and combined Sr–Cr–Cd isotopes in the Corumbá Group, Brazil 水循环、氧化还原和生产力动态塑造了埃迪卡拉晚期生态系统:来自巴西corumb<e:1>群微量元素和Sr-Cr-Cd组合同位素的见解
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-04 DOI: 10.1016/j.gr.2026.01.006
Henrique Albuquerque Fernandes , Paulo César Boggiani , Jesper Allan Frederiksen , Thales Pescarini , Vinicius Cardoso Lucas , Gustavo Paula Santos , Eric Elias , Marly Babinski , Juliana Leme , Catherine V. Rose , Ricardo Ivan Ferreira Trindade , Robert Frei
The relationship between marine oxygenation and early animal evolution remains a highly debated topic. Recent research suggests that, rather than absolute atmospheric O2 threshold levels, the main factor controlling early animal distribution was long-term local marine redox conditions. To explore this hypothesis, we present trace element data along with Sr, Cr, and Cd isotopes in carbonate rocks from the late Ediacaran Corumbá Group, Brazil, obtained from drill cores of the GRIND-ECT project. This multiproxy approach is designed to constrain basin water circulation, redox conditions, and bioproductivity levels from ca. 565 to 540 Ma, ultimately aiming to reconstruct the paleoceanographic scenario in which early animal colonization occurred in the Corumbá Basin. Redox-sensitive metal abundances indicate a contrasting redox scenario, with predominant anoxia in the Bocaina Formation and expanded oxia in the overlying Tamengo Formation. This interpretation is further reinforced by Cr isotopes, whereby δ53Cr passes from low values in the range of Bulk Silicate Earth to positively fractionated values upsection. Two negative δ53Cr excursions in the Tamengo Formation are interpreted as anoxic intervals. 87Sr/86Sr values decrease from 0.7100 in the Bocaina Formation to late Ediacaran values around 0.7085 in the Tamengo Formation. These radiogenic values in the Bocaina Formation are attributed to post-depositional diagenesis of Sr-depleted dolostones. Lastly, variable δ114Cd in the Bocaina Formation indicate contrasting productivity levels during highstand and flooding periods. The two anoxic intervals in the Tamengo Formation exhibit anomalous negative δ114Cd values, which may be linked to widespread eutrophication. Our study, combined with compilations of redox and fossil data, reveals that the Corumbá Basin evolved from a predominantly anoxic setting dominated by microfossils in the Bocaina Formation, to a connected marine setting in the Tamengo Formation. This later phase featured a deeper redoxcline and was dominated by fossils of biomineralizing animals, representing a near-optimal environment for early animal benthic colonization.
海洋氧合与早期动物进化之间的关系仍然是一个备受争议的话题。最近的研究表明,控制早期动物分布的主要因素不是绝对的大气O2阈值水平,而是长期的当地海洋氧化还原条件。为了探索这一假设,我们提供了巴西埃迪卡拉纪晚期corumb群碳酸盐岩中Sr、Cr和Cd同位素的微量元素数据,这些数据来自GRIND-ECT项目的岩心。这种多代理方法旨在限制大约565至540 Ma的盆地水循环、氧化还原条件和生物生产力水平,最终旨在重建早期动物殖民发生在corumb盆地的古海洋学情景。氧化还原敏感金属丰度表明了一个截然不同的氧化还原情景,在Bocaina组中主要是缺氧,而在其上的Tamengo组中则是缺氧扩展。Cr同位素进一步加强了这一解释,即δ53Cr从块状硅酸盐土范围内的低值过渡到上部的正分馏值。Tamengo组两次δ53Cr负偏移被解释为缺氧层段。87Sr/86Sr值从Bocaina组的0.7100下降到Tamengo组的0.7085左右。波坎纳组的这些放射性成因价值归因于贫锶白云岩的沉积后成岩作用。最后,Bocaina组δ114Cd的变化表明了高水位和淹水时期的生产力水平差异。Tamengo组两个缺氧层段δ114Cd值异常,可能与富营养化有关。我们的研究结合氧化还原和化石资料的汇编,揭示了corumb盆地从以微化石为主的Bocaina组缺氧环境演变到Tamengo组连接的海相环境。这一后期阶段具有较深的氧化还原层,主要是生物矿化动物的化石,代表了早期底栖动物定居的近乎最佳环境。
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引用次数: 0
Influence of chemical enhancer injection timings on electrokinetic geosynthetics-assisted vacuum preloading combined with electroosmosis for dredged sediments dewatering and heavy metal removal 化学增强剂注入时间对电动土工合成助力真空预压联合电渗透疏浚沉积物脱水除重金属的影响
IF 6.2 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2026-06-01 Epub Date: 2026-01-20 DOI: 10.1016/j.geotexmem.2026.01.005
Yang Shen , Ligao Zheng , Wencheng Qi , Chang Liu , Jianting Feng
Effective dewatering and heavy metal removal of dredged sediments using the electrokinetic geosynthetics-assisted vacuum preloading combined with electroosmosis (VPE) technique can convert dredged sediments into valuable resources for construction use. Chemical enhancers are commonly employed to enhance VPE performance, but their optimal injection timing remains largely unclear. This study investigated the influence of ethylenediaminetetraacetic acid (EDTA) and citric acid (CA) as well as their injection timings on the VPE efficacy for dredged sediment improvement. It compared drainage volume and drainage rate, moisture content, electric current and effective voltage, Cu concentration and speciation, and energy consumption under early- (It = I0), mid- (It = 70 %I0), and late-stage (It = 40 %I0) injections. The results showed that CA generally outperformed EDTA, achieving approximately 200 mL greater final drainage volumes and averagely reducing Cu concentrations from ∼1640 mg/kg to ∼745 mg/kg (EDTA was ∼755 mg/kg). Late-stage CA injection optimized drainage efficiency and moisture content uniformity. It reduced the moisture content gradients between the cathode and the anode to ∼4 % (it was ∼12 % for the injection of It = I0). The mid-stage injection of CA may achieve a balance between Cu removal and energy efficiency. EDTA, while less energy-intensive, retained higher weak-acid extractable Cu (∼15 %), posing leaching risks.
利用电动土工合成助力真空预压结合电渗透(VPE)技术对疏浚沉积物进行有效脱水和重金属去除,可将疏浚沉积物转化为有价值的建筑资源。化学增强剂通常用于提高VPE性能,但其最佳注射时间仍不清楚。本研究考察了乙二胺四乙酸(EDTA)和柠檬酸(CA)及其注入时间对疏浚底泥VPE改善效果的影响。比较了早期(It = I0)、中期(It = 70% I0)和后期(It = 40% I0)注射的排液量和排液速率、含水率、电流和有效电压、Cu浓度和形态、能耗。结果表明,CA总体上优于EDTA,最终排水量增加约200 mL,平均将Cu浓度从~ 1640 mg/kg降至~ 745 mg/kg (EDTA为~ 755 mg/kg)。后期CA注入优化了排水效率和含水率均匀性。它将阴极和阳极之间的水分含量梯度降低到~ 4%(注射It = I0时为~ 12%)。中期注入CA可以达到Cu去除和能量效率之间的平衡。EDTA虽然能耗较低,但保留了较高的弱酸可提取铜(约15%),存在浸出风险。
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引用次数: 0
Design and development of catalytic converter for diesel engines using phase change materials 采用相变材料的柴油机催化转化器的设计与开发
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-17 DOI: 10.1016/j.pce.2026.104289
R.K. Tyagi, Yash Saksena
An exhaust system is a discharge control mechanism for vehicles that transforms the fumes from an ignition motor's burning byproducts into less hazardous compounds through catalyzed compound reactions. To reduce emissions, aluminum oxide and chromium oxide are used in the catalytic converter analysis for the minimization of emissions as much as possible. Polyurethane has been used as a phase change material which plays a pivotal role in adsorbing the heat for a prolonged period and then releasing it which enhances the fuel efficiency of the vehicle, increases the life cycle of the vehicle and increases its life cycle for a prolonged period. The analysis also aims to determine the impact of the catalytic converter on emissions. The test engine, catalytic converter, AVL exhaust fuel analyzer, temperature gun and other measurement devices make up the experimental setup. The test engine was a four-stroke diesel single-cylinder engine. Initially, the engine was running with the existing catalytic converter with no other addition, and the emissions have been analyzed using gas analyzer of AVL. The exhaust emissions, and the design of the catalytic converter were considered as a main challenge where it was observed that heat was being adsorbed and emissions were reduced to around 30-40% in every case possible and oxygen, lambda value increased by 15-20 % where these test were examined under no load conditions of the engine where welding of catalysts and PCM played an important role for enhancement of the catalytic converter. Under identical engine rotational conditions, the catalytic converter equipped with phase change material achieved significant reductions in hydrocarbon emissions (63%), intake air temperature (48%), NOx (24%), and CO (60%).This catalytic converter can further reduce the knocking possibilities of the engine in the harsh weather conditions as diesel engines possess cluster combustion and constant heat adsorption can enhance the life cycle of the engine which is one of the major finding from this experiment.
排气系统是车辆的一种排放控制机制,它通过催化的化合物反应将点火电机燃烧副产物产生的烟雾转化为危害较小的化合物。为了减少排放,在催化转化器分析中使用氧化铝和氧化铬,以尽可能减少排放。聚氨酯已被用作相变材料,它在长时间吸附热量然后释放热量方面起着至关重要的作用,提高了车辆的燃油效率,增加了车辆的使用周期,并延长了车辆的使用周期。分析还旨在确定催化转化器对排放的影响。实验装置由试验发动机、催化转化器、AVL排气燃油分析仪、温度枪等测量装置组成。测试发动机是一台四冲程柴油单缸发动机。最初,发动机在现有催化转化器的基础上运行,不添加其他设备,并使用AVL气体分析仪对排放进行了分析。废气排放和催化转化器的设计被认为是一个主要的挑战,在所有可能的情况下,观察到热量被吸附,排放减少到30-40%左右,氧气,lambda值增加了15- 20%,这些测试是在发动机的空载条件下进行的,催化剂和PCM的焊接对催化转化器的增强起着重要的作用。在相同的发动机旋转条件下,配备相变材料的催化转化器显著降低了碳氢化合物排放(63%)、进气温度(48%)、NOx(24%)和CO(60%)。该催化转化器可以进一步减少发动机在恶劣天气条件下的爆震可能性,因为柴油发动机具有簇燃特性,持续吸热可以提高发动机的寿命周期,这是本实验的主要发现之一。
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引用次数: 0
In situ grown montmorillonite@layered double hydroxide assembled with sodium phytate towards improving flame retardancy and mechanical properties of leather 原位生长montmorillonite@layered双氢氧化物与植酸钠组装,以改善皮革的阻燃性和机械性能
IF 5.8 2区 地球科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-10 DOI: 10.1016/j.clay.2026.108157
Bin Lyu , Lurong Wang , Dangge Gao , Mengnan Kou , Jianzhong Ma
The flammability of oils, the main component of leather fatliquoring agent, has largely limited in leather applications. In this work, layered double hydroxide (LDH) was grown in situ on montmorillonite (MMT) lamellae using a hydrothermal method, followed by sodium phytate (SP) modification to obtain SP-MMT@LDH. It was further introduced into modified zanthoxylum bungeanum maxim seed oil (MZBMSO) to construct a high-performance flame-retardancy leather fatliquoring agent. The introduction of 12 wt% SP-MMT@LDH into MZBMSO resulted in good thermal stability and flame retardancy for the fatliquored leather. The sustained burning time of the SP-MMT@LDH/MZBMSO fatliquored leather was only 29 s, and the limiting oxygen index value reached 29.5%. Compared to MZBMSO fatliquored leather, the peak heat release rate (pHRR), total heat release (THR), peak smoke production rate (pSPR), and total smoke production (TSP) values of SP-MMT@LDH/MZBMSO fatliquored leather decreased effectively by 50.1%, 45.9%, 50.2%, and 75.0%, respectively. The excellent heat and smoke reduction performance of the fatliquored leather was further validated through condensed and gas phase flame retardancy mechanism. Moreover, the SP-MMT@LDH/MZBMSO fatliquored leather has good mechanical properties, including a softness of 5.23 mm. This study provides a new approach to improve the flame retardancy and mechanical properties of fatliquored leather.
油脂是皮革加脂剂的主要成分,其易燃性在很大程度上限制了皮革加脂剂的应用。本文采用水热法在蒙脱土(MMT)片层上原位生长层状双氢氧化物(LDH),然后用植酸钠(SP)改性得到SP-MMT@LDH。将其进一步引入改性花椒籽油(MZBMSO)中,制成高性能阻燃皮革加脂剂。在MZBMSO中引入12wt % SP-MMT@LDH,使加脂皮革具有良好的热稳定性和阻燃性。SP-MMT@LDH/MZBMSO加脂皮革的持续燃烧时间仅为29 s,极限氧指数达到29.5%。与MZBMSO加脂革相比,SP-MMT@LDH/MZBMSO加脂革的峰值放热率(pHRR)、总放热率(THR)、峰值产烟率(pSPR)和总产烟率(TSP)值分别有效降低了50.1%、45.9%、50.2%和75.0%。通过缩合和气相阻燃机理进一步验证了加脂皮革优异的减热降烟性能。此外,SP-MMT@LDH/MZBMSO加脂皮革具有良好的机械性能,柔软度为5.23 mm。本研究为提高加脂皮革的阻燃性和力学性能提供了一条新的途径。
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引用次数: 0
Precambrian ribbon structures of the Grand Canyon, Arizona 亚利桑那州大峡谷的前寒武纪带状结构
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-25 DOI: 10.1016/j.precamres.2026.108058
J.W. Hagadorn , C.M. Dehler
Macroscopic ribbon-shaped structures occur in the late Tonian Carbon Canyon Member, Galeros Formation, Chuar Group in the Grand Canyon, Arizona. Ribbons are three-dimensional dolomite clasts, are ornamented by longitudinal striations on both sides, and are ∼1 cm wide, ∼1 mm thick, and range from 2 to ≥17 cm long. Ribbons were transported and are preserved in abundance on bedding planes, often stacked atop one another. Ribbons have jagged to shredded terminations and exhibit evidence of flexure, twisting and deformation—indicating that they were pliable and torn prior to deposition. Although ribbons are morphologically similar to casts of blade-like macroalgal stipes and thalli, they lack features common to fossilized benthic algae, such as carbonaceous films. Thus, we tentatively interpret ribbons as sedimentary structures.
宏观带状构造出现在美国亚利桑那州大峡谷Chuar群Galeros组晚第三纪碳峡谷段。带状是三维白云岩碎屑,两侧有纵向条纹装饰,宽~ 1 cm,厚~ 1 mm,长度在2 ~≥17 cm之间。缎带被大量地运输和保存在铺层飞机上,通常一个叠一个。缎带的末端呈锯齿状,并显示出弯曲、扭曲和变形的迹象,表明它们在沉积之前是柔韧和撕裂的。虽然带状在形态上类似于叶片状的大型藻茎和菌体,但它们缺乏底栖藻类化石的共同特征,如碳质薄膜。因此,我们暂时将带状解释为沉积构造。
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引用次数: 0
Seasonal variation and distribution of microplastics in surface water and sediments of Coimbatore Lakes, India 印度哥印拜陀湖表层水和沉积物中微塑料的季节变化和分布
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-23 DOI: 10.1016/j.gr.2025.12.013
Davis Kaimalayil Ephsy, Selvaraju Raja
This study quantified the abundance, distribution, and characteristics of microplastics in surface water and sediments from five lakes in the Coimbatore District: Kumaraswamy Lake, Ukkadam Lake, Kuruchi Lake, Singanallur Lake, and Sulur Lake. The highest microplastic abundance was found in the surface water of Kuruchi Lake (14.08 ± 0.63 particles/L) at site S5 during the monsoon, and in the surface sediments of Kumaraswamy Lake (13.33 ± 0.33 particles/g) at site S6 during summer. Spatial distribution patterns indicated that lakes receiving urban runoff, domestic wastewater inflow, and inputs from fishing and recreational activities exhibited higher microplastic concentrations. Seasonal variations showed elevated microplastic abundance in summer sediments and monsoon surface water samples. Microplastics were identified using Attenuated total reflectance- Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Differential Scanning Calorimetry (DSC)), revealing Linear low-density polyethylene (LLDPE), High-density polyethylene (HDPE), Polyethylene terephthalate (PET), and Polypropylene (PP). These microplastic occurred in white, transparent, black, blue, yellow, and pink colors and appeared as films, fragments, thin pieces, and fibres. Characteristic DSC melting peaks were observed 200 °C for PET, 167.98 °C for PP, 126.70 °C for LLDPE, and 130.02 °C for HDPE. The lake’s pollution load index is categorized as risk level 1, indicating a low level of microplastic pollution. The presence and distribution of these microplastics suggest potential ecological risks to freshwater organisms and possible implications for human health.
本研究量化了哥印拜陀地区Kumaraswamy湖、Ukkadam湖、Kuruchi湖、Singanallur湖和Sulur湖五个湖泊地表水和沉积物中微塑料的丰度、分布和特征。季风期库鲁奇湖表层水(14.08±0.63颗粒/L)和夏季库马拉斯瓦米湖表层沉积物(13.33±0.33颗粒/g)的微塑料丰度最高。空间分布格局表明,城市径流、生活污水流入以及渔业和娱乐活动输入的湖泊呈现出较高的微塑料浓度。夏季沉积物和季风地表水样品的微塑料丰度随季节变化而升高。利用衰减全反射-傅里叶变换红外光谱(ATR-FTIR)和差示扫描量热法(DSC)对微塑料进行了鉴定,发现了线性低密度聚乙烯(LLDPE)、高密度聚乙烯(HDPE)、聚对苯二甲酸乙二醇酯(PET)和聚丙烯(PP)。这些微塑料有白色、透明、黑色、蓝色、黄色和粉红色,以薄膜、碎片、薄片和纤维的形式出现。PET的DSC熔化峰为200°C, PP为167.98°C, LLDPE为126.70°C, HDPE为130.02°C。该湖的污染负荷指数为风险1级,表明微塑料污染水平较低。这些微塑料的存在和分布表明对淡水生物存在潜在的生态风险,并可能对人类健康产生影响。
{"title":"Seasonal variation and distribution of microplastics in surface water and sediments of Coimbatore Lakes, India","authors":"Davis Kaimalayil Ephsy,&nbsp;Selvaraju Raja","doi":"10.1016/j.gr.2025.12.013","DOIUrl":"10.1016/j.gr.2025.12.013","url":null,"abstract":"<div><div>This study quantified the abundance, distribution, and characteristics of microplastics in surface water and sediments from five lakes in the Coimbatore District: Kumaraswamy Lake, Ukkadam Lake, Kuruchi Lake, Singanallur Lake, and<!--> <!-->Sulur Lake. The highest microplastic abundance was found in the<!--> <!-->surface water of Kuruchi Lake (14.08 ± 0.63 particles/L) at site S5 during the monsoon, and in the surface sediments of Kumaraswamy Lake (13.33 ± 0.33 particles/g) at site S6 during summer. Spatial distribution patterns indicated that lakes receiving urban runoff, domestic wastewater inflow, and inputs from fishing and recreational activities exhibited higher microplastic concentrations. Seasonal variations showed elevated microplastic abundance in summer sediments and monsoon surface water samples. Microplastics were identified using Attenuated total reflectance- Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Differential Scanning Calorimetry (DSC)), revealing Linear low-density polyethylene (LLDPE), High-density polyethylene (HDPE), Polyethylene terephthalate (PET), and Polypropylene (PP). These microplastic occurred in white, transparent, black, blue, yellow, and pink colors and appeared as films, fragments, thin pieces, and fibres. Characteristic DSC melting peaks were observed 200 °C for PET, 167.98 °C for PP, 126.70 °C for LLDPE, and 130.02 °C for HDPE. The lake’s pollution load index is categorized as risk level 1, indicating a low level of microplastic pollution. The presence and distribution of these microplastics suggest potential ecological risks to freshwater organisms and possible implications for human health.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"154 ","pages":"Pages 310-322"},"PeriodicalIF":7.2,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146033602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
DOC-governed metal solubility and mobility in river sediments: Integrating machine learning, causal pathways, and geochemical simulations doc控制的河流沉积物中的金属溶解度和流动性:整合机器学习,因果途径和地球化学模拟
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-29 DOI: 10.1016/j.pce.2026.104322
Fahmida Sultana , Zia Ahmed , Fei Zhang , Tasrina R. Choudhury , M. Safiur Rahman
This study explores the complex interactions between sediment texture, dissolved organic carbon (DOC) levels, and water chemistry in influencing the solubility and mobility of toxic metals (Cd, Ni, Zn, Cu, Cr, Pb) in river sediments. A multi-tiered approach integrating machine learning, Structural Equation Modeling (SEM), and geochemical simulations was employed to understand metal behavior in the Meghna River, Bangladesh. Redundancy Analysis (RDA) revealed that sediment texture and DOC fractions are the primary drivers of metal mobility, with clay content contributing the most to variation in metal concentrations (Variance Inflation Factor (VIF) values for clay = 3.50). The study employed Random Forest (RF) and XGBoost models to predict metal concentrations, achieving exceptional predictive accuracy with Area Under the Curve (AUC) values of 1.000 for Ni, Zn, Cr, and Pb, and 0.964 for Cd. Regression models demonstrated strong performance with R2 values of 0.963 for Pb, 0.938 for Ni, and 0.928 for Zn, highlighting the robustness of DOC and sediment texture in explaining metal variability. SEM analysis indicated that pH mediates the DOC–metal relationship, with standardized path coefficients for DOC retention and metal mobility being −0.475 and 0.96 for Zn, respectively. The GIS-based Metal Mobility Index (MMI) and Soil Mobility Index (SMI) predicted high-risk zones for metal mobility, with an AUC of 0.91, effectively distinguishing between high and low mobility regions. These findings provide critical insights into metal transport dynamics and offer valuable tools for river sediment management and metal contamination risk assessment.
本研究探讨了沉积物结构、溶解有机碳(DOC)水平和水化学之间的复杂相互作用对河流沉积物中有毒金属(Cd、Ni、Zn、Cu、Cr、Pb)溶解度和迁移率的影响。采用结合机器学习、结构方程建模(SEM)和地球化学模拟的多层方法来了解孟加拉国梅克纳河中的金属行为。冗余分析(RDA)表明,沉积物结构和DOC组分是金属迁移的主要驱动因素,粘土含量对金属浓度变化的贡献最大(粘土的方差膨胀因子(VIF)值= 3.50)。研究采用随机森林(Random Forest, RF)和XGBoost模型预测金属浓度,Ni、Zn、Cr和Pb的曲线下面积(Area Under The Curve, AUC)值为1.000,Cd的AUC值为0.964,预测精度极高。回归模型显示,Pb的R2值为0.963,Ni的R2值为0.938,Zn的R2值为0.928,这突出了DOC和沉积物质地在解释金属变异方面的鲁棒性。SEM分析表明pH调节了DOC与金属的关系,Zn的DOC保留率和金属迁移率的标准化通径系数分别为- 0.475和0.96。基于gis的金属流动性指数(MMI)和土壤流动性指数(SMI)预测了土壤金属流动性的高风险区,AUC为0.91,有效区分了土壤金属流动性的高、低风险区。这些发现为金属运移动力学提供了重要的见解,并为河流沉积物管理和金属污染风险评估提供了有价值的工具。
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