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Front Cover: (Eur. J. Inorg. Chem. 5/2025)
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-02-17 DOI: 10.1002/ejic.202580501

{"title":"Front Cover: (Eur. J. Inorg. Chem. 5/2025)","authors":"","doi":"10.1002/ejic.202580501","DOIUrl":"https://doi.org/10.1002/ejic.202580501","url":null,"abstract":"<p>\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 5","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202580501","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Solid-State Ion Exchange of Organic Ammonium Cations in Molecular Crystals (Eur. J. Inorg. Chem. 4/2025)
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-02-03 DOI: 10.1002/ejic.202580401
Mizuki Ito, Jun Manabe, Katsuya Inoue, Yin Qian, Xiao-Ming Ren, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara

The Front Cover illustrates a claw machine extracting a three-dimensional object, shaped to match its claw, from water. This visual symbolizes a Li2([18]crown-6)3[Ni(dmit)2]2(H2O)4 crystal, whose channel structure, formed by aligned [18]crown-6 molecules (orange rings), enables selective ion exchange. The crystal selectively incorporates MeNH3+ from a mixture of organic cations (MeNH3+, EtNH3+, nPrNH3+) in aqueous solution, maintaining its crystalline integrity. More information can be found in the Research Article by S. Nishihara and co-workers.

{"title":"Front Cover: Solid-State Ion Exchange of Organic Ammonium Cations in Molecular Crystals (Eur. J. Inorg. Chem. 4/2025)","authors":"Mizuki Ito,&nbsp;Jun Manabe,&nbsp;Katsuya Inoue,&nbsp;Yin Qian,&nbsp;Xiao-Ming Ren,&nbsp;Tomoyuki Akutagawa,&nbsp;Takayoshi Nakamura,&nbsp;Sadafumi Nishihara","doi":"10.1002/ejic.202580401","DOIUrl":"https://doi.org/10.1002/ejic.202580401","url":null,"abstract":"<p><b>The Front Cover</b> illustrates a claw machine extracting a three-dimensional object, shaped to match its claw, from water. This visual symbolizes a Li<sub>2</sub>([18]crown-6)<sub>3</sub>[Ni(dmit)<sub>2</sub>]<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub> crystal, whose channel structure, formed by aligned [18]crown-6 molecules (orange rings), enables selective ion exchange. The crystal selectively incorporates MeNH<sub>3</sub><sup>+</sup> from a mixture of organic cations (MeNH<sub>3</sub><sup>+</sup>, EtNH<sub>3</sub><sup>+</sup>, <i>n</i>PrNH<sub>3</sub><sup>+</sup>) in aqueous solution, maintaining its crystalline integrity. More information can be found in the Research Article by S. Nishihara and co-workers.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 4","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202580401","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143111331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Redox Reactions of [RuIII(pic)3] (pic−=picolinate) with Sulfite in Aqueous Solution: Kinetic, and Mechanistic Studies (Eur. J. Inorg. Chem. 3/2025)
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-22 DOI: 10.1002/ejic.202580301
Olga Impert, Debabrata Chatterjee

The Front Cover shows the redox reaction of a substitution-inert and electrically neutral [RuIII(pic)3] (pic=picolinate) complex with sulfite in aqueous solution. Studies revealed that, despite being a considerably more weakly electron-accepting oxidant than those reported previously for SIV oxidation, [RuIII(pic)3] can effectively and selectively oxidize sulfite to sulfate through an outer-sphere electron-transfer pathway. More information can be found in the Research Article by O. Impert and D. Chatterjee.

{"title":"Front Cover: Redox Reactions of [RuIII(pic)3] (pic−=picolinate) with Sulfite in Aqueous Solution: Kinetic, and Mechanistic Studies (Eur. J. Inorg. Chem. 3/2025)","authors":"Olga Impert,&nbsp;Debabrata Chatterjee","doi":"10.1002/ejic.202580301","DOIUrl":"https://doi.org/10.1002/ejic.202580301","url":null,"abstract":"<p><b>The Front Cover</b> shows the redox reaction of a substitution-inert and electrically neutral [Ru<sup>III</sup>(pic)<sub>3</sub>] (pic<sup>−</sup>=picolinate) complex with sulfite in aqueous solution. Studies revealed that, despite being a considerably more weakly electron-accepting oxidant than those reported previously for S<sup>IV</sup> oxidation, [Ru<sup>III</sup>(pic)<sub>3</sub>] can effectively and selectively oxidize sulfite to sulfate through an outer-sphere electron-transfer pathway. More information can be found in the Research Article by O. Impert and D. Chatterjee.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 3","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202580301","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal Expansion Behavior of Halide Perovskite Single Crystals Across a Broad Temperature Range
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-21 DOI: 10.1002/ejic.202400682
Dr. Yuiga Nakamura, Prof. Naoyuki Shibayama, Prof. Hideki Hayashida, Prof. Kunihisa Sugimoto, Prof. Tsutomu Miyasaka

Halide perovskite crystals are garnering significant interest as a promising material for next-generation solar cells. They are also anticipated to be applicable in devices used across a wide temperature range, including X-ray and γ-ray detectors, as well as in solar cells designed for satellite environments. The coefficient of thermal expansion of halide perovskite crystals is a critical physical property to understand, especially given the potential for mechanical degradation in layered devices due to abrupt temperature fluctuations, which may result in mismatched expansion coefficients among different layers. In this study, we employed single crystal X-ray diffraction (XRD) techniques to investigate the coefficient of thermal expansion of halide perovskite crystals, with a specific focus on CH3NH3PbI3, across an extensive temperature range. Our findings reveal that the lattice parameters exhibit discontinuous changes during the phase transition from the β-phase to the γ-phase, in stark contrast to the α to β phase transition. This observation implies that structural phase transitions at low temperatures could significantly affect the longevity and reliability of devices incorporating these materials. The methodology we have utilized for assessing coefficient of thermal expansion via single crystal structural analysis at low temperatures presents a substantial advancement in the research of halide perovskite crystals.

{"title":"Thermal Expansion Behavior of Halide Perovskite Single Crystals Across a Broad Temperature Range","authors":"Dr. Yuiga Nakamura,&nbsp;Prof. Naoyuki Shibayama,&nbsp;Prof. Hideki Hayashida,&nbsp;Prof. Kunihisa Sugimoto,&nbsp;Prof. Tsutomu Miyasaka","doi":"10.1002/ejic.202400682","DOIUrl":"https://doi.org/10.1002/ejic.202400682","url":null,"abstract":"<p>Halide perovskite crystals are garnering significant interest as a promising material for next-generation solar cells. They are also anticipated to be applicable in devices used across a wide temperature range, including X-ray and γ-ray detectors, as well as in solar cells designed for satellite environments. The coefficient of thermal expansion of halide perovskite crystals is a critical physical property to understand, especially given the potential for mechanical degradation in layered devices due to abrupt temperature fluctuations, which may result in mismatched expansion coefficients among different layers. In this study, we employed single crystal X-ray diffraction (XRD) techniques to investigate the coefficient of thermal expansion of halide perovskite crystals, with a specific focus on CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub>, across an extensive temperature range. Our findings reveal that the lattice parameters exhibit discontinuous changes during the phase transition from the β-phase to the γ-phase, in stark contrast to the α to β phase transition. This observation implies that structural phase transitions at low temperatures could significantly affect the longevity and reliability of devices incorporating these materials. The methodology we have utilized for assessing coefficient of thermal expansion via single crystal structural analysis at low temperatures presents a substantial advancement in the research of halide perovskite crystals.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 5","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mononuclear Pt(II) Complexes and [Pt-Ag-Pt] Cluster: Controllable Syntheses, Structural Transition and Luminescence Modulation
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-13 DOI: 10.1002/ejic.202400714
Xin-Tong Lv, Jian-Gong Huang, Deng-Ke Cao

Complexes [Pt(moppy)(PPh2Py)Cl] (1), [Pt(moppy)(PPh2Py)]PF6 (2) and [Pt2(moppy)2(CH3CN)2Ag(μ-PPh2Py)2](PF6)3 (3) have been synthesized through choosing suitable experimental condition to modulate the coordination mode of PPh2Py. Crystal structures indicate that 1 and 2 show distinct mononuclear structures, and complex 3 is a [Pt−Ag-Pt] cluster. In a CH2Cl2–H2O mixed solvent, complexes 1 and 2 can be interconverted upon alternately adding AgPF6 and NaCl. Complex 3 can dissociate into complex 2 in solution. These complexes reveal different luminescence. In deaerated acetone, complex 1 is non-luminescent, while 2 show green luminescence with main emission bands at 511 and 534 nm. Complexes 1 and 2 in solid state show similar green luminescence, but significant differences in quantum yield, Φ=7.4 % for 1, and Φ=17.6 % for 2. Compared to 1 and 2, complex 3⋅CH3COCH3 exhibits yellow solid-state luminescecne (Φ=14.1 %). In this paper, we discuss structural transitions among complexes 13 and luminescence modulation.

{"title":"Mononuclear Pt(II) Complexes and [Pt-Ag-Pt] Cluster: Controllable Syntheses, Structural Transition and Luminescence Modulation","authors":"Xin-Tong Lv,&nbsp;Jian-Gong Huang,&nbsp;Deng-Ke Cao","doi":"10.1002/ejic.202400714","DOIUrl":"https://doi.org/10.1002/ejic.202400714","url":null,"abstract":"<p>Complexes [Pt(moppy)(PPh<sub>2</sub>Py)Cl] (<b>1</b>), [Pt(moppy)(PPh<sub>2</sub>Py)]PF<sub>6</sub> (<b>2</b>) and [Pt<sub>2</sub>(moppy)<sub>2</sub>(CH<sub>3</sub>CN)<sub>2</sub>Ag(<i>μ</i>-PPh<sub>2</sub>Py)<sub>2</sub>](PF<sub>6</sub>)<sub>3</sub> (<b>3</b>) have been synthesized through choosing suitable experimental condition to modulate the coordination mode of PPh<sub>2</sub>Py. Crystal structures indicate that <b>1</b> and <b>2</b> show distinct mononuclear structures, and complex <b>3</b> is a [Pt−Ag-Pt] cluster. In a CH<sub>2</sub>Cl<sub>2</sub>–H<sub>2</sub>O mixed solvent, complexes <b>1</b> and <b>2</b> can be interconverted upon alternately adding AgPF<sub>6</sub> and NaCl. Complex <b>3</b> can dissociate into complex <b>2</b> in solution. These complexes reveal different luminescence. In deaerated acetone, complex <b>1</b> is non-luminescent, while <b>2</b> show green luminescence with main emission bands at 511 and 534 nm. Complexes <b>1</b> and <b>2</b> in solid state show similar green luminescence, but significant differences in quantum yield, <i>Φ</i>=7.4 % for <b>1</b>, and <i>Φ</i>=17.6 % for <b>2</b>. Compared to <b>1</b> and <b>2</b>, complex <b>3</b>⋅CH<sub>3</sub>COCH<sub>3</sub> exhibits yellow solid-state luminescecne (<i>Φ</i>=14.1 %). In this paper, we discuss structural transitions among complexes <b>1</b>–<b>3</b> and luminescence modulation.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 5","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: A Reversibly Photoswitchable Zinc Metallocycle based on Azobenzene (Eur. J. Inorg. Chem. 2/2025)
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-13 DOI: 10.1002/ejic.202580201
Oliver A. Müller, Marcel J. P. Schmitt, Christoph Riehn, Sabine Becker

The Front Cover highlights the novel azobenzene-based ligand 3,3’-azobenz(BPA)2 (1). Upon reaction with Zn(BF4)2 and ZnCl2, the metallocycle [Zn2(1)2)](BF4)4 and the linear complex [{ZnCl2}2(1)] are formed (shown left and right). Both complexes retain the reversible photoswitchability of the ligand and do not disassemble during photoisomerization. Reversible photoisomerization was observed with NMR and UV/Vis spectroscopy, which spectra are shown schematically in the background. More information can be found in the Research Article by S. Becker and co-workers.

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引用次数: 0
Construction and Reactivity of Benzimidazole-Modified Thiolate-Bridged Diiron Complexes with Different Electronic Structures
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-12 DOI: 10.1002/ejic.202400643
Kai Di, Dawei Yang, Ronghuan Du, Shengbin Dong, Baomin Wang, Jingping Qu

Thiolate-bridged diiron complexes have drawn extensive attention due to their wide applications in the biomimetic simulation for the structure and function of various metalloenzymes and the related bioinspired catalysis. Through the introduction of the functional subunit into the bridging thiolate ligands, the resulting thiolate-bridged diiron complexes with different geometric and electronic structures can exhibit distinct reactivity. Herein, we utilize a half-sandwich type of mononuclear iron complex as the reaction precursor to construct two novel thiolate-bridged diiron complexes featuring the benzimidazole moiety through the oxidative dimerization strategy. X-ray diffraction analysis reveals the two thiolate ligands containing the benzimidazole group in a syn arrangement bridge the two iron centers through the sulfur and nitrogen atoms. Furthermore, Mössbauer spectroscopy and computational studies suggest two complexes both possess two low-spin FeIII ions, but adopt different magnetic couplings to give different electronic structures. Notably, difference in geometric and electronic structures between two complexes results in the distinct reactivity toward the azide species.

{"title":"Construction and Reactivity of Benzimidazole-Modified Thiolate-Bridged Diiron Complexes with Different Electronic Structures","authors":"Kai Di,&nbsp;Dawei Yang,&nbsp;Ronghuan Du,&nbsp;Shengbin Dong,&nbsp;Baomin Wang,&nbsp;Jingping Qu","doi":"10.1002/ejic.202400643","DOIUrl":"https://doi.org/10.1002/ejic.202400643","url":null,"abstract":"<p>Thiolate-bridged diiron complexes have drawn extensive attention due to their wide applications in the biomimetic simulation for the structure and function of various metalloenzymes and the related bioinspired catalysis. Through the introduction of the functional subunit into the bridging thiolate ligands, the resulting thiolate-bridged diiron complexes with different geometric and electronic structures can exhibit distinct reactivity. Herein, we utilize a half-sandwich type of mononuclear iron complex as the reaction precursor to construct two novel thiolate-bridged diiron complexes featuring the benzimidazole moiety through the oxidative dimerization strategy. X-ray diffraction analysis reveals the two thiolate ligands containing the benzimidazole group in a <i>syn</i> arrangement bridge the two iron centers through the sulfur and nitrogen atoms. Furthermore, Mössbauer spectroscopy and computational studies suggest two complexes both possess two low-spin Fe<sup>III</sup> ions, but adopt different magnetic couplings to give different electronic structures. Notably, difference in geometric and electronic structures between two complexes results in the distinct reactivity toward the azide species.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 5","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal Structure, Band Gap, and Optoelectronic Performance of Lead-Free Cs2FeCl5⋅H2O Erythrosiderite-Halide Single Crystal and Its Thin Film
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-10 DOI: 10.1002/ejic.202400628
Chen Wang, Wenhuan Cao, Huimeng Shen, Huidan Gao, Huawei Zhou, Xiaoying Guo

The unique physical and chemical properties of erythrosiderite-halides make them candidates for semiconductor materials and optoelectronic devices. However, research on the optoelectronic properties of these materials is still relatively limited. This study presents the crystal structure and optoelectronic properties of Cs₂FeCl₅⋅H₂O erythrosiderite halide. The results show that Cs₂FeCl₅⋅H₂O is an orange-red needle-like crystal, with its crystal system and space group belonging to the orthorhombic system and Cmcm(63), respectively. Photodetectors made from Cs₂FeCl₅⋅H₂O exhibit stable photocurrent responses in the visible light range (from 397 to 564 nm). Under conditions of a light intensity of 30 W/m2 at 397 nm with a bias voltage of 4.5 V, the responsivity of Cs₂FeCl₅⋅H₂O is 8.41 mA/W, and the detectivity is 4.43 × 106 Jones. There is a strong linear relationship between the net photocurrent density of Cs₂FeCl₅⋅H₂O and light intensity, as well as a strong linear relationship between responsivity and voltage, with R2=0.96. Thus, Cs₂FeCl₅⋅H₂O has excellent optoelectronic performance and is a promising compound for optoelectronic applications.

{"title":"Crystal Structure, Band Gap, and Optoelectronic Performance of Lead-Free Cs2FeCl5⋅H2O Erythrosiderite-Halide Single Crystal and Its Thin Film","authors":"Chen Wang,&nbsp;Wenhuan Cao,&nbsp;Huimeng Shen,&nbsp;Huidan Gao,&nbsp;Huawei Zhou,&nbsp;Xiaoying Guo","doi":"10.1002/ejic.202400628","DOIUrl":"https://doi.org/10.1002/ejic.202400628","url":null,"abstract":"<p>The unique physical and chemical properties of erythrosiderite-halides make them candidates for semiconductor materials and optoelectronic devices. However, research on the optoelectronic properties of these materials is still relatively limited. This study presents the crystal structure and optoelectronic properties of Cs₂FeCl₅⋅H₂O erythrosiderite halide. The results show that Cs₂FeCl₅⋅H₂O is an orange-red needle-like crystal, with its crystal system and space group belonging to the orthorhombic system and Cmcm(63), respectively. Photodetectors made from Cs₂FeCl₅⋅H₂O exhibit stable photocurrent responses in the visible light range (from 397 to 564 nm). Under conditions of a light intensity of 30 W/m<sup>2</sup> at 397 nm with a bias voltage of 4.5 V, the responsivity of Cs₂FeCl₅⋅H₂O is 8.41 mA/W, and the detectivity is 4.43 × 10<sup>6</sup> Jones. There is a strong linear relationship between the net photocurrent density of Cs₂FeCl₅⋅H₂O and light intensity, as well as a strong linear relationship between responsivity and voltage, with R<sup>2</sup>=0.96. Thus, Cs₂FeCl₅⋅H₂O has excellent optoelectronic performance and is a promising compound for optoelectronic applications.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 5","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: An Intramolecular Bis(Amino)Phosphine-Stabilised Phosphinidene: Synthesis and CuCl Coordination (Eur. J. Inorg. Chem. 1/2025)
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-10 DOI: 10.1002/ejic.202580101
Lisa N. Kreimer, Terrance J. Hadlington

The Front Cover shows a naphthyl island that supports the growth of two P-trees, with a family of tigers moving from tree to tree. The tigers move towards the P-tree full of purple fruit, representing the intense colour of the title compound, and its electron-rich phosphinidene centre. The vast network of roots growing from this tree into the naphthyl island indicates the electron delocalisation within this system, guarded by two rare amino-parrots. More information can be found in the Research Article by L. N. Kreimer and T. J. Hadlington. Cover produced by M. Neuwirt and L. N. Kreimer

{"title":"Front Cover: An Intramolecular Bis(Amino)Phosphine-Stabilised Phosphinidene: Synthesis and CuCl Coordination (Eur. J. Inorg. Chem. 1/2025)","authors":"Lisa N. Kreimer,&nbsp;Terrance J. Hadlington","doi":"10.1002/ejic.202580101","DOIUrl":"https://doi.org/10.1002/ejic.202580101","url":null,"abstract":"<p><b>The Front Cover</b> shows a naphthyl island that supports the growth of two P-trees, with a family of tigers moving from tree to tree. The tigers move towards the P-tree full of purple fruit, representing the intense colour of the title compound, and its electron-rich phosphinidene centre. The vast network of roots growing from this tree into the naphthyl island indicates the electron delocalisation within this system, guarded by two rare amino-parrots. More information can be found in the Research Article by L. N. Kreimer and T. J. Hadlington. Cover produced by M. Neuwirt and L. N. Kreimer\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202580101","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical and Electrochemical Oxidation of Diferrocenyltelluride
IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2025-01-10 DOI: 10.1002/ejic.202400709
Corina Stoian, Nils Schmidt, Pim Puylaert, Mathias H. Linden, H. Bernhard Linden, Jens Beckmann

The halogenation of diferrocenyltelluride, Fc2Te, with XeF2, PhICl2 and I2 afforded the diferrocenyltellurium dihalides Fc2TeX2 (X=F, Cl, I). Halide exchange of Fc2TeCl2 with KBr yielded Fc2TeBr2. The oxidation of Fc2Te with NO[SbF6] and K[B(C6F5)4] provided the triferrocenyltelluronium salt [Fc3Te][B(C6F5)4] and the dinuclear nitrosyl iron complex Fe2(μ-TeFc)2(NO)4. The new compounds were comprehensively characterized by multinuclear NMR spectroscopy (125Te, 19F, 13C, 1H), UV/vis absorption spectroscopy, cyclic voltammetry, LIFDI-TOF mass spectrometry and single crystal X-ray diffraction.

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European Journal of Inorganic Chemistry
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