Jayesh R Sonawane, Rajashri Jundale, Amol A Kulkarni
This review comprehensively covers the translation from batch to continuous flow synthesis of metal nanowires (i.e., silver, copper, gold, and platinum nanowires) and their diverse applications across various sectors. Metal nanowires have attracted significant attention owing to their versatility and feasibility for large-scale synthesis. The efficacy of flow chemistry in nanomaterial synthesis has been extensively demonstrated over the past few decades. Continuous flow synthesis offers scalability, high throughput screening, and robust and reproducible synthesis procedures, making it a promising technology. Silver nanowires, widely used in flexible electronics, transparent conductive films, and sensors, have benefited from advancements in continuous flow synthesis aimed at achieving high aspect ratios and uniform diameters, though challenges in preventing agglomeration during large-scale production remain. Copper nanowires, considered as a cost-effective alternative to silver nanowires for conductive materials, have benefited from continuous flow synthesis methods that minimize oxidation and enhance stability, yet scaling up these processes requires precise control of reducing environments and copper ion concentration. A critical evaluation of various metal nanowire ink formulations is conducted, aiming to identify formulations that exhibit superior properties with lower metal solid content. This study delves into the intricacies of continuous flow synthesis methods for metal nanowires, emphasizing the exploration of engineering considerations essential for the design of continuous flow reactors. Furthermore, challenges associated with large-scale synthesis are addressed, highlighting the process-related issues.
{"title":"Continuous flow synthesis of metal nanowires: protocols, engineering aspects of scale-up and applications.","authors":"Jayesh R Sonawane, Rajashri Jundale, Amol A Kulkarni","doi":"10.1039/d4mh00781f","DOIUrl":"https://doi.org/10.1039/d4mh00781f","url":null,"abstract":"<p><p>This review comprehensively covers the translation from batch to continuous flow synthesis of metal nanowires (<i>i.e.</i>, silver, copper, gold, and platinum nanowires) and their diverse applications across various sectors. Metal nanowires have attracted significant attention owing to their versatility and feasibility for large-scale synthesis. The efficacy of flow chemistry in nanomaterial synthesis has been extensively demonstrated over the past few decades. Continuous flow synthesis offers scalability, high throughput screening, and robust and reproducible synthesis procedures, making it a promising technology. Silver nanowires, widely used in flexible electronics, transparent conductive films, and sensors, have benefited from advancements in continuous flow synthesis aimed at achieving high aspect ratios and uniform diameters, though challenges in preventing agglomeration during large-scale production remain. Copper nanowires, considered as a cost-effective alternative to silver nanowires for conductive materials, have benefited from continuous flow synthesis methods that minimize oxidation and enhance stability, yet scaling up these processes requires precise control of reducing environments and copper ion concentration. A critical evaluation of various metal nanowire ink formulations is conducted, aiming to identify formulations that exhibit superior properties with lower metal solid content. This study delves into the intricacies of continuous flow synthesis methods for metal nanowires, emphasizing the exploration of engineering considerations essential for the design of continuous flow reactors. Furthermore, challenges associated with large-scale synthesis are addressed, highlighting the process-related issues.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
All-solid-state lithium-sulfur batteries (ASSLSBs) using poly(ethylene oxide) (PEO) electrolytes offer significant advantages in energy density and safety. However, their development is hampered by the slow Li+ conduction in solid polymer electrolytes and sluggish electrochemical conversion at the cathode-electrolyte interface. Herein, we fabricate a self-healing poly(β-amino ester) with a comb-like topological structure and multiple functional groups, synthesized through a Michael addition strategy. This material modifies the PEO-based solid-state electrolyte, creating fast Li+ transport channels and improving polysulfides conversion kinetics at the electrode surface. Consequently, both modified all-solid-state lithium symmetric cells and lithium-sulfur batteries exhibit improved electrochemical performance. This work demonstrates an expanded interpenetrating macromolecular engineering approach to develop highly ion-conductive solid polymer electrolytes for ASSLSBs.
{"title":"Comb-like poly(β-amino ester)-integrated PEO-based self-healing solid electrolytes for fast ion conduction in lithium-sulfur batteries.","authors":"Hui-Min Wang, Mengdi Geng, Jing Bai, Dezhong Zhou, Weibo Hua, Sheng Liu, Xueping Gao","doi":"10.1039/d4mh01181c","DOIUrl":"https://doi.org/10.1039/d4mh01181c","url":null,"abstract":"<p><p>All-solid-state lithium-sulfur batteries (ASSLSBs) using poly(ethylene oxide) (PEO) electrolytes offer significant advantages in energy density and safety. However, their development is hampered by the slow Li<sup>+</sup> conduction in solid polymer electrolytes and sluggish electrochemical conversion at the cathode-electrolyte interface. Herein, we fabricate a self-healing poly(β-amino ester) with a comb-like topological structure and multiple functional groups, synthesized through a Michael addition strategy. This material modifies the PEO-based solid-state electrolyte, creating fast Li<sup>+</sup> transport channels and improving polysulfides conversion kinetics at the electrode surface. Consequently, both modified all-solid-state lithium symmetric cells and lithium-sulfur batteries exhibit improved electrochemical performance. This work demonstrates an expanded interpenetrating macromolecular engineering approach to develop highly ion-conductive solid polymer electrolytes for ASSLSBs.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dezhi Jiao, Sihan Gu, Li Cheng, Shuoqi Li, Chengbao Liu
Visually monitoring micro-crack initiation and corrosion failure evolution is crucial for early diagnosis of structural health and ensuring safe operation of infrastructures. However, existing damage detecting approaches are subject to the limited-detection of heterogeneous structures, intolerance of harsh environments, and challenge of quantitative analysis, impeding applications in structural health monitoring (SHM). Herein, we present a stretchable, semi-quantitative, instrument-free, supramolecular SHM sensor by integrating a polyurea elastomer with sensitive corrosion-probes, enabling localized corrosion monitoring and quantification of failure dynamics. Initially, a correlation between visual monitoring signals and structural health status is proposed, and sensor-based image processing software that accurately quantifies structural failure indicators (crack scale, corrosion reactivity and deterioration status) is proposed. Moreover, this sensor can be fabricated as multiple derivatives: a coating or patch covered on metallic substrates and an ionic-responsive test strip, ensuring real-time detection of the initiation of pitting, degradation events of metallic components and convenient monitoring of ion concentrations in corrosive media. Furthermore, the inherent geometric plasticity and dynamic hydrogen-bonded network validates the reliability for heterogeneous components and stability under extreme environments of sensors. This portable, smart SHM strategy established the channel-transformation model from corrosion dynamics to visual signals, exhibiting prospects for structural monitoring in offshore energy-harvesting equipment.
{"title":"Flexible, self-healing and portable supramolecular visualization smart sensors for monitoring and quantifying structural damage.","authors":"Dezhi Jiao, Sihan Gu, Li Cheng, Shuoqi Li, Chengbao Liu","doi":"10.1039/d4mh01233j","DOIUrl":"https://doi.org/10.1039/d4mh01233j","url":null,"abstract":"<p><p>Visually monitoring micro-crack initiation and corrosion failure evolution is crucial for early diagnosis of structural health and ensuring safe operation of infrastructures. However, existing damage detecting approaches are subject to the limited-detection of heterogeneous structures, intolerance of harsh environments, and challenge of quantitative analysis, impeding applications in structural health monitoring (SHM). Herein, we present a stretchable, semi-quantitative, instrument-free, supramolecular SHM sensor by integrating a polyurea elastomer with sensitive corrosion-probes, enabling localized corrosion monitoring and quantification of failure dynamics. Initially, a correlation between visual monitoring signals and structural health status is proposed, and sensor-based image processing software that accurately quantifies structural failure indicators (crack scale, corrosion reactivity and deterioration status) is proposed. Moreover, this sensor can be fabricated as multiple derivatives: a coating or patch covered on metallic substrates and an ionic-responsive test strip, ensuring real-time detection of the initiation of pitting, degradation events of metallic components and convenient monitoring of ion concentrations in corrosive media. Furthermore, the inherent geometric plasticity and dynamic hydrogen-bonded network validates the reliability for heterogeneous components and stability under extreme environments of sensors. This portable, smart SHM strategy established the channel-transformation model from corrosion dynamics to visual signals, exhibiting prospects for structural monitoring in offshore energy-harvesting equipment.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A synchronous way of energy generation and storage in a single portable device is in high demand for the development of high-end electromagnetic interference (EMI) free modern electronics. Thus, this study highlights the devising of a piezoelectrically self-chargeable symmetric supercapacitor (PSCS) device using a polyvinyl alcohol (PVA)/succulent inspired grown g-C3N4@lithium sodium niobate (GNLNN)/potassium hydroxide (KOH) based piezo separator with GNLNN electrode. The GNLNN electrode exhibits a surface capacitive controlled specific capacitance of 503 F g-1. The PSCS device exhibits an energy density of 15.3 W h kg-1 and a power density of 4.2 kW kg-1 with an impressive capacitive retention capability of 93.2% after 6000 cycles of charging-discharging. The PSCS device can be charged up to 393 mV within 180 s under 14.2 N of cyclic pressing by human finger imparting. The fabricated PSCS device was also investigated for self-charging potential regulated smart EMI shielding applications. The smart PSCS device achieves an 88.3 dB increment from 40.9 dB of EMI shielding under charging from 0 mV to 300 mV. The increased charging potential of the PSCS device enhances the destructive interference and leads to boosted absorption and decreased reflection of incident EM radiation.
{"title":"Succulent inspired grown g-C<sub>3</sub>N<sub>4</sub>@lithium sodium niobate for supercapacitors and piezo-tuned electrochemical potential controlled smart electromagnetic shielding management.","authors":"Prem Pal Singh, Bhanu Bhusan Khatua","doi":"10.1039/d4mh01127a","DOIUrl":"https://doi.org/10.1039/d4mh01127a","url":null,"abstract":"<p><p>A synchronous way of energy generation and storage in a single portable device is in high demand for the development of high-end electromagnetic interference (EMI) free modern electronics. Thus, this study highlights the devising of a piezoelectrically self-chargeable symmetric supercapacitor (PSCS) device using a polyvinyl alcohol (PVA)/succulent inspired grown g-C<sub>3</sub>N<sub>4</sub>@lithium sodium niobate (GNLNN)/potassium hydroxide (KOH) based piezo separator with GNLNN electrode. The GNLNN electrode exhibits a surface capacitive controlled specific capacitance of 503 F g<sup>-1</sup>. The PSCS device exhibits an energy density of 15.3 W h kg<sup>-1</sup> and a power density of 4.2 kW kg<sup>-1</sup> with an impressive capacitive retention capability of 93.2% after 6000 cycles of charging-discharging. The PSCS device can be charged up to 393 mV within 180 s under 14.2 N of cyclic pressing by human finger imparting. The fabricated PSCS device was also investigated for self-charging potential regulated smart EMI shielding applications. The smart PSCS device achieves an 88.3 dB increment from 40.9 dB of EMI shielding under charging from 0 mV to 300 mV. The increased charging potential of the PSCS device enhances the destructive interference and leads to boosted absorption and decreased reflection of incident EM radiation.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yangguang Zhu, Chen Ye, Xiao Xiao, Zhuang Sun, Xiufen Li, Li Fu, Hassan Karimi-Maleh, Jun Chen, Cheng-Te Lin
Owing to the extensive use of antibiotics for treating infectious diseases in livestock and humans, the resulting residual antibiotics are a burden to the ecosystem and human health. Hence, for human health and ecological safety, it is critical to determine the residual antibiotics with accuracy and convenience. Graphene-based electrochemical sensors are an effective tool to detect residual antibiotics owing to their advantages, such as, high sensitivity, simplicity, and time efficiency. In this work, we comprehensively summarize the recent advances in graphene-based electrochemical sensors used for detecting antibiotics, including modifiers for electrode fabrication, theoretical elaboration of electrochemical sensing mechanisms, and practical applications of portable electrochemical platforms for the on-site monitoring of antibiotics. It is anticipated that the current review will be a valuable reference for comprehensively comprehending graphene-based electrochemical sensors and further promoting their applications in the fields of healthcare, environmental protection, and food safety.
{"title":"Graphene-based electrochemical sensors for antibiotics: sensing theories, synthetic methods, and on-site monitoring applications.","authors":"Yangguang Zhu, Chen Ye, Xiao Xiao, Zhuang Sun, Xiufen Li, Li Fu, Hassan Karimi-Maleh, Jun Chen, Cheng-Te Lin","doi":"10.1039/d4mh00776j","DOIUrl":"https://doi.org/10.1039/d4mh00776j","url":null,"abstract":"<p><p>Owing to the extensive use of antibiotics for treating infectious diseases in livestock and humans, the resulting residual antibiotics are a burden to the ecosystem and human health. Hence, for human health and ecological safety, it is critical to determine the residual antibiotics with accuracy and convenience. Graphene-based electrochemical sensors are an effective tool to detect residual antibiotics owing to their advantages, such as, high sensitivity, simplicity, and time efficiency. In this work, we comprehensively summarize the recent advances in graphene-based electrochemical sensors used for detecting antibiotics, including modifiers for electrode fabrication, theoretical elaboration of electrochemical sensing mechanisms, and practical applications of portable electrochemical platforms for the on-site monitoring of antibiotics. It is anticipated that the current review will be a valuable reference for comprehensively comprehending graphene-based electrochemical sensors and further promoting their applications in the fields of healthcare, environmental protection, and food safety.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ashuang Liu, Zhimao Huang, Shengyong Cui, Ying Xiao, Xiangshu Guo, Gaoke Pan, Lei Song, Junjie Deng, Ting Xu, Youfen Fan, Rong Wang
Upper gastrointestinal bleeding (UGIB) is bleeding in the upper part of the gastrointestinal tract with an acidic and dynamic environment that limits the application of conventional hemostatic materials. This study focuses on the development of N-[(2-hydroxy-3-trimethylammonium) propyl] chitosan chloride/phytic acid (HTCC/PA, HP) powders with fast hemostatic capability and strong acid resistance, for potential applications in managing UGIB. Upon contact with liquids within 5 seconds, HP powders rapidly transform into hydrogels, forming ionic networks through electrostatic interactions. The ionic crosslinking process facilitates the HP powders with high blood absorption (3.4 times of self-weight), sufficient tissue adhesion (5.2 and 6.1 kPa on porcine skin and stomach, respectively), and hemostasis (within 15 seconds for in vitro clotting). Interestingly, the PA imparts the HP powders with strong acid resistance (69.8% mass remaining after 10 days of incubation at pH 1) and on-demand removable sealing while HTCC contributes to fast hemostasis and good wet adhesion. Moreover, the HP powders show good biocompatibility and promote wound healing. Therefore, these characteristics highlight the promising clinical potential of HP powders for effectively managing UGIB.
{"title":"Ionically assembled hemostatic powders with rapid self-gelation, strong acid resistance, and on-demand removability for upper gastrointestinal bleeding.","authors":"Ashuang Liu, Zhimao Huang, Shengyong Cui, Ying Xiao, Xiangshu Guo, Gaoke Pan, Lei Song, Junjie Deng, Ting Xu, Youfen Fan, Rong Wang","doi":"10.1039/d4mh00837e","DOIUrl":"https://doi.org/10.1039/d4mh00837e","url":null,"abstract":"<p><p>Upper gastrointestinal bleeding (UGIB) is bleeding in the upper part of the gastrointestinal tract with an acidic and dynamic environment that limits the application of conventional hemostatic materials. This study focuses on the development of <i>N</i>-[(2-hydroxy-3-trimethylammonium) propyl] chitosan chloride/phytic acid (HTCC/PA, HP) powders with fast hemostatic capability and strong acid resistance, for potential applications in managing UGIB. Upon contact with liquids within 5 seconds, HP powders rapidly transform into hydrogels, forming ionic networks through electrostatic interactions. The ionic crosslinking process facilitates the HP powders with high blood absorption (3.4 times of self-weight), sufficient tissue adhesion (5.2 and 6.1 kPa on porcine skin and stomach, respectively), and hemostasis (within 15 seconds for <i>in vitro</i> clotting). Interestingly, the PA imparts the HP powders with strong acid resistance (69.8% mass remaining after 10 days of incubation at pH 1) and on-demand removable sealing while HTCC contributes to fast hemostasis and good wet adhesion. Moreover, the HP powders show good biocompatibility and promote wound healing. Therefore, these characteristics highlight the promising clinical potential of HP powders for effectively managing UGIB.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pan Deng, Lin Chen, Yue Li, Bo-Wen Liu, Xiu-Li Wang, Yu-Zhong Wang
Both the circular economy and fire-safety of polymer plastics have become a global consensus. Herein, an integrated strategy for selectively self-recyclable, highly-transparent and fire-safe polycarbonate plastic is proposed by thermally responsive phosphonium-phosphate (DP). During its service life, DP, as a flame-retardant with good compatibility, enables polycarbonate plastic with high transparency in visible light, excellent self-extinguishing and high fire-safety. After consumption, DP, as a catalyst, triggers the selective self-recycling of DP-containing polycarbonate in mixed plastics and even in same-kind polycarbonate plastics without an external catalyst. Importantly, the oxygen-consuming mechanism at high temperature in fire accidents (>350 °C) and the double hydrogen bond catalysis mechanism at a lower temperature (180 °C) of DP are key to the life cycle management of polycarbonate from use-stage to post-consumption. This work inspires a new solution to plastic pollution by designing sustainable plastics that satisfy both service-stage and end-of-life criteria, striving towards a zero-waste circular economy.
{"title":"Selectively self-recyclable, highly transparent and fire-safe polycarbonate plastic enabled by thermally responsive phosphonium-phosphate.","authors":"Pan Deng, Lin Chen, Yue Li, Bo-Wen Liu, Xiu-Li Wang, Yu-Zhong Wang","doi":"10.1039/d4mh01139b","DOIUrl":"https://doi.org/10.1039/d4mh01139b","url":null,"abstract":"<p><p>Both the circular economy and fire-safety of polymer plastics have become a global consensus. Herein, an integrated strategy for selectively self-recyclable, highly-transparent and fire-safe polycarbonate plastic is proposed by thermally responsive phosphonium-phosphate (DP). During its service life, DP, as a flame-retardant with good compatibility, enables polycarbonate plastic with high transparency in visible light, excellent self-extinguishing and high fire-safety. After consumption, DP, as a catalyst, triggers the selective self-recycling of DP-containing polycarbonate in mixed plastics and even in same-kind polycarbonate plastics without an external catalyst. Importantly, the oxygen-consuming mechanism at high temperature in fire accidents (>350 °C) and the double hydrogen bond catalysis mechanism at a lower temperature (180 °C) of DP are key to the life cycle management of polycarbonate from use-stage to post-consumption. This work inspires a new solution to plastic pollution by designing sustainable plastics that satisfy both service-stage and end-of-life criteria, striving towards a zero-waste circular economy.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fengyang Wang, Mohammad Morsali, Jānis Rižikovs, Ievgen Pylypchuk, Aji P Mathew, Mika H Sipponen
Surface protection is essential when using wood as a construction material. However, the industry lacks sustainable alternatives to replace the presently dominant fossil-based synthetic water-resistant coatings. Here, we show a fully bio-based wood surface protection system using components sourced from birch bark and spruce bark, inspired by the natural barrier function of bark in trees. The coating formulation contains suberinic acids and spruce bark polyphenols, resulting in a waterborne suspension that is safe and easy to apply to wood. The polyphenols play a dual role in the formulation as they stabilize the water-insoluble suberinic acids and serve as nanofillers in the thermally cured coating, enabling the adjustment of the mechanical properties of the resulting coating. When applied to spruce wood, the coating formulation with 10% polyphenol and 90% suberinic acids achieved a water absorption value of 100 g m-2 after 72 hours of water exposure, demonstrating superior performance compared to an alkyd emulsion coating. We conclude that instead of combusting tree bark, it can serve as a valuable resource for wood protection, closing the circle in the wood processing industry.
{"title":"Fully bio-based water-resistant wood coatings derived from tree bark.","authors":"Fengyang Wang, Mohammad Morsali, Jānis Rižikovs, Ievgen Pylypchuk, Aji P Mathew, Mika H Sipponen","doi":"10.1039/d4mh01010h","DOIUrl":"https://doi.org/10.1039/d4mh01010h","url":null,"abstract":"<p><p>Surface protection is essential when using wood as a construction material. However, the industry lacks sustainable alternatives to replace the presently dominant fossil-based synthetic water-resistant coatings. Here, we show a fully bio-based wood surface protection system using components sourced from birch bark and spruce bark, inspired by the natural barrier function of bark in trees. The coating formulation contains suberinic acids and spruce bark polyphenols, resulting in a waterborne suspension that is safe and easy to apply to wood. The polyphenols play a dual role in the formulation as they stabilize the water-insoluble suberinic acids and serve as nanofillers in the thermally cured coating, enabling the adjustment of the mechanical properties of the resulting coating. When applied to spruce wood, the coating formulation with 10% polyphenol and 90% suberinic acids achieved a water absorption value of 100 g m<sup>-2</sup> after 72 hours of water exposure, demonstrating superior performance compared to an alkyd emulsion coating. We conclude that instead of combusting tree bark, it can serve as a valuable resource for wood protection, closing the circle in the wood processing industry.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gas sensors convert gas-related information into usable data by monitoring changes in conductivity and chemical reactions resulting from the adsorption of gas molecules. Recently, perovskites have emerged as promising candidate materials for gas sensors, owing to their polar reactivity, chemical responsiveness, and sensitivity. These characteristics enable the detection of the presence and concentration of various gases. This article provides a concise review of recent advancements in perovskite-based gas sensors. First, the chemical composition, structure, and preparation methods of perovskites, as well as the effects of their structure on gas sensing performance, are examined. The key performance parameters of the sensor and the sensing mechanism of the perovskite-based gas sensor are discussed. Then the development of gas sensors based on different structural types of perovskites, including single-component perovskites, mixed-component perovskites, and metal-oxide perovskites, is discussed. Finally, the challenges and opportunities for gas sensors based on perovskites are summarized and prospected.
{"title":"Recent progress of gas sensors based on perovskites.","authors":"Chenghong Wei, Ziyi Guo, Heng Wang, Shiqi Zhang, Dandan Hao, Jia Huang","doi":"10.1039/d4mh01306a","DOIUrl":"https://doi.org/10.1039/d4mh01306a","url":null,"abstract":"<p><p>Gas sensors convert gas-related information into usable data by monitoring changes in conductivity and chemical reactions resulting from the adsorption of gas molecules. Recently, perovskites have emerged as promising candidate materials for gas sensors, owing to their polar reactivity, chemical responsiveness, and sensitivity. These characteristics enable the detection of the presence and concentration of various gases. This article provides a concise review of recent advancements in perovskite-based gas sensors. First, the chemical composition, structure, and preparation methods of perovskites, as well as the effects of their structure on gas sensing performance, are examined. The key performance parameters of the sensor and the sensing mechanism of the perovskite-based gas sensor are discussed. Then the development of gas sensors based on different structural types of perovskites, including single-component perovskites, mixed-component perovskites, and metal-oxide perovskites, is discussed. Finally, the challenges and opportunities for gas sensors based on perovskites are summarized and prospected.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Moslem Moradi, Oleg E Shklyaev, Wenzheng Shi, Anna C Balazs
Communication in biological systems typically involves enzymatic reactions that occur within fluids confined between the soft, elastic walls of bio-channels and chambers. Through the inherent transformation of chemical to mechanical energy, the fluids can be driven to flow within the confined domains. Through fluid-structure interactions, the confining walls in turn are deformed by and affect this fluid flow. Imbuing synthetic materials with analogous feedback among chemo-mechanical, hydrodynamic and fluid-structure interactions could enable materials to perform self-driven communication and self-regulation. Herein, we develop computational models to determine how chemo-hydro-mechanical feedback affects interactions in biomimetic arrays of chemically active and passive micro-posts anchored in fluid-filled chambers. Once activated, the enzymatic reactions trigger the latter feedback, which generates a surprising variety of long-range, cooperative motion, including self-oscillations and non-reciprocal interactions, which are vital for propagating coherent, directional signals over net distances in fluids. In particular, the array propagates a distinct message; each post interprets the message; and the system responds with a specific mode of organized, collective behavior. This level of autonomous remote control is relatively rare in synthetic systems, particularly as this system operates without external electronics or power sources and only requires the addition of chemical reactants to function.
{"title":"Fluid mediated communication among flexible micro-posts in chemically reactive solutions.","authors":"Moslem Moradi, Oleg E Shklyaev, Wenzheng Shi, Anna C Balazs","doi":"10.1039/d4mh01111b","DOIUrl":"https://doi.org/10.1039/d4mh01111b","url":null,"abstract":"<p><p>Communication in biological systems typically involves enzymatic reactions that occur within fluids confined between the soft, elastic walls of bio-channels and chambers. Through the inherent transformation of chemical to mechanical energy, the fluids can be driven to flow within the confined domains. Through fluid-structure interactions, the confining walls in turn are deformed by and affect this fluid flow. Imbuing synthetic materials with analogous feedback among chemo-mechanical, hydrodynamic and fluid-structure interactions could enable materials to perform self-driven communication and self-regulation. Herein, we develop computational models to determine how chemo-hydro-mechanical feedback affects interactions in biomimetic arrays of chemically active and passive micro-posts anchored in fluid-filled chambers. Once activated, the enzymatic reactions trigger the latter feedback, which generates a surprising variety of long-range, cooperative motion, including self-oscillations and non-reciprocal interactions, which are vital for propagating coherent, directional signals over net distances in fluids. In particular, the array propagates a distinct message; each post interprets the message; and the system responds with a specific mode of organized, collective behavior. This level of autonomous remote control is relatively rare in synthetic systems, particularly as this system operates without external electronics or power sources and only requires the addition of chemical reactants to function.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":null,"pages":null},"PeriodicalIF":12.2,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142453643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}