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Photoluminescence from Ordered Ge/Si Quantum Dot Groups Grown on the Strain‐Patterned Substrates 应变图案衬底上生长的有序Ge/Si量子点群的光致发光
Pub Date : 2017-09-15 DOI: 10.1002/PSSC.201700187
A. Dvurechenskii, A. Zinovieva, V. Zinovyev, A. Nenashev, Zh. V. Smagina, S. Teys, A. Shklyaev, S. Erenburg, S. Trubina, O. M. Borodavchenko, V. Zhivulko, A. Mudryi
The photoluminescence (PL) properties of combined Ge/Si structures representing a combination of large (200–250 nm) SiGe disk-like quantum dots (QDs) and the groups of smaller (40–50 nm) laterally ordered QDs grown on the nanodisk surface are studied. The experimental results are analyzed basing on the calculations of energy spectra, electron and hole wave functions. It is found that the strain accumulation in multi-layered structure is the main factor providing the room temperature PL. The new type of QD structures that should provide the observation of enhanced PL from SiGe QDs at room temperature is proposed. The structures represent the stacked compact groups of laterally aligned QDs incorporated in Si at the distance 30–40 nm above the large nanodisks.
研究了由大的(200-250 nm) SiGe盘状量子点(QDs)和小的(40-50 nm)横向有序量子点组合而成的Ge/Si结构的光致发光(PL)特性。基于能谱、电子和空穴波函数的计算,对实验结果进行了分析。发现多层结构中的应变积累是提供室温PL的主要因素,并提出了一种在室温下可以从SiGe量子点观察到增强PL的新型量子点结构。该结构代表了在大纳米片上方30-40 nm处的Si中横向排列的量子点堆叠致密团。
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引用次数: 4
Coupling Optical and Electrical Modelling for the study of a-Si:H-based nanowire Array Solar Cells a-Si: h基纳米线阵列太阳能电池研究的耦合光学和电学建模
Pub Date : 2017-09-15 DOI: 10.1002/PSSC.201700181
Alexandra Levtchenko, R. Lachaume, Jérôme Michallon, S. Collin, J. Alvarez, S. D. Gall, Z. Djebbour, J. Kleider
Coupled optical/electrical simulations have been performed on solar cells consisting in arrays of p-i-n radial nanowires based on crystalline p-type silicon (c-Si) core/hydrogenated amorphous silicon (a-Si:H) shell heterojunctions. Three-dimensional (3D) optical calculations based on rigorous coupled wave analysis (RCWA) are firstly performed and then coupled to a semiconductor device simulator that exploits the radial symmetry of the nanowires. By varying either the doping concentration of the c-Si core, or the work function of the Al-doped ZnO (AZO) back contact we can separate and originally highlight the contribution to the cells performance of the nanowires themselves (the radial cell) from the planar part in between the nanowires (the planar cell). We show that the short-circuit current density (Jsc) only depends on the doping of the c-Si core indicating that it is mainly influenced by the radial cell. On the contrary the open-circuit voltage (Voc) is strongly affected by the back contact conditions (AZO work function), revealing an important impact of the interspacing between the nanowires on the characteristics of the entire nanowire array. We explain this strong influence of the back contact conditions by the fact that it determines the band-bending in the a-Si:H absorber shell touching the AZO, i.e. in the planar part. Therefore, it directly impacts the potential drop (Vbi) in the same area. For low AZO work functions, the dark current density (Jdark) is increased in the planar region, where Vbi is lower, which degrades the Voc of the entire cell.
对基于晶体p型硅(c-Si)核/氢化非晶硅(a-Si:H)壳异质结的p-i-n径向纳米线阵列太阳能电池进行了耦合光学/电学模拟。首先进行了基于严格耦合波分析(RCWA)的三维光学计算,然后耦合到利用纳米线径向对称性的半导体器件模拟器上。通过改变c-Si核心的掺杂浓度或al掺杂ZnO (AZO)背触点的功函数,我们可以将纳米线本身(径向电池)与纳米线之间的平面部分(平面电池)分开并最初突出对电池性能的贡献。我们发现短路电流密度(Jsc)只取决于c-Si芯的掺杂,表明它主要受径向电池的影响。相反,开路电压(Voc)受到反接触条件(AZO功函数)的强烈影响,揭示了纳米线间距对整个纳米线阵列特性的重要影响。我们解释了背接触条件的这种强烈影响,因为它决定了a-Si:H吸收壳接触AZO的带弯曲,即在平面部分。因此,它直接影响到同一区域的电位降(Vbi)。对于低AZO功函数,在Vbi较低的平面区域暗电流密度(Jdark)增加,从而降低了整个电池的Voc。
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引用次数: 3
High Sensitivity Flame Sensor Based on PbS Colloidal Quantum Dots 基于PbS胶体量子点的高灵敏度火焰传感器
Pub Date : 2017-09-15 DOI: 10.1002/PSSC.201700186
A. D. Iacovo, Carlo Venettacci, L. Colace, L. Scopa, S. Foglia
Flame sensing and early fire detection are primary features in modern security and surveillance systems. Optical detection systems are widely developed and offer the highest sensitivity and selectivity but they are still expensive and show a high power budget. Here we propose a low-cost, low-power flame detector based on PbS colloidal quantum dots. We show detector operation with a 21 nW total power dissipation and the ability to detect the flame of a candle at 20 m with a 5 dB signal to noise ratio (SNR).
火焰传感和早期火灾探测是现代安防监控系统的主要特征。光学检测系统得到了广泛的发展,并提供了最高的灵敏度和选择性,但它们仍然昂贵,并且显示出高功率预算。本文提出了一种基于PbS胶体量子点的低成本、低功耗火焰探测器。我们展示了检测器的工作,总功耗为21 nW,能够以5 dB的信噪比(SNR)检测20米处蜡烛的火焰。
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引用次数: 1
Flexible Cu(In,Ga)Se2 Based Solar Cells Using Molybdenum Foils as Substrate 以钼箔为衬底的柔性Cu(In,Ga)Se2基太阳能电池
Pub Date : 2017-09-14 DOI: 10.1002/PSSC.201700174
M. Stanley, M. Jubault, F. Donsanti, N. Naghavi
Recently, there has been increased interest in the use of flexible substrates for the fabrication of Cu(In,Ga)Se2 solar cells due to their light weight and easy application. This work focuses on the use of 150 μm thick Mo foils as substrates which has not received much attention compared to other metals such as Ti and Stainless Steel although the coefficient of expansion of Mo better matches that of CIGS. Interestingly, Mo foil can be used as both the substrate and back contact which reduces the manufacturing steps of this type of solar cell. The CIGS absorbers herein were realized by a 3-stage coevaporation process. This work studies the impact of temperature, Na incorporation and the optimization of the Ga gradient on the cell performance using different characterization techniques such as XRD, GD-OES, and IV measurements. Efficiencies up to 14%, with Voc = 0.60 V, Jsc = 34.1 mA cm−2 and FF = 70.4% have been obtained.
近年来,人们对使用柔性衬底制造Cu(in,Ga)Se2太阳能电池越来越感兴趣,因为它们重量轻,易于应用。本文的工作重点是使用150 μm厚的Mo箔作为衬底,尽管Mo的膨胀系数与CIGS的膨胀系数更匹配,但与Ti和不锈钢等其他金属相比,这种衬底并未受到太多关注。有趣的是,钼箔既可以用作衬底,也可以用作背触点,从而减少了这种类型太阳能电池的制造步骤。CIGS吸收器采用三段共蒸发工艺实现。本文采用不同的表征技术,如XRD、GD-OES和IV测量,研究了温度、Na掺入和Ga梯度优化对电池性能的影响。效率高达14%,Voc = 0.60 V, Jsc = 34.1 mA cm - 2, FF = 70.4%。
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引用次数: 4
Impact of the Seed Layer Morphology on the Initial Growth of HPMC‐Si Ingot 种子层形态对HPMC - Si铸锭初始生长的影响
Pub Date : 2017-09-13 DOI: 10.1002/PSSC.201700177
Giri Wahyu Alam, E. Pihan, B. Marie, N. Mangelinck-Noël
In High Performance Multi-Crystalline-Silicon (HPMC-Si) ingots, small seed grains generate grain boundaries that can terminate the propagation of dislocation clusters. Here, we focus on the seed template formation and its impact on the initial growth by directional solidification utilizing metallography, photoluminescence, and EBSD analysis. In the seed region, two randomly oriented grain morphologies are found: a genuine nonmelted seed from the poly-Si chunks, and a re-solidified infiltrated molten silicon region. All grains grow by epitaxy on the seed grains and grains grown from wider grains in the seed, reach a higher solidification height.
在高性能多晶硅(HPMC-Si)铸锭中,细小的种子晶粒产生的晶界可以终止位错团簇的扩展。本文利用金相、光致发光和EBSD分析等方法研究了定向凝固过程中种子模板的形成及其对初始生长的影响。在种子区,发现了两种随机取向的晶粒形态:一种是来自多晶硅块的真正未熔化的种子,另一种是再固化的渗透熔融硅区。所有晶粒都是在种晶上外延生长,在种晶上由更宽的晶粒生长而来的晶粒达到更高的凝固高度。
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引用次数: 2
Formation and Strain Analysis of Stacked Ge Quantum Dots With Strain‐Compensating Si1−xCx Spacer 应变补偿Si1−xCx间隔层叠加Ge量子点的形成和应变分析
Pub Date : 2017-09-11 DOI: 10.1002/PSSC.201700197
Y. Itoh, T. Kawashima, K. Washio
To stack Ge quantum dots (QDs) in a multilayer structure without undesirable enlargement of the QDs, the effects of both Si1−xCx spacer on a strain compensation of the embedded QDs and a sub-monolayer (ML) carbon (C) mediation on a formation of the Volmer-Weber (VW)-mode Ge QDs on the Si1−xCx spacer were investigated. In a Si1−xCx/Ge/Si(100) structure, lattice rexation of the embedded QDs was kept about 80% at x = 0.015. This maintaining the state of high relaxation attributed to a tensile strain from the Si1−xCx layer grown on a surface of a Si substrate around the QDs. In addition, by utilizing an analysis of Kelvin probe force microscopy, it was revealed that the sub-ML C mediation of 0.25 ML and over is effective to form the VW-mode Ge QDs on the Si1−xCx spacer. This is because the promotion of subdivision effect for the formation of the QDs via C mediation was also effective on the Si1−xCx surface. At C = 0.25 and 0.5 ML, diameter and density of second QDs were about 22 nm and 1.5 × 1011 cm−2, respectively. These results pave the way to stack the VW-mode Ge QDs in the multilayer structure without enlargement of the QDs.
为了将Ge量子点(QDs)堆叠在多层结构中而不导致QDs的扩大,研究了Si1−xCx间隔层对嵌入量子点应变补偿的影响,以及亚单层(ML)碳(C)介质对Si1−xCx间隔层上Volmer-Weber (VW)模式Ge量子点形成的影响。在Si1−xCx/Ge/Si(100)结构中,当x = 0.015时,嵌入的量子点的晶格还原率保持在80%左右。这保持了高弛豫状态,这是由于生长在量子点周围Si衬底表面的Si1−xCx层的拉伸应变造成的。此外,利用开尔文探针力显微镜分析发现,0.25 ML及以上的亚ML C介质可以有效地在Si1−xCx间隔层上形成vw模式的Ge量子点。这是因为在Si1−xCx表面上,通过C介质促进量子点形成的细分效应也是有效的。在C = 0.25和0.5 ML时,第二个量子点的直径约为22 nm,密度约为1.5 × 1011 cm−2。这些结果为在不扩大量子点的情况下在多层结构中堆叠vw模式的Ge量子点铺平了道路。
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引用次数: 0
Investigation of Structural, Optical, and Electrical Properties of In‐Doped SnO2 Thin Films Deposited by Spray Pyrolysis 喷雾热解沉积In掺杂SnO2薄膜的结构、光学和电学性质研究
Pub Date : 2017-09-11 DOI: 10.1002/PSSC.201700189
A. Hadri, A. E. Hat, M. Sekkati, A. Mzerd
In this work, undoped and 1–5 at.% In-doped SnO2-δ films are deposited onto glass substrates at 350 °C by spray pyrolysis technique. The influence of dopant concentration is investigated using X-ray diffraction (XRD), UV-Visible spectroscopy, and Hall Effect measurements using van der Pauw method. X-ray diffraction studies indicate that all films had preferred orientation along (200) plane and are polycrystalline with tetragonal rutile structure. The calculated average crystallite sizes increased after doping. Substitution of In into SnO2-δ thin films can be confirmed by the shifting of the peaks in the XRD patterns. Optical transmittance of the films show high average transparency ∼80–90% in the visible region. Hall measurements show that the conduction type is dependent on In content. For low-doped films (In ≤3 at.%), the films are n-type, while at higher doping concentration the films are p-type. The calculated values of the mean free path are very small compared to the average crystallite sizes calculated using XRD measurements. Therefore, we suggest that ionized and/or neutral impurity scattering are the main scattering mechanisms in these films. The above-mentioned characteristics render these In-doped SnO2 films potential candidates for their use in light-emitting diode and in optoelectronic devices, with the advantage that they are prepared by a simple and economical technique.
在这项工作中,未掺杂和1-5 at。采用喷雾热解技术,在350℃的温度下在玻璃衬底上沉积了掺杂SnO2-δ薄膜。采用x射线衍射(XRD)、紫外可见光谱和范德波法测量霍尔效应研究了掺杂剂浓度的影响。x射线衍射研究表明,所有薄膜沿(200)面均具有择优取向,为四边形金红石型多晶结构。计算得到的平均晶粒尺寸在掺杂后增大。在SnO2-δ薄膜中可以通过XRD谱图中峰的移动来证实In的取代作用。在可见光区,薄膜的平均透光率为80-90%。霍尔测量表明,导电类型与In含量有关。低掺杂时(In≤3 at.%)薄膜为n型,高掺杂时薄膜为p型。平均自由程的计算值与用XRD测量得到的平均晶粒尺寸相比非常小。因此,我们认为电离和/或中性杂质散射是这些薄膜的主要散射机制。上述特性使这些掺杂SnO2薄膜具有用于发光二极管和光电子器件的潜在候选物,其优点是制备方法简单且经济。
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引用次数: 2
Improved Reliability Performance of Junctionless Nanoscale DG MOSFET with Graded Channel Doping Engineering 采用渐变通道掺杂技术提高无结纳米级DG MOSFET的可靠性性能
Pub Date : 2017-09-07 DOI: 10.1002/PSSC.201700147
T. Bentrcia, F. Djeffal, D. Arar, Elasaad Chebaki
In the last few years, an accelerated trend toward the miniaturization of nanoscale circuits has been recorded. In fact, this has been reflected by numerous enhancements at different levels of multi-gate structures such as the channel body or the gate material. Our aim in this work is to investigate the reliability performance of junctionless DG MOSFET including graded channel aspect. The behavior of the considered device is analyzed numerically using ATLAS-2D simulator, where degradation phenomena are accounted for in the model. The variation of some analog/RF criteria namely the transconductance and cut-off frequency are established in terms of the channel length and traps density. The obtained responses indicate the superior immunity of the graded channel device against traps-induced degradation in comparison to the conventional structure. Thus, this work can offer more insights regarding the benefit of adopting the channel doping engineering for future nanoscale electronic applications.
在过去的几年里,纳米电路小型化的趋势加速发展。事实上,这已经在多栅极结构(如通道体或栅极材料)的不同层次上得到了许多改进。我们在这项工作的目的是研究无结DG MOSFET的可靠性性能,包括梯度通道方面。使用ATLAS-2D模拟器对所考虑的器件的行为进行了数值分析,其中模型中考虑了退化现象。一些模拟/射频标准的变化,即跨导和截止频率,是根据信道长度和陷阱密度建立的。得到的响应表明,与传统结构相比,梯度通道器件对陷阱诱导的退化具有更好的免疫能力。因此,这项工作可以为未来纳米级电子应用中采用通道掺杂工程的好处提供更多的见解。
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引用次数: 1
Efficiency Enhancement of a-Si:H/c-Si-Based Radial Solar Cell by Optimizing the Geometrical and Electrical Parameters 优化几何和电学参数提高a-Si:H/c- si基径向太阳能电池效率
Pub Date : 2017-09-07 DOI: 10.1002/PSSC.201700146
H. Ferhati, F. Djeffal, D. Arar, Z. Dibi
In this paper, a new particle swarm optimization-based approach is proposed for the geometrical optimization of the nanowires solar cells to achieve improved optical performance. The proposed hybrid approach combines the 3-D numerical analysis using accurate solutions of Maxwell's equations and metaheuristic investigation to boost the solar cell total absorbance efficiency. Our purpose resides on modulating the electric field and increasing the light trapping capability by optimizing the radial solar cell geometrical parameters. Moreover, a comprehensive study of vertical core-shell nanowire arrays optical parameters such as the integral absorption, reflection, and total absorbance efficiency is carried out, in order to reveal the optimized radial solar cells optical performance for low-cost photovoltaic applications. We find that the proposed hybrid approach plays a crucial role in improving the nanowires solar cells optical performance, where the optimized design exhibits superior total absorbance efficiency and lower total reflection in comparison with those provided by the conventional planar design. The obtained results make the proposed global optimization approach valuable for providing high-efficiency nanowires solar cells.
本文提出了一种基于粒子群优化的纳米线太阳能电池几何优化方法,以提高其光学性能。提出的混合方法结合了三维数值分析的精确解麦克斯韦方程组和元启发式研究,以提高太阳能电池的总吸光度效率。我们的目的在于通过优化径向太阳能电池的几何参数来调制电场和增加光捕获能力。此外,为了揭示适合低成本光伏应用的优化径向太阳能电池的光学性能,对垂直核壳纳米线阵列的积分吸收、反射和总吸收效率等光学参数进行了全面的研究。我们发现,这种混合方法对提高纳米线太阳能电池的光学性能起着至关重要的作用,与传统的平面设计相比,优化设计的纳米线太阳能电池具有更高的总吸收效率和更低的总反射。研究结果表明,所提出的全局优化方法对于提供高效率的纳米线太阳能电池具有重要意义。
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引用次数: 1
PbS Colloidal Quantum Dot Near Infrared Photoconductors: DC and Noise Characterization PbS胶体量子点近红外光导体:直流和噪声特性
Pub Date : 2017-09-06 DOI: 10.1002/pssc.201700185
L. Colace, A. D. Iacovo, Carlo Venettacci
High sensitivity photodetectors based on PbS colloidal quantum dots have been demonstrated by several research groups in the last years with performance comparable to commercial III–V semiconductor devices. Nevertheless, investigation of the noise performance of such new photodetectors is still lacking. Here we report on the characterization of PbS colloidal quantum dot near infrared photoconductors including a preliminary analysis of noise power spectra. Devices have been characterized focusing on the low frequency regime (up to 10 kHz) investigating the noise dependence on the voltage bias.
基于PbS胶体量子点的高灵敏度光电探测器在过去几年中已经被几个研究小组证明,其性能可与商用III-V型半导体器件相媲美。然而,对这种新型光电探测器的噪声性能的研究仍然缺乏。本文报道了PbS胶体量子点近红外光导体的特性,包括噪声功率谱的初步分析。器件的特点集中在低频状态(高达10khz),研究噪声对电压偏置的依赖。
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引用次数: 0
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