The collapse behavior of nanobubble in the vicinity of solid-liquid interface under impact loading critically influences material erosion, cavitation damage, and surface degradation in fluid-structure systems. This study employs the Reactive Molecular Dynamics (RMD) method to investigate the dynamic processes of nanobubble collapse near solid-liquid interface at realistic impact velocities. The simulation procedure involved initial Canonical ensemble (The NVT ensemble) equilibration of water molecules and iron atoms, followed by microcanonical ensemble (The NVE ensemble) impact loading via piston driving with an initial velocity of 5 km/s in the z-direction. We tracked the propagation of shock waves, the evolution of atomic velocity fields, and the spatiotemporal evolution of nanobubble radius, revealing complex deformation and collapse characteristics of nanobubble with different initial radius. Results show that nanobubble collapse morphology, energy localization effects, and momentum transfer to iron substrates are highly sensitive to nanobubble size. Notably, larger nanobubble induce local localized compressive-stress peaks that significantly alter substrate surface roughness and microstructural features, shedding light on potential mechanisms of surface erosion and fatigue initiation. This study elucidated the cavitation damage mechanism at the atomic scale, verified the reactive force field (ReaxFF) method's analytical capability in coupling chemical-mechanical responses under extreme conditions, and provided a theoretical basis for multi-scale modeling of cavitation erosion phenomena in engineering materials.


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