The conservative Allen–Cahn (CAC) equation is a second-order nonlinear partial differential equation that models phase separation in binary mixtures while preserving the total volume. Physics-informed neural networks (PINNs) have demonstrated considerable success in approximating solutions to various classes of partial differential equations; however, their application to CAC models remains challenging. These difficulties stem from the presence of a small interfacial parameter in the nonlinear term and highly nonlinear mass-correction terms , , which significantly degrade the approximation accuracy and mass conservation properties of standard PINNs. In this work, we propose a novel hybrid mass-constrained physics-informed neural network (Mc-PINN) framework for efficiently and accurately solving three types of CAC models in convex polygonal domains. The proposed method integrates deep learning with operator-splitting strategies to decompose the original CAC equations into simpler subproblems. One subproblem admits an analytical solution, while the other is solved using the Mc-PINN scheme. To further enhance efficiency, a Metropolis–Hastings based adaptive sampling strategy is introduced. In addition, we derive error estimates for the proposed method applied to all three CAC models. Numerical experiments demonstrate the robustness, accuracy, and mass-conservation capability of the proposed framework.
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