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Distorted land price and green innovation: empirical evidence from 273 cities in China 扭曲地价与绿色创新:来自中国273个城市的经验证据
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-25 DOI: 10.1007/s10668-024-05901-x
Quan Xiao, Xinhe Chen, Jing Gao, Xubing Fang

Green innovation is an important catalyst for achieving China’s sustainable transformation and “double carbon” goals. Taking distorted land price as the entry point, this article utilizes 273 cities and corporate-level data from 2005 to 2019 and employs a spatial econometric model system to investigate the influence of distorted land price on corporate green innovation and its underlying mechanisms. The findings suggest a significant negative impact of distorted land price on corporate green innovation, with substantial regional heterogeneity. Furthermore, distorted land price exhibits a spatial spillover effect, detrimentally influencing corporate green innovation. Mechanism tests indicate that distorted land price influences corporate green innovation through the supply–demand effect and price effect. Threshold effects tests show a non-linear influence of distorted land price on corporate green innovation in different policy contexts. A certain policy threshold can moderate the adverse effects of distorted land price on corporate green innovation. By dissecting the intrinsic mechanism between land price and corporate green innovation, this paper contributes valuable policy insights for China’s green economic transformation and the pursuit of “carbon peaking” and “carbon neutrality” in the context of global green development.

绿色创新是实现中国可持续转型和“双碳”目标的重要催化剂。本文以扭曲地价为切入点,利用2005 - 2019年273个城市和企业层面的数据,运用空间计量模型系统研究扭曲地价对企业绿色创新的影响及其机制。研究发现,土地价格扭曲对企业绿色创新具有显著的负向影响,且具有显著的区域异质性。此外,扭曲的土地价格表现出空间溢出效应,不利于企业的绿色创新。机制检验表明,土地价格扭曲通过供需效应和价格效应影响企业绿色创新。门槛效应检验表明,在不同政策背景下,扭曲地价对企业绿色创新的影响呈非线性。一定的政策门槛可以缓和地价扭曲对企业绿色创新的不利影响。本文通过剖析土地价格与企业绿色创新之间的内在机制,为全球绿色发展背景下中国经济绿色转型以及追求“碳峰值”和“碳中和”提供了有价值的政策见解。
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引用次数: 0
Greening gateways: navigating tourists pro-environmental behavior through norms and emotions 绿色门户:通过规范和情感引导游客亲环境行为
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-25 DOI: 10.1007/s10668-024-05890-x
Qingyu Zhang, Safeer Ullah Khan, Salman Khan, Ikram Ullah Khan, Shafaqat Mehmood

Sustainable tourism initiatives depend heavily on tourists' environmental behavior, with their willingness to adopt sustainable practices being crucial for the success of destination marketing campaigns. Grounded on the cognitive dissonance theory and the norm activation model, an integrated framework was built to investigate the influence of green guilt on the pro-environmental behavior (PEB) of forest park visitors, considering the mediating roles of social and personal norms. We also explored the moderating role of positive emotions, providing theoretical and practical implications for promoting sustainability in tourist destinations and encouraging positive human-nature interactions. Based on a sample of 293 visitors from a national forest park in Pakistan, the results showed that green guilt significantly enhanced personal norms, which in turn mediated the link between green guilt and PEB. Personal norms played a significant mediating role in this process. Moreover, positive emotions moderated on the link between green guilt and PEB. The study concludes with theoretical implications for sustainable tourism and practical recommendations for practitioners.

可持续旅游计划在很大程度上取决于游客的环境行为,他们是否愿意采取可持续的做法对目的地营销活动的成功至关重要。基于认知失调理论和规范激活模型,考虑社会规范和个人规范的中介作用,构建绿色内疚对森林公园游客亲环境行为影响的整合框架。我们还探讨了积极情绪的调节作用,为促进旅游目的地的可持续性和鼓励积极的人与自然互动提供了理论和实践意义。基于293名来自巴基斯坦国家森林公园的游客的样本,结果表明绿色内疚显著增强了个人规范,而个人规范反过来又中介了绿色内疚与PEB之间的联系。个人规范在这一过程中起着重要的中介作用。此外,积极情绪调节了绿色内疚和PEB之间的联系。本研究总结了可持续旅游的理论意义和对从业者的实践建议。
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引用次数: 0
Strategic interactions of Chinese cities in improving total factor energy efficiency: a two-regime spatial econometric analysis 中国城市在提高全要素能源效率中的战略互动:一种双机制空间计量分析
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-24 DOI: 10.1007/s10668-024-05844-3
Lixingzi Yang, Weijin Qian

Exploring the strategic interactions of Chinese cities in improving total factor energy efficiency (TFEE) is crucial for promoting regional sustainable development. However, existing literature lacks a comprehensive analysis of the complex patterns and mechanisms of these interactions. Using city-level data from 2006 to 2017, this study contributes to the literature by employing single-regime and two-regime spatial Durbin models to investigate the spatial spillover effects and strategic interactions of cities’ TFEE improvement. The results reveal significant positive spatial autocorrelation and spillover effects of TFEE among cities. While factors like environmental regulation and fiscal decentralization influence TFEE, their spillover effects vary across different regional relationships. Furthermore, the two-regime model uncovers asymmetric strategic interactions: geographically adjacent cities tend to engage in “race to the bottom” competition, while economically similar cities exhibit both “race to the top” and “race to the bottom” behaviors. In short, local cities will adopt imitation or differentiation strategies according to the changes in the TFEE levels of neighboring cities, taking into account their own geographic location and level of economic development, and form different strategic interaction patterns, thus affecting the overall TFEE levels and sustainable development of the region.

探索中国城市在提高全要素能源效率方面的战略互动,对于促进区域可持续发展具有重要意义。然而,现有文献缺乏对这些相互作用的复杂模式和机制的全面分析。本文利用2006 - 2017年的城市数据,采用单制度和双制度空间Durbin模型,对城市TFEE提升的空间溢出效应和战略互动进行了实证研究。结果表明,城市间TFEE存在显著的空间自相关和溢出效应。虽然环境规制和财政分权等因素影响TFEE,但其溢出效应在不同区域关系中存在差异。此外,双体制模型揭示了不对称的战略互动:地理上相邻的城市倾向于参与“竞相向底”的竞争,而经济上相似的城市则表现出“竞相向上”和“竞相向底”的行为。简而言之,地方城市会根据周边城市TFEE水平的变化,结合自身的地理位置和经济发展水平,采取模仿或差异化策略,形成不同的战略互动模式,从而影响区域整体TFEE水平和可持续发展。
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引用次数: 0
Biodiversity and phenology of native dicotyledonous species in a newly established vineyard in Mendoza, Argentina 阿根廷门多萨新建立的葡萄园中本地双子叶植物物种的生物多样性和物候
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-23 DOI: 10.1007/s10668-024-05885-8
Romanela Giusti, José A. Portela, Andrea Fruitos, Bruno Marcucci, Natalia Aquindo, Javier Chaar, Marcela Gonzalez, Emilia Mazzitelli, Lucía del Barrio, Agustín Zarco, Guillermo López-García, Guillermo Debandi

Biodiversity plays a crucial role in supporting ecosystem functions and enhancing agroecosystem resilience to anthropogenic disturbances. The establishment of vineyards in natural areas with native vegetation is recognized as a significant driver of landscape fragmentation and biodiversity loss. This study was conducted in a vineyard surrounded by natural vegetation, including two riparian corridors serving as biological corridors, to assess the impact of vineyard management practices on biodiversity. Taxonomic and functional richness of dicotyledonous vegetation were evaluated across different zones: vineyard center, border, biological corridors, and surrounding natural areas. Vegetation surveys were conducted using fixed transects, and citizen science data were integrated to complement surveys and enhance species detection. The response of dicotyledonous species persisting within the vineyard to mowing practices was examined through phenology-related variables, focusing on six species from Asteraceae, Fabaceae, and Malvaceae families under mowed and non-mowed treatments. Results showed a significant decrease in taxonomic and functional richness toward the vineyard interior. Riparian corridors were identified as key contributors to species richness, positively influencing adjacent crop edges. Floral abundance and days in flower were notably reduced in mowed sectors, particularly affecting Malvaceae species. However, resilience to mowing was observed in species such as Thelesperma megapotamicum (Asteraceae) and Adesmia grandiflora (Fabaceae), indicating their potential for use as native cover crops. These findings highlight the necessity of maintaining or restoring areas with shrub and tree elements to enhance vertical heterogeneity and provide resources for biodiversity. Integrating these conservation measures with vineyard management can contribute to sustainable and ecologically responsible grape cultivation.

生物多样性在支持生态系统功能和增强农业生态系统对人为干扰的抵御能力方面发挥着至关重要的作用。在有原生植被的自然区域建立葡萄园被认为是景观破碎化和生物多样性丧失的重要驱动因素。本研究在一个被自然植被包围的葡萄园中进行,包括两条作为生物走廊的河岸走廊,以评估葡萄园管理措施对生物多样性的影响。对双子叶植物在葡萄园中心、边界、生物廊道和周围自然区域的分类和功能丰富度进行了评价。利用固定样带进行植被调查,并整合公民科学数据,以补充调查并加强物种检测。通过物候相关变量研究了葡萄园内双子叶植物对刈割措施的响应,重点研究了菊科、豆科和锦葵科6种植物在刈割和未刈割处理下的生长情况。结果表明,葡萄树内部的分类和功能丰富度显著下降。河岸廊道是物种丰富度的主要贡献者,对相邻的作物边缘具有积极影响。在刈割区,花的丰度和花的天数明显减少,尤其是锦葵科。然而,对刈割的抗御能力在菊科(Thelesperma megapotamicum)和豆科(Adesmia grandflora)等植物中观察到,这表明它们有潜力作为本地覆盖作物。这些发现强调了保持或恢复灌木和乔木要素区域的必要性,以增强垂直异质性,为生物多样性提供资源。将这些保护措施与葡萄园管理相结合,可以促进可持续的、对生态负责的葡萄种植。
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引用次数: 0
Evaluating variability in soil attributes and forest vegetation in a degraded dry tropical region: an ecological restoration perspective 退化干旱热带地区土壤属性和森林植被的变异性评价:生态恢复视角
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-14 DOI: 10.1007/s10668-024-05811-y
Anil Sharma, Sanoj Kumar Patel, Anil Barla, Gopal Shankar Singh

The land use change pattern from disturbed tropical dry forests has significant impact on vegetation and soil physico-chemical properties, leading to alterations in vegetation structure and diversity. Thus, aim of this study was to better understand how disturbances affect forest vegetation and soil physico-chemical attributes under varied land uses in the deciduous forest region of Vindhyan highlands, India. Soil samples and vegetation analyses were conducted across three distinct disturbed forest sites on three land use types using the quadrate method. The study documented 45 species in the tree layer, with 37 in least disturbed, 33 in moderate disturbed, and 28 in highly disturbed stands. Shannon, Simpson, Evenness, Margalef and β-diversity indices exhibited pronounced variations among the three disturbed stands. A two-way analysis of variance (ANOVA) revealed significant difference in soil physico-chemical properties (p < 0.001, p < 0.01 and p < 0.05) due to various disturbed forest stands and land use types. Micronutrients such as zinc, copper, and nickel showed significant variation, with higher concentrations in least disturbed stands. Pearson’s correlation analysis indicated strong relationships between vegetation characteristics and soil physico-chemical attributes, consistent across disturbances. Additionally, the principal component analysis indicated that the first four principal components accounted for 77.7% of the total variation in the data. The comprehensive research will add forest managers in developing long-term eco-restoration plans that will result in reduced soil loss and degradation. This study contributes to more effective forest management and conservation efforts by providing essential insights into the interactions between disturbances, vegetation, and soil properties.

热带干旱林受干扰后的土地利用变化模式对植被和土壤理化性质有显著影响,导致植被结构和多样性发生变化。因此,本研究的目的是更好地了解在不同土地利用方式下,干扰对印度温德扬高原落叶林区森林植被和土壤理化属性的影响。采用方形法对三种土地利用类型的三种不同的扰动森林样地进行了土壤样品和植被分析。该研究记录了45种树层物种,其中37种受干扰最小,33种受干扰中度,28种受干扰高度。Shannon指数、Simpson指数、Evenness指数、Margalef指数和β-多样性指数在不同受干扰林分间表现出显著差异。双向方差分析(ANOVA)显示,不同受干扰林分和土地利用类型对土壤理化性质的影响差异显著(p < 0.001, p <; 0.01和p <; 0.05)。锌、铜、镍等微量元素含量变化显著,受干扰最小的林分浓度较高。Pearson相关分析表明,植被特征与土壤理化属性之间存在较强的相关性,且在不同干扰条件下具有一致性。此外,主成分分析表明,前4个主成分占数据总变异的77.7%。这项综合研究将有助于森林管理者制定长期生态恢复计划,从而减少土壤流失和退化。该研究通过提供干扰、植被和土壤特性之间相互作用的基本见解,有助于更有效的森林管理和保护工作。
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引用次数: 0
Decision support system for assessing quality and consumer acceptance of active biocomposite based food packaging 评价活性生物复合材料食品包装的质量和消费者接受度的决策支持系统
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-14 DOI: 10.1007/s10668-024-05782-0
Vishal Srivastava, Sumer Singh, Dipayan Das

Food wastage contributes to approximately 8% of global greenhouse emissions, posing a major sustainability challenge with significant losses in both the pre-retail and household sectors. The drawbacks of traditional preservation methods have sparked interest in active sustainable packaging. Active sustainable packaging has the ability to enhance the shelf life of food products and reduce environmental impacts, which is crucial for consumer acceptance and market penetration. The consumer acceptability and quality of packaged food in sustainable active packaging with time have been assessed using sensory criteria and multicriteria decision-making techniques. Sensory evaluation is done with consumers, and assessment is shown as a spider graph based on six sensory criteria. The effect of time and type of packaging on consumer preference based on individual sensory criteria has been assessed using the 3D surface graph. Relative weightage of sensory criteria such as appearance, colour, texture, touch, aroma, and overall has been obtained by implementing the analytical hierarchy process (AHP). The AHP model results reveal that active packaging-based alternatives (A1D7, A2D15, A3D30) are the most acceptable packaging alternatives with time compared to synthetic and open packaging based on selected sensory criteria. Moreover, the technique for order preference by similarity to the ideal solution (TOPSIS) method is implemented to find the ranking of all nine packaging alternatives. The ranking of the packaging alternatives based on sensory criteria also supports the ranking obtained from the AHP analysis. This study provides crucial insights for food manufacturers to enhance packaging strategies, optimizing product appeal and consumer satisfaction.

食物浪费约占全球温室气体排放量的8%,在零售前和家庭部门都造成了重大损失,对可持续性构成了重大挑战。传统保存方法的缺点引发了人们对积极可持续包装的兴趣。主动可持续包装具有提高食品保质期和减少环境影响的能力,这对消费者接受和市场渗透至关重要。利用感官标准和多标准决策技术对可持续活性包装食品的消费者接受度和质量随时间的变化进行了评估。感官评估是与消费者一起完成的,评估显示为基于六个感官标准的蜘蛛图。根据个人感官标准,时间和包装类型对消费者偏好的影响已经使用3D表面图进行了评估。通过实施层次分析法(AHP),获得了外观、颜色、质地、触觉、香气和整体等感官标准的相对权重。AHP模型结果显示,根据选定的感官标准,与合成包装和开放式包装相比,基于活性包装的替代品(A1D7, A2D15, A3D30)是最可接受的时间包装替代品。此外,采用理想解相似度排序偏好法(TOPSIS)对9种包装方案进行排序。基于感官标准的包装替代品排名也支持从AHP分析中获得的排名。该研究为食品制造商提高包装策略,优化产品吸引力和消费者满意度提供了重要的见解。
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引用次数: 0
The impact of ecological environment pressure on renewable energy technology innovation: evidence from China’s Yangtze River Economic Belt 生态环境压力对可再生能源技术创新的影响:来自中国长江经济带的证据
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-14 DOI: 10.1007/s10668-024-05763-3
Shanggang Yin, Junjie Zhou, Yijing Zhou, Weiwei Xiao, Caiquan Bai

The ecological environment forms the essential basis for human society's survival and progress. However, the growing pressure exerted on it by human economic activities also hinders scientific advancement and energy efficiency. To examine the influence of ecological environment pressure (EEP) on renewable energy technology innovation (RETI), this study developed an EEP indicator system encompassing the pressure, status, and response dimensions across 108 cities within China’s Yangtze River Economic Belt (YEB). Spatial autocorrelation was introduced to analyze the spatiotemporal evolution characteristics of EEP and RETI from 2011 to 2021. Geographical detector and multi-scale geographically weighted regression model were utilized to reveal the mechanisms by which EEP impacts RETI. The study found that: (1) between 2011 and 2021, there was a notable decline in the average EEP, dropping from 0.2996 to 0.2162. This reduction was characterized by higher pressures in the western YEB than in the eastern YEB, with a strengthening trend in the spatial correlation of these pressures. Concurrently, the average RETI indicator demonstrated an escalating tendency, increasing from 27.80 to 45.03. This growth is evidenced by a significant enhancement in the innovation performance of the eastern YEB compared to that of the western YEB, with a weakening trend in the spatial correlation of innovation levels. (2) The influence of EEP on RETI, as measured by explanatory power, diminished over the decade, decreasing from 0.3169 in 2011 to 0.2568 in 2021. Interactions between EEP and other factors can increase this explanatory power. The spatial heterogeneity of EEP's impact on RETI remains largely stable, showing a positive impact in the eastern regions while exhibiting a negative effect in the western regions.

生态环境是人类社会赖以生存和进步的重要基础。然而,人类经济活动对它施加的压力越来越大,也阻碍了科学进步和能源效率。为考察生态环境压力对可再生能源技术创新(RETI)的影响,本研究构建了包含长江经济带108个城市生态环境压力、现状和响应维度的指标体系。引入空间自相关分析了2011 - 2021年EEP和RETI的时空演变特征。利用地理探测器和多尺度地理加权回归模型揭示了生态环境指数影响RETI的机制。研究发现:(1)2011年至2021年间,平均EEP显著下降,从0.2996下降到0.2162。这种减少的特点是,西部YEB的压力高于东部YEB,并且这些压力的空间相关性呈增强趋势。同时,平均RETI指标呈上升趋势,从27.80上升到45.03。这一增长表现为东部工业园区创新绩效显著高于西部工业园区,创新水平的空间相关性呈减弱趋势。(2) EEP对RETI的影响在解释能力上呈下降趋势,从2011年的0.3169下降到2021年的0.2568。EEP与其他因素之间的相互作用可以增强这种解释力。经济生产力对RETI影响的空间异质性基本保持稳定,东部地区表现为正向影响,西部地区表现为负向影响。
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引用次数: 0
Pattern evolution and spatial structure of ecological and construction security network of the Yangtze River Economic Belt in China 中国长江经济带生态与建设安全网络格局演化与空间结构
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-14 DOI: 10.1007/s10668-024-05848-z
Wei Wang, Haofei Wang, Qian Xiaojin

This study employs remote sensing data on natural resources, environmental conditions, as well as socio-economic statistics to establish a landscape source-sink model for both ecology-oriented development axes and infrastructure-oriented development axes within China's Yangtze River Economic Belt region. Our findings reveal that: (1) Ecological sources exhibit a significantly larger scale compared to their counterparts in infrastructure development; they demonstrate stable spatial distributions for resistance zones while also displaying robust reconstruction capabilities for these zones; (2) An extensive presence of an ecologically oriented security framework characterizes central-western regions within this economic belt—marked by lush forests alongside intricate river systems—and contrasts sharply against an infrastructure-focused security framework prevalent across its eastern counterpart—defined by concentrated agricultural land use juxtaposed against densely populated urban centers; (3) A notable alignment exists between our identified ecologically secure zones vis-à-vis high-value domains associated with carbon sequestration potentiality alongside superior habitat preservation qualities coupled with effective soil–water conservation measures—a stark contrast emerges when examining corresponding features within our identified infrastructural secure zones which tend to be situated amidst lower carbon sequestration capacities combined with inferior habitat preservation attributes alongside suboptimal soil–water retention abilities resulting in diminished water yields; (4) Our delineated ecologically secure axis closely mirrors fluvial patterns along this economic belt whereas our infrastructural secure axis distinctly corresponds to agricultural landscapes intertwined seamlessly amongst key transportation arteries.

本研究利用自然资源、环境条件遥感数据以及社会经济统计数据,建立了中国长江经济带生态发展轴和基础设施发展轴的景观源汇模型。研究结果表明:①生态资源在基础设施建设中的规模显著大于生态资源;它们表现出稳定的阻力区空间分布,同时也表现出对这些区域的强大重建能力;(2)以生态为导向的安全框架的广泛存在是该经济带内中西部地区的特征——以茂密的森林和错综复杂的河流系统为标志——与东部地区普遍存在的以基础设施为重点的安全框架形成鲜明对比——由集中的农业用地与人口密集的城市中心并列定义;(3)我们确定的生态安全区域与-à-vis高价值区域之间存在显著的一致性,这些区域与固碳潜力相关,同时具有优越的栖息地保护质量和有效的水土保持措施-当检查我们确定的基础设施安全区域内的相应特征时,出现了鲜明的对比,这些区域往往位于较低的固碳能力和较差的栖息地保护中属性与次优土壤保水能力一起导致产水量减少;(4)我们划定的生态安全轴紧密反映了该经济带的河流格局,而我们的基础设施安全轴则明显对应于农业景观,这些景观在主要交通干线之间无缝地交织在一起。
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引用次数: 0
Environment, development, and health: the vulnerability of sub-populations in İstanbul to heat extremes 环境、发展和健康:İstanbul亚群体对极端高温的脆弱性
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-14 DOI: 10.1007/s10668-024-05828-3
Merve Yılmaz, Hazal Cansu Çulpan, Günay Can, Hüseyin Toros, Mete Tayanç

The Mediterranean region is highly vulnerable to climate risks such as prolonged and more intense heat waves with increased drought. İstanbul has the climate characteristics of the Mediterranean region and interacts with the surrounding climate regions. Also, the city is the largest among Türkiye’s major urban areas. The study aims to determine the vulnerability of İstanbul residents to heat extremes as well as their mortality risks according to region, age group, sex, and cause of death. The distributed lag non-linear model was used to analyze risk by establishing a statistical relationship between extreme temperatures and mortality rates. A separate model was defined for each sub-population group and the increase in mortality risks was estimated when daily maximum temperatures increased from minimum mortality temperature to the heat wave threshold. The highest increase in excess rate was observed in the low urbanization region (19.5%) followed by the medium urbanization region (18.0%). Mortality risk was also higher in people aged ≥ 65 years (20.9%), females (16.2%), people with cerebrovascular (53.4%) and respiratory diseases (40.7%). The vulnerability in less populated areas is likely to be due to the cumulative intensity of regional heat waves as well as inadequate access to health services, housing, and climatization conditions in these areas; in addition, as the population density of the elderly increases, regional vulnerability is considered to be higher. The findings of this multidisciplinary study can guide decision makers and be implemented in future local climate action plans, public health strategies, and people-friendly urban design in line with Sustainable Development Goals (SDGs).

地中海地区极易受到气候风险的影响,例如持续时间更长、更强烈的热浪以及干旱加剧。İstanbul具有地中海地区的气候特征,并与周围气候区相互作用。此外,这个城市是缅甸主要城市地区中最大的。该研究旨在确定İstanbul居民对极端高温的脆弱性,以及根据地区、年龄组、性别和死亡原因确定他们的死亡风险。通过建立极端温度与死亡率之间的统计关系,采用分布滞后非线性模型进行风险分析。为每个亚人群组定义了一个单独的模型,并估计当每日最高温度从最低死亡温度上升到热浪阈值时死亡风险的增加。城市化程度较低的地区植被超限率增幅最大(19.5%),中等城市化地区次之(18.0%)。年龄≥65岁的人群(20.9%)、女性(16.2%)、脑血管(53.4%)和呼吸系统疾病(40.7%)患者的死亡风险也较高。人口较少地区的脆弱性可能是由于区域热浪的累积强度以及这些地区获得卫生服务、住房和气候条件不足;此外,随着老年人人口密度的增加,区域脆弱性被认为更高。这项多学科研究的结果可以指导决策者,并在未来的地方气候行动计划、公共卫生战略和符合可持续发展目标(SDGs)的人性化城市设计中加以实施。
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引用次数: 0
H2S and SO2 toxic gases removal using date palm-tree branches based activated carbon: experimental findings and machine learning (ML) modeling 使用基于枣椰树树枝的活性炭去除H2S和SO2有毒气体:实验结果和机器学习(ML)建模
IF 4.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-13 DOI: 10.1007/s10668-024-05847-0
Usman M. Ismail, Minaam Hussaini, Muhammad S. Vohra

Utilization of carbonaceous waste material as precursors for production of activated carbon (AC) is desired. Hence, this study made use of date palm tree branches (DPB)—a major source of waste—in Saudi Arabia to produce AC that was used for treatment of air contaminated with H2S and SO2 gases. A dynamic adsorption setting was used to explore the uptake of H2S and SO2 onto DPB AC column with the aid of state-of-the-art bench-top gas analyzers. Several process parameters were varied to understand their effect on the breakthrough and exhaustion times of the gases under study. Response surface methodology (RSM) technique was used to further explore the relationship between the variables and machine learning (ML) techniques were used to create models for prediction of breakthrough and exhaustion times. Textural properties of DPB AC were explored using characterization techniques. AC produced from DPB had high BET specific surface area (800.87 m2/g) and a flaky morphology along with several oxygen-containing surface functional groups. The breakthrough profiles of both H2S and SO2 exhibited similar sigmoidal pattern. However, the broader breakthrough pattern of SO2 indicated that DPB has more affinity for SO2. The RSM study indicate that an increase in gas flow and gas initial concentration led to a shortening od both breakthrough and exhaustion time for both gases. However, when the column depth as increased, the breakthrough and exhaustion times lengthened for both gases. Furthermore, machine learning (ML) modeling results revealed that the artificial neural network (ANN) model was predicted H2S/SO2 breakthrough and exhaustion times with greater efficiency relative to other ML models. Our study revealed that AC produced from DPB can be used for treatment of air contaminated with H2S and SO2 gases and mechanistic modelling techniques can aid in exploring the adsorptive removal of harmful gases. It is recommended that a larger sample size should be utilized when conducting mechanistic modelling in future studies and that effective means for desorbing and regenerated contaminated AC should also be explored.

希望利用含碳废物作为生产活性炭(AC)的前体。因此,本研究利用沙特阿拉伯的主要废物来源枣椰树树枝(DPB)生产用于处理被H2S和SO2气体污染的空气的AC。采用动态吸附设置,借助最先进的台式气体分析仪,研究了DPB交流柱对H2S和SO2的吸附情况。改变了几个工艺参数,以了解它们对所研究气体的突破和耗尽时间的影响。使用响应面方法(RSM)技术进一步探索变量之间的关系,并使用机器学习(ML)技术创建预测突破和耗尽时间的模型。利用表征技术对DPB AC的织构性能进行了研究。由DPB制备的AC具有较高的BET比表面积(800.87 m2/g)和片状形貌,表面含有几个含氧官能团。H2S和SO2的突破剖面均呈现相似的s型曲线。然而,SO2的突破范围更广,表明DPB对SO2的亲和力更强。RSM研究表明,随着瓦斯流量和瓦斯初始浓度的增加,两种气体的突破时间和衰竭时间都缩短了。然而,随着塔深的增加,两种气体的突破和耗尽时间都延长了。此外,机器学习(ML)建模结果表明,与其他ML模型相比,人工神经网络(ANN)模型预测H2S/SO2突破和耗尽时间的效率更高。我们的研究表明,由DPB产生的AC可以用于处理被H2S和SO2气体污染的空气,并且机理建模技术可以帮助探索吸附去除有害气体。建议在今后的研究中进行机理模拟时采用更大的样本量,并探索污染AC解吸再生的有效手段。
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Environment, Development and Sustainability
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