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Investigations on SS304-Cu Bimetallic Joint Realized through Cold Metal Transfer-Based Wire Arc Additive Manufacturing 基于冷金属转移的丝弧增材制造实现SS304-Cu双金属接头的研究
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-09-05 DOI: 10.1007/s11665-026-15005-4
K. Santhosh Kumar, P. Chakravarthy, T. Venkateswaran, Debalina Bhattacharjee, S. Shiva, T. M. Anup Kumar

The increasing demand for multi-material components in advanced engineering systems, particularly in thermal management, power generation, and electronic industries, necessitates the development of reliable strategies for joining stainless steel to copper. Wire arc additive manufacturing (WAAM) has emerged as a promising approach for joining dissimilar metals by enabling controlled heat input, compositional grading, and layer-by-layer fabrication. In the present study, a multilayer deposition strategy was employed to join AISI 304 stainless steel to pure copper using WAAM through a cold metal transfer (CMT) mode. Detailed microstructural characterization using optical microscopy, scanning electron microscopy, and electron backscatter diffraction revealed the formation of a defect-free joint facilitated by a diffusion-driven bonding, exhibiting gradual compositional transition from coarse columnar SS304 grains to comparatively fine equiaxed Cu grains across the interface. Significant grain evolution without any preferred crystallographic orientation was observed on the Cu side, with greater diffusion depth of SS304 into Cu. Microhardness mapping indicated that the interfacial properties were governed by the harder SS304 phase. The hardness values across the interface varied between 109 and 187 HV, indicating a gradual transition from the softer Cu region to the stronger SS304 side. The SS304-Cu bimetallic joint exhibited a UTS of 290 MPa and 0.2% YS of 175 MPa, outperforming WAAM-deposited pure Cu and demonstrating failure in the Cu region rather than at the interface. Radiographic examination confirmed minimal porosity within acceptable limits, demonstrating that defect-free and reliable SS304-Cu joints can be systematically achieved through CMT-based WAAM.

在先进的工程系统中,特别是在热管理、发电和电子工业中,对多材料组件的需求日益增长,需要开发可靠的不锈钢与铜连接策略。电弧增材制造(WAAM)已经成为一种很有前途的方法,可以通过控制热输入、成分分级和逐层制造来连接不同的金属。在本研究中,采用多层沉积策略,采用WAAM通过冷金属转移(CMT)模式将AISI 304不锈钢与纯铜结合。利用光学显微镜、扫描电镜和电子背散射衍射进行详细的微观结构表征,发现通过扩散驱动键合形成了一个无缺陷的接头,其成分逐渐从粗柱状SS304晶粒转变为相对细小的等轴Cu晶粒。在Cu侧观察到明显的晶粒演化,没有任何优先的晶体取向,SS304在Cu中的扩散深度更大。显微硬度图表明,界面性能受较硬的SS304相控制。界面上的硬度值在109 ~ 187 HV之间变化,表明从较软的Cu区逐渐过渡到较强的SS304侧。SS304-Cu双金属接头的UTS为290 MPa, YS为175 MPa,优于waam沉积的纯Cu,并且在Cu区域而不是界面处表现出破坏。x线检查证实最小孔隙度在可接受范围内,表明通过基于cmt的WAAM可以系统地实现无缺陷和可靠的SS304-Cu接头。
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引用次数: 0
Special Issue on the Space and Aerospace Exploration Revolution: Metal Additive Manufacturing 航天探索革命特刊:金属增材制造
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-09-03 DOI: 10.1007/s11665-026-14953-1
Shahrooz Nafisi, Douglas Hofmann, Paul Gradl
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引用次数: 0
Permeable Additive Manufacturing Qualification Framework and Evaluation Methodology for Inconel 718 Inconel 718可渗透增材制造鉴定框架与评价方法
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-09-01 DOI: 10.1007/s11665-026-14784-0
Darren C. Tinker, Carly J. Romnes, Claire E. Handley, Michael V. Consolo, Marie C. Tankard, Nicholas T. Beaty, Diana Y. Andreev, Alexis J. Harroun, Ari G. Martinez

Permeable additive manufacturing is immature relative to the field of additive manufacturing, resulting in unknown operating margins for end-use applications. Permeable additive structures are commonly manufactured via Laser Powder Bed Fusion through varying weld penetrations and hatch spacing. These methods produce permeable structures with unique manufacturability, mechanical properties, and flow resistances. Preliminary results of this work confirm correlations of porosity and permeability. The correlation of porosity and permeability is agnostic to the exact structural composition of the printed material, which may mask flaws beneath the surface of the build. While target permeability can be met for a given porosity, the equivalent pore volume can include large, inconsistently located voids instead of an equivalent volume of smaller, evenly spaced pores. To rephrase, select build parameters may cause internal part delamination that are only visible after metallographic cross-section examination. The delamination inherently reduces mechanical properties that are needed for end-use applications and must be avoided. The previous literature has provided quality overviews of permeable additive manufacturing and point design applications but lacks information on the full scope of manufacturing failure mechanisms. This manuscript expands upon mainstream literature, providing failure mechanisms and performance correlations to develop a holistic view of laser parameter development for permeable additive manufacturing. In short, this work provides detailed manufacturing guidelines, inclusive of post-processing techniques, as well as an evaluation methodology to correlate build parameters to performance parameters for Inconel 718.

相对于增材制造领域,可渗透增材制造尚不成熟,导致最终用途应用的营业利润率未知。可渗透的添加剂结构通常是通过激光粉末床熔化通过不同的焊缝穿透和舱口间距制造的。这些方法产生的透水结构具有独特的可制造性、机械性能和流动阻力。本工作的初步结果证实了孔隙度和渗透率的相关性。孔隙率和渗透率的相关性与印刷材料的确切结构组成无关,这可能掩盖了构建表面下的缺陷。虽然给定孔隙度可以满足目标渗透率,但等效孔隙体积可能包括较大的、位置不一致的孔隙,而不是等效体积较小的、均匀分布的孔隙。换句话说,选择的构建参数可能会导致内部零件分层,只有在金相截面检查后才能看到。分层本质上降低了最终应用所需的机械性能,必须避免。以前的文献提供了渗透性增材制造和点设计应用的质量概述,但缺乏制造失效机制的全部范围的信息。本文扩展了主流文献,提供失效机制和性能相关性,以开发可渗透增材制造的激光参数开发的整体视图。简而言之,这项工作提供了详细的制造指南,包括后处理技术,以及将Inconel 718的构建参数与性能参数相关联的评估方法。
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引用次数: 0
Cold Metal Transfer-Based Wire Arc Additive Manufacturing of AA4043: Microstructural, Mechanical, and Surface Characteristics 基于冷金属转移的AA4043电弧增材制造:显微组织、机械和表面特性
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-29 DOI: 10.1007/s11665-026-14998-2
Siddharthan Rajakumar, Narayanasamy Pandiarajan,  Abhilash, Ramkumar Thulasiram

Wire arc additive manufacturing (WAAM) has emerged as a promising near-net-shape manufacturing technology for producing large-scale metallic components with high material utilization and cost-efficiency. However, the widespread adoption of aluminum alloys in WAAM remains challenging due to the complex interactions between process parameters, thermal history, microstructural evolution, defect formation, and mechanical performance. In this study, the influence of wire current on the microstructure, porosity evolution, crystallographic characteristics, residual strain distribution, and mechanical properties of CMT-WAAM-fabricated AA4043 deposits was systematically investigated. Quantitative porosity analysis using ImageJ revealed porosity area fractions of 0.138, 0.033, 0.257, and 2.704% for samples fabricated at 75, 100, 125, and  A, respectively, demonstrating the strong influence of heat input on pore formation. XRD confirmed the dominance of the α-Al phase across all processing conditions, while EBSD analysis revealed a transition from relatively refined cellular–dendritic structures at lower currents to coarse epitaxial columnar grains at higher heat inputs. Kernel average misorientation (KAM) analysis indicated progressive residual strain relaxation with increasing wire current due to enhanced thermal exposure. Excessive heat input at 150 A promoted abnormal grain growth (> 100 µm), significant porosity formation, and deterioration of mechanical properties. In contrast, the 125 A condition provided the most favorable balance of microstructural refinement, texture development (MUD = 11.55), low defect content, and residual strain distribution, resulting in the highest average microhardness (108 HV) and ultimate tensile strength (162 MPa). The findings establish a comprehensive process–structure–property relationship for CMT-WAAM-fabricated AA4043 and provide practical guidance for optimizing deposition parameters to minimize defects and enhance structural performance.

电弧增材制造(WAAM)是一种极具发展前景的近净成形制造技术,可用于生产具有高材料利用率和高成本效益的大型金属部件。然而,由于工艺参数、热历史、微观组织演变、缺陷形成和力学性能之间复杂的相互作用,铝合金在WAAM中的广泛采用仍然具有挑战性。本研究系统研究了线材电流对cmt - waam制备的AA4043镀层微观结构、孔隙演化、结晶学特征、残余应变分布及力学性能的影响。利用ImageJ进行定量孔隙度分析,在75、100、125和A条件下制备的样品的孔隙面积分数分别为0.138、0.033、0.257和2.704%,表明热输入对孔隙形成的强烈影响。XRD证实了α-Al相在所有加工条件下都占主导地位,而EBSD分析显示,在低电流下,α-Al相从相对精细的细胞枝晶结构转变为高热量输入下的粗外延柱状晶粒。核平均取向偏差(KAM)分析表明,由于热暴露的增强,残余应变随着导线电流的增加而逐渐松弛。在150 A时,过多的热输入会导致晶粒生长异常(> 100µm),气孔形成明显,力学性能恶化。相比之下,125 A条件在组织细化、织构发育(MUD = 11.55)、缺陷含量低和残余应变分布方面的平衡最为有利,平均显微硬度最高(108 HV),极限抗拉强度最高(162 MPa)。研究结果为cmt - waam制备的AA4043建立了全面的工艺-结构-性能关系,并为优化沉积参数以减少缺陷和提高结构性能提供了实用指导。
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引用次数: 0
Multi-scale Coupling Simulation of Dendritic Growth Kinetics and Microstructural Evolution in Single-Pass Wire-Arc Surfacing of Inconel 625 Superalloy Inconel 625高温合金单道线弧堆焊枝晶生长动力学与显微组织演变的多尺度耦合模拟
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-28 DOI: 10.1007/s11665-026-13954-4
Xiaoyan Gu, Dian Yang, Xiaopeng Lin, Bofang Zhou, Hongxia Zhang, Jian Li, Quantao Yang

A multi-scale model is developed to simulate the solidification structure of single-pass wire-arc surfacing (WAS) of Inconel 625 superalloy. This study focuses on clarifying the fundamental thermo-solid coupling laws of single-pass WAS, which provide a critical basis for its application in wire-arc repair and additive manufacturing. The model emphasizes the dynamic thermal conditions at the solid-liquid interface, extracted from a three-dimensional conduction-based heat transfer model with a double-ellipsoid arc heat source. To isolate the effects of local solidification parameters on dendritic morphology, the complex alloy is modeled as a Ni‐Nb binary system, and the phase-field simulation focuses on single-dendrite growth under a transient temperature gradient G and an interface velocity Vs. Results show that dendritic growth evolves through linear, unstable, competitive, and stable stages, with primary dendrite arm spacing (PDAS) increasing from the top to the bottom of the molten pool as the cooling rate (G·Vs) decreases. Furthermore, higher heat-source power reduces G·Vs, leading to coarser dendrites and larger PDAS. Experimental measurements of PDAS and Nb segregation validate the simulation trends, with a relative error of 6.44%. This work provides a quantitative link between arc-surfacing parameters and dendritic microstructure via a multi-scale phase-field approach, offering a theoretical basis for optimizing the performance of repair layers.

建立了一种多尺度模型来模拟Inconel 625高温合金单道电弧堆焊的凝固组织。本研究重点阐明了单道WAS的基本热固耦合规律,为其在线弧修复和增材制造中的应用提供了重要依据。该模型从基于双椭球弧热源的三维导热传热模型中提取,强调了固液界面的动态热条件。为了分离局部凝固参数对枝晶形貌的影响,将复合合金建模为Ni - Nb二元体系,并将相场模拟重点放在瞬态温度梯度G和界面速度vs下的单枝晶生长上。结果表明,枝晶生长经历了线性、不稳定、竞争和稳定四个阶段。随着冷却速率(G·Vs)的减小,初生枝晶臂间距(PDAS)从熔池顶部到底部逐渐增大。此外,较高的热源功率降低了G·Vs,导致枝晶更粗,PDAS更大。PDAS和Nb偏析的实验测量结果验证了模拟趋势,相对误差为6.44%。本研究通过多尺度相场方法提供了电弧堆焊参数与枝晶微观结构之间的定量联系,为优化修复层的性能提供了理论基础。
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引用次数: 0
Exploring Low-Energy Density Regimes in Laser Powder Bed Fusion of CuCrZr Alloy: Effects on Densification, Heat Treatment, and Mechanical Properties 激光粉末床熔合CuCrZr合金的低能量密度:对致密化、热处理和力学性能的影响
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-25 DOI: 10.1007/s11665-026-14918-4
Sailesh Kamath, Ravi Ranjan Kumar, Robert Johnson, Jobin Cyriac, S. V. S. Narayana Murty

Precipitation-hardened CuCrZr (UNS No. C18150) is a performance-critical copper alloy with good thermal and mechanical properties, making it ideal for space applications where fast heat extraction is essential to maintain the integrity of the component and maintain mechanical properties. However, due to its high reflectivity and thermal conductivity, laser powder bed fusion (L-PBF) processing of Cu alloys is difficult, especially at lower energy inputs. Most prior studies focus on high volumetric energy densities (VEDs), neglecting the low-VED regime, which may help to reduce laser back reflection and associated risks to optical systems in industrial L-PBF systems. This study aims to characterize the L-PBF processing of the CuCrZr alloy across a wide VED range (41.15-202.19 J/mm3). In this study, the samples were fabricated using L-PBF and were subjected to two post-processing routes: solution treatment followed by aging (STA) and direct age hardening (DAH). This study analyzed the densification behavior, microstructural evolution, and mechanical properties. Optical microscopy, scanning electron microscopy, and electron backscatter diffraction were employed for microstructural analysis. A maximum relative density (RD) of 99.88% was achieved at a VED of 171.3 J/mm3. Direct aging at 450 °C for 4 h resulted in the highest hardness (189 HV0.2), showing a 119% increase over the as-printed condition. Mechanical performance, including yield strength and ductility, peaked near a VED of 159.72 J/mm3 and plateaued at higher energy levels. EBSD revealed a crystallographic texture shift from <111> //[001] in the as-printed condition to <101> //[001] post-aging, while fracture morphology transitioned from ductile to mixed mode. An increase in thermal conductivity was noted for L-PBF samples, compared to wrought CuCrZr alloy. These results establish a robust L-PBF processing window for the CuCrZr alloy, which would be useful for additive manufacturing of critical space components made from this high-conductivity alloy.

沉淀硬化CuCrZr (UNS号)C18150)是一种性能关键的铜合金,具有良好的热性能和机械性能,使其成为空间应用的理想选择,在这些应用中,快速热提取对于保持组件的完整性和保持机械性能至关重要。然而,由于铜合金的高反射率和高导热性,激光粉末床熔合(L-PBF)加工铜合金是困难的,特别是在低能量输入下。大多数先前的研究都集中在高体积能量密度(VEDs)上,而忽略了低体积能量密度(VEDs)状态,这可能有助于减少工业L-PBF系统的激光背反射和相关风险。本研究的目的是表征CuCrZr合金的L-PBF加工过程在较宽的VED范围内(41.15-202.19 J/mm3)。在本研究中,使用L-PBF制备样品,并进行两种后处理路线:固溶处理后时效(STA)和直接时效硬化(DAH)。本研究分析了合金的致密化行为、显微组织演变和力学性能。采用光学显微镜、扫描电镜、电子背散射衍射等方法进行显微结构分析。在功率为171.3 J/mm3时,最大相对密度(RD)达到99.88%。在450°C下直接时效4小时,硬度最高(189 HV0.2),比印刷状态增加了119%。机械性能,包括屈服强度和延展性,在VED为159.72 J/mm3附近达到峰值,在更高的能量水平下趋于稳定。EBSD显示,打印状态下的晶体织构从<;111>; //[001]转变为时效后的<;101> //[001],断口形貌从延性转变为混合型。与变形CuCrZr合金相比,L-PBF样品的导热系数有所增加。这些结果为CuCrZr合金建立了一个强大的L-PBF加工窗口,这将有助于由这种高导电性合金制成的关键空间部件的增材制造。
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引用次数: 0
Parameter-Controlled Geometrically-Undefined Porosity in Laser Powder Bed Fusion of Metals: A Review 激光粉末床熔合中参数控制的几何未定义孔隙率研究进展
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-21 DOI: 10.1007/s11665-026-14731-z
Roenigk Straub, Derek Murphy, Daniel Oropeza

Porous metal structures provide unique capabilities for energy absorption, thermal management, and fluid transport, particularly for aerospace platforms. Laser powder bed fusion additive manufacturing has enabled unprecedented spatial control of porosity, surpassing the capabilities of conventional porous metal foam manufacturing processes. Two distinct approaches exist for fabricating porous metals via powder bed fusion: (1) geometrically-defined porosity, where porous structures are explicitly included in computer-aided design and manufactured with controlled lattice/pore features, and (2) geometrically-undefined porosity, where porosity arises as an artifact of strategically adjusted processing parameters during manufacturing. While geometrically-defined porosity fabrication of lattice structures via powder bed fusion has been extensively reviewed, parameter-based geometrically-undefined porosity fabrication remains comparatively underexplored despite its ability to generally achieve pore sizes ranging from 1 to 100 µm and total porosity between 0 and 50%. By systematically adjusting key processing parameters, including laser power, scan speed, hatch spacing, and layer thickness, researchers can tailor pore density, distribution, and morphology within the fabricated structures. Geometrically-undefined porosity offers distinct advantages, including the ability to achieve finer feature sizes, gradient porosity transitions, and potentially reduce manufacturing complexity for certain applications. This review provides a comprehensive overview of parameter-based geometrically-undefined porosity formation in laser powder bed fusion, synthesizes experimental findings across multiple alloy systems, examines the influence of porosity on mechanical, thermal, electrical, and permeability properties, and discusses research gaps and potential applications for this emerging technique.

多孔金属结构为能量吸收、热管理和流体输送提供了独特的能力,尤其适用于航空航天平台。激光粉末床熔融增材制造实现了前所未有的孔隙度空间控制,超越了传统多孔金属泡沫制造工艺的能力。通过粉末床熔合制造多孔金属存在两种不同的方法:(1)几何定义孔隙度,其中多孔结构明确包含在计算机辅助设计中,并以受控的晶格/孔隙特征制造;(2)几何定义孔隙度,其中孔隙度是在制造过程中战略性调整加工参数的产物。虽然通过粉末床融合的几何定义孔隙度制造晶格结构已经得到了广泛的研究,但基于参数的几何定义孔隙度制造仍然相对欠开发,尽管它通常能够实现孔径范围从1到100微米,总孔隙度在0到50%之间。通过系统地调整关键加工参数,包括激光功率、扫描速度、舱口间距和层厚,研究人员可以在制造结构中定制孔隙密度、分布和形态。几何上未定义的孔隙度具有明显的优势,包括能够实现更精细的特征尺寸,梯度孔隙度转换,并有可能降低某些应用的制造复杂性。本文全面概述了激光粉末床熔合中基于参数的几何未定义孔隙度形成,综合了多种合金系统的实验结果,研究了孔隙度对机械、热、电和渗透性能的影响,并讨论了这一新兴技术的研究空白和潜在应用。
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引用次数: 0
Influences of Symmetric Tilt Grain Boundary on the Mechanical Properties of Cu Bicrystals under Nanoindentation 对称倾斜晶界对纳米压痕下Cu双晶力学性能的影响
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-17 DOI: 10.1007/s11665-026-14756-4
Juan Chen, Yunyun Dai, Zhuoran Li, Fengming Qin, Huiqin Chen, Xiaotian Fang

The grain boundary (GB) is a planar defect that strongly influences the mechanical properties of polycrystalline materials as the size of the grains decreases down to the nanoscale. In this work, the bicrystal Cu samples with different coincidence site lattice (CSL) interfaces are constructed, and nanoindentation tests are conducted parallel to symmetric tilt interface using molecular dynamics simulation to investigate the effect of the interface on mechanical properties and plastic deformation behaviors. The results imply that the GB energy and Von Mises shear stress distribution are related to interface structures. A regular and thinner interface always results in a lower GB energy and stress concentration. It is found that the monocrystalline Cu samples exhibit different yield strengths due to crystallographic orientation, and the value of yield strength is higher than that of bicrystal samples, except for CSL3, CSL67, CSL73, CSL81 and CSL83 bicrystal samples. The higher yield strength of bicrystal samples is attributed to longer average dislocation length and higher Shockley dislocation proportion of as-prepared samples through dislocation analysis. Moreover, accompanied by the nucleation and extension along dissociation planes of interface, the activation of additional slipping system acquires higher external force during loading. In conclusion, the bicrystal strength depends upon the interface structure, crystallographic orientation and loading conditions.

晶界(GB)是一种平面缺陷,当晶粒尺寸减小到纳米级时,会严重影响多晶材料的力学性能。本文构建了具有不同重合点位晶格(CSL)界面的双晶Cu样品,并利用分子动力学模拟方法对对称倾斜界面进行了平行纳米压痕试验,研究了界面对力学性能和塑性变形行为的影响。结果表明,界面结构与GB能量和Von Mises剪应力分布有关。规则且薄的界面总是导致较低的GB能量和应力集中。结果发现,单晶Cu样品由于晶体取向不同,屈服强度值均高于双晶样品,但CSL3、CSL67、CSL73、CSL81和CSL83双晶样品除外。通过位错分析,制备的双晶样品的平均位错长度和肖克利位错比例较高,从而获得较高的屈服强度。此外,附加滑移系统的激活伴随着界面解离面形核和扩展,在加载过程中获得了更高的外力。综上所述,双晶强度与界面结构、晶体取向和加载条件有关。
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引用次数: 0
Study on the Microstructure and Properties of Cu-1.5Ni-0.32P Alloy Cu-1.5Ni-0.32P合金的组织与性能研究
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-17 DOI: 10.1007/s11665-026-13674-9
Xiongwei Huang, Xiaokang Chen, Kun Lu, Wenxiu Ning, Xiangpeng Xiao

This study investigated the Cu-1.5Ni-0.32P alloy processed via hot rolling, solution treatment, cold rolling, and aging, focusing on the influence of cold rolling deformation degree and aging parameters on its microstructure and properties. The results show that the properties of as-cast Cu-1.5Ni-0.32P alloy are uneven due to the enrichment of coarse Ni-P second phase at grain boundaries. After hot rolling with 50% deformation at 900 °C for 2 h and solid solution treatment at 900 °C for 1 h, the second phase is completely dissolved and fine equiaxed grains are formed. The hardness is increased to 125.6 HV, but the conductivity is reduced to 30.1% IACS. After further optimization by 75% cold rolling and aging, it is found that spherical nano-Ni3P phase precipitates after aging at 450 °C for 6 h, the hardness reaches a peak of 210.7 HV, and the conductivity increases to 65.8% IACS, representing a 138% increase in hardness and a 51% increase in electrical conductivity compared to the as-cast alloy. In this state, the alloy maintains high electrical conductivity while achieving a significant increase in strength, demonstrating outstanding combined properties of high strength and high conductivity. When the aging time was prolonged to 9 h, it was transformed into rod-like Ni2P phase, which was coherent with the Cu matrix, and the texture was transformed from {001} < 100 > Cube to {112} < 111 > Copper. This study provides important reference for achieving synergistic enhancement of strength and electrical conductivity in Cu-Ni-P alloys through optimized process routes.

研究了经过热轧、固溶、冷轧和时效处理的Cu-1.5Ni-0.32P合金,重点研究了冷轧变形程度和时效参数对其组织和性能的影响。结果表明:铸态Cu-1.5Ni-0.32P合金在晶界处富集了粗大的Ni-P第二相,导致合金性能不均匀;经900℃50%变形热轧2 h, 900℃固溶1 h,第二相完全溶解,形成细小的等轴晶。硬度提高到125.6 HV,但电导率降低到30.1% IACS。进一步优化75%冷轧时效后,发现450℃时效6 h后析出球形纳米ni3p相,硬度峰值达到210.7 HV,电导率提高到65.8% IACS,硬度比铸态提高138%,电导率提高51%。在这种状态下,合金在保持高导电性的同时,强度显著提高,表现出优异的高强度和高导电性的综合性能。时效时间延长至9 h后,转变为棒状Ni2P相,与Cu基体相共融,织构由{001}<; 100 >; Cube转变为{112}<; 111 > Copper。该研究为通过优化工艺路线实现Cu-Ni-P合金强度和电导率的协同增强提供了重要参考。
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引用次数: 0
Additive Manufacturing of Carbothermally Produced Structural (CarPS) Material from Martian Regolith and Bosch By-Product Carbon Simulants 从火星风化层和博世副产品碳模拟物中增材制造碳热生产结构(CarPS)材料
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-08-17 DOI: 10.1007/s11665-026-14783-1
Blake C. Stewart, Parker D. Shake, Shiraz Mujahid, Dawn Van Iderstine, Joel Austin, Hongjoo Rhee

Future crewed missions and eventual long-term habitation of the Martian surface will rely on the ability to produce and repair components and structures on-site with materials sourced from the local environment, i.e., in situ resource utilization (ISRU). Synergizing additive manufacturing (AM) processes with ISRU techniques satisfies these requirements while also allowing for on-demand, rapid prototyping and net-shape construction. Direct regolith printing of ceramics and elements harvested for metallic material feedstocks has been shown to be viable in the past, and carbothermal reduction (CR) has been a successful endeavor for oxygen (O2) generation thus far. In this study, a mixture of JSC-Mars-1A Martian regolith simulant and carbon (C) was subjected to Laser Powder Bed Fusion (L-PBF) to explore the application of AM and CR simultaneously. The regolith and C sources were characterized prior to constructing samples of feedstock-only and feedstock-C mixture, coined Carbothermally Produced Structural (CarPS) material, for x-ray diffraction (XRD), energy-dispersive x-ray spectroscopy (EDS), and compression testing. Results show significantly improved sample build quality in the CarPS samples with a reduction in compressive fracture stress using the same build parameters with evidence of reduced bulk oxygen content.

未来的载人飞行任务和最终的火星表面长期居住将依赖于利用当地环境的材料在现场生产和修理部件和结构的能力,即就地资源利用(ISRU)。与ISRU技术协同的增材制造(AM)工艺满足了这些要求,同时还允许按需、快速原型和净形状构建。在过去,陶瓷和金属材料原料中收获的元素的直接风化层印刷已被证明是可行的,碳热还原(CR)是迄今为止生成氧气(O2)的成功尝试。本研究采用JSC-Mars-1A火星风化模拟物与碳(C)的混合物进行激光粉末床熔融(L-PBF),同时探索AM和CR的应用。在构建纯原料和混合原料(CarPS)材料样品之前,对风化层和碳源进行了表征,并进行了x射线衍射(XRD)、能量色散x射线光谱(EDS)和压缩测试。结果表明,在相同的构建参数下,CarPS样品的压缩断裂应力降低了,样品的构建质量得到了显着提高,并且降低了总体氧含量。
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Journal of Materials Engineering and Performance
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