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International Journal of High Technology Ceramics最新文献

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Hydrothermal preparation of the low-expansion NZP family of materials 水热法制备低膨胀NZP系列材料
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90062-8
Sridhar Komarneni

This paper reports on the synthesis of low thermal expansion NaZr2(PO4)3 (NZP) and CaZr4(PO4)6 (CZP) families of materials and their analogues for each of the alkali and alkaline earth metals by the hydrothermal method. Starting gels were prepared by mixing stoichiometric proportions of alkali and alkaline earth metal chlorides of nitrates with a 0·5m ZrOCl2 solution and by titrating this mixture with a stoichiometric amount of 1·0m H3PO4 while the solution was constantly stirred. The gels were dried to remove the HCl produced during the reaction between ZrOCl2 and H3PO4, and were then heated with water in teflon-lined Parr bombs or gold capsules. In general, the hydrothermal method yielded 100–300 nm sized rhombohedral single crystals of different NZP materials at 175–200°C under saturated steam pressure conditions. The initial pH and the temperature of treatment are the most critical factors in the hydrothermal synthesis of these technologically important low expansion materials.

本文报道了用水热法制备碱金属和碱土金属的低热膨胀材料NaZr2(PO4)3 (NZP)和CaZr4(PO4)6 (CZP)族及其类似物。将化学计量比例的碱和碱土金属氯化物的硝酸盐与0·m的ZrOCl2溶液混合,并以化学计量量的1·m H3PO4滴定,不断搅拌,制备起始凝胶。将凝胶干燥以去除ZrOCl2和H3PO4反应时产生的HCl,然后在铁氟龙衬里的Parr炸弹或金胶囊中加水加热。总的来说,水热法在175 ~ 200℃的饱和蒸汽压力条件下,得到了不同NZP材料尺寸为100 ~ 300 nm的菱形单晶。初始pH值和处理温度是水热合成这些技术上重要的低膨胀材料的最关键因素。
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引用次数: 26
Crystal structure change of thermistor of MnCoz.sbnd;Ni oxides in firing process 烧成过程中mncoz、sbnd、Ni氧化物热敏电阻晶体结构的变化
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90073-2
Takeshi Meguro, Tadashi Sasamoto, Takashi Yokoyama, Satoru Yamada, Yoshiaki Abe, Naochika Torikai
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引用次数: 0
Contents of volume 4 第四卷内容
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90058-6
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引用次数: 0
Elastic properties of engineering ceramics at elevated temperature 工程陶瓷的高温弹性性能
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90090-2
Shuji Sakaguchi, Fumihiro Wakai, Yosoo Matsuno
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引用次数: 5
Machine design requirements for uniaxial testing of ceramics materials 陶瓷材料单轴试验机器设计要求
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90042-2
J.E. Amaral, C.N. Pollock
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引用次数: 4
High-temperature flexural strength of engineering ceramics 工程陶瓷的高温抗弯强度
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90050-1
A. Marsh, D.A. Bell

The BCRL high-temperature flexural strength facility has been developed using the most suitable methods reported in the scientific literature. Temperature monitoring and control, together with stress-strain measurement are performed by a microcomputer with 16-bit analogue-to-digital converters, and the results are outputted to an intelligent plotter. The equipment is suitable for measurements on high strength ceramics and has been fully evaluated on a wide range of engineering ceramic materials.

该BCRL高温弯曲强度设施已开发使用最合适的方法在科学文献报道。温度监测、控制和应力应变测量由16位模数转换器的微型计算机完成,并输出到智能绘图仪。该设备适用于高强度陶瓷的测量,并已在各种工程陶瓷材料上进行了全面评估。
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引用次数: 1
Effects of ZrO2 ultrafine particle additive on the formation of Al2O3 from sulfate ZrO2超细颗粒添加剂对硫酸盐生成Al2O3的影响
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90079-3
Keiji Daimon, Etsuro Kato
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引用次数: 0
Successive phase transitions of BaTiO3 ceramics synthesized by powder-calcination 粉末煅烧合成BaTiO3陶瓷的连续相变
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90063-X
Akihiro Hamano, Tooru Atake, Yasutoshi Saito

The BaTiO3 ceramics has been synthesized by calcining the powdered reactants BaCO3 and TiO2 at various temperatures, to examine the influences of calcination temperature on the successive phase transitions. The properties of the products have been studied by differential thermal analysis, dielectric measurements, X-ray diffraction and scanning electron microscopy. While the cubic-tetragonal transition temperature shifts towards higher temperatures with increasing calcination temperature, the lower two transitions shift towards lower temperatures. The thermal and dielectric anomalies due to the phase transitions increase as the calcination temperature rises.

将粉末反应物BaCO3和TiO2在不同温度下煅烧合成了BaTiO3陶瓷,考察了煅烧温度对连续相变的影响。用差热分析、介电测量、x射线衍射和扫描电镜对产物的性质进行了研究。随着煅烧温度的升高,立方四方转变温度向高温方向转变,而低两种转变温度向低温方向转变。相变引起的热异常和介电异常随着煅烧温度的升高而增大。
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引用次数: 5
Solubility of MgO in single-crystal Al2O3 MgO在单晶Al2O3中的溶解度
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90075-6
Ken Ando, Masataka Momoda
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引用次数: 12
Behavior of mirror-like region of sintered Si3N4 under rotary bending 旋转弯曲下烧结Si3N4镜面区的行为
Pub Date : 1988-01-01 Epub Date: 2003-06-11 DOI: 10.1016/0267-3762(88)90089-6
Haeng-Nam Ko
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引用次数: 7
期刊
International Journal of High Technology Ceramics
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