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Current Opinion in Colloid & Interface Science最新文献

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Colloidal phenomena reflect the interplay between interfacial solution structure, interparticle forces, and dynamical response 胶体现象反映了界面溶液结构、粒子间作用力和动力学响应之间的相互作用
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-12-06 DOI: 10.1016/j.cocis.2024.101887
Jaeyoung Heo , Pravalika Butreddy , Gregory K. Schenter , Christopher J. Mundy , James J. De Yoreo , Elias Nakouzi , Jaewon Lee , Jaehun Chun
The physical and chemical properties of colloidal systems are central to both natural and synthetic processes that enable a wide range of energy and environmental applications. These properties are an emergent outcome of the structure that colloidal systems adopt in response to the interplay of electrical, van der Waals, hydration, and steric forces coupled to the inherent fluctuations of the system. Here we review the nature of those forces and show how variations in their relative importance lead to distinct free energy landscapes and consequent dynamic behaviors, illustrated for colloidal dispersions, nanocrystal superlattices, and single crystals formed through oriented attachment. We end by discussing the challenges to future progress arising from the need to seamlessly couple from molecular to particle to ensemble scales.
胶体系统的物理和化学性质是自然和合成过程的核心,可以实现广泛的能源和环境应用。这些性质是胶体系统在电学、范德华、水合作用和系统固有波动耦合的空间力的相互作用下所采用的结构的紧急结果。在这里,我们回顾了这些力的性质,并展示了它们的相对重要性的变化如何导致不同的自由能景观和随之而来的动态行为,例如胶体分散,纳米晶超晶格和通过定向附着形成的单晶。最后,我们讨论了由于需要从分子到粒子到集合尺度无缝耦合而产生的未来进展的挑战。
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引用次数: 0
Progress in rheology of active colloidal systems 活性胶体体系流变学研究进展
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-12-07 DOI: 10.1016/j.cocis.2024.101886
Jacob John, Amirreza Panahi, Di Pu, Giovanniantonio Natale
We review recent theoretical and experimental developments in measuring the rheological response of active colloidal systems. Particular attention is dedicated to active and passive microrheological characterization. These techniques are essential to measure active fluctuations and micromechanical heterogeneities present in living and artificial active matter. We also discuss the coupling between viscoelasticity and collective motion in crowded active colloidal suspensions. We conclude this work with a discussion on open challenges.
我们回顾了最近在测量活性胶体系统流变反应方面的理论和实验进展。特别关注的是主动和被动微流变特性。这些技术对于测量生物和人工活性物质中存在的主动波动和微力学异质性至关重要。我们还讨论了粘弹性和集体运动之间的耦合在拥挤的活性胶体悬浮液。我们以公开挑战的讨论来结束这项工作。
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引用次数: 0
Data-driven techniques in rheology: Developments, challenges and perspective 流变学中的数据驱动技术:发展、挑战与展望
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-11-02 DOI: 10.1016/j.cocis.2024.101873
Deepak Mangal, Anushka Jha, Donya Dabiri, Safa Jamali
With the rapid development and adoption of different data-driven techniques in rheology, this review aims to reflect on the advent and growth of these frameworks, survey the state-of-the-art methods relevant to rheological applications, and explore potential future directions. We classify different machine learning (ML) methodologies into data-centric and physics-informed frameworks. Data-centric methods leverage conventional ML techniques to uncover relationships within specific datasets, demonstrating success in rheological properties prediction, material characterization, properties optimization, and accelerated numerical simulations. Physics-informed machine learning combines physical laws and domain knowledge with data to produce generalizable and physically consistent predictions, proving effective in solving rheological differential equations, utilizing multi-fidelity datasets to enhance predictions, and constitutive modeling. The paper also discusses the limitations of these approaches and the ongoing efforts to address them. Looking ahead, this article emphasizes the need for explainable ML techniques to enhance transparency and trust, improved tools for uncertainty quantification. These advancements could significantly transform rheology and non-Newtonian fluid mechanics by enabling more robust, insightful, and efficient data-driven methodologies.
随着各种数据驱动技术在流变学领域的快速发展和采用,本综述旨在反思这些框架的出现和发展,调查与流变学应用相关的最新方法,并探索潜在的未来方向。我们将不同的机器学习(ML)方法分为以数据为中心的框架和物理信息框架。以数据为中心的方法利用传统的 ML 技术来揭示特定数据集中的关系,在流变特性预测、材料表征、特性优化和加速数值模拟方面取得了成功。物理信息机器学习将物理定律和领域知识与数据相结合,以产生可推广的、物理上一致的预测结果,在求解流变微分方程、利用多保真度数据集增强预测结果以及构造建模方面证明是有效的。本文还讨论了这些方法的局限性以及为解决这些问题正在进行的努力。展望未来,本文强调需要可解释的 ML 技术来提高透明度和信任度,并改进不确定性量化工具。这些进步可以使数据驱动的方法更稳健、更有洞察力、更高效,从而极大地改变流变学和非牛顿流体力学。
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引用次数: 0
A glance at the future. Biosurfactants at the interface between colloids and surface science, from academia to industry 展望未来。从学术界到工业界,生物表面活性剂处于胶体与表面科学的交界处
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-10-15 DOI: 10.1016/j.cocis.2024.101870
Niki Baccile, Jochen Kleinen
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引用次数: 0
Driving the future of cosmetics, fragrances and foods with COSMO-RS.Part 2–From theory to practice 用cosmos - rs引领化妆品、香水和食品的未来。第二部分:从理论到实践
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-11-25 DOI: 10.1016/j.cocis.2024.101876
Théophile Gaudin , Jean-Marie Aubry
The second part of this two-part review provides a comprehensive overview of the practical applications of COSMO-RS methodology in the formulation of cosmetics, fragrances, and foods. The current literature predominantly focuses on the recovery and characterization of ingredients, with fewer studies addressing end-use formulations. Four major types of applications have been identified and are discussed (i) the extraction of active ingredients and additives from biomass, by far the most documented, (ii) their solubilization in skin-compatible or ingestible solvents, (iii) the selection of fragrant molecules to establish a predefined olfactory profile, and finally, (iv) the physico-chemical characterization of ingredients to maximize their sensory performance and safety. For further familiarization with COSMO-RS, the typical calculation procedures are demonstrated step-by-step for key target properties.
这两部分综述的第二部分提供了COSMO-RS方法在化妆品,香水和食品配方中的实际应用的全面概述。目前的文献主要集中在成分的回收和表征,较少的研究解决最终用途的配方。已经确定并讨论了四种主要的应用类型:(i)从生物质中提取活性成分和添加剂,这是迄今为止记录最多的,(ii)它们在皮肤相容或可摄取溶剂中的溶解,(iii)选择芳香分子以建立预定义的嗅觉特征,最后,(iv)成分的物理化学表征以最大化其感官性能和安全性。为了进一步熟悉cosmos - rs,本文逐步演示了关键目标属性的典型计算过程。
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引用次数: 0
Biosurfactants and bioamphiphiles, survey, perspectives and applicative potential from a colloid science point of view 从胶体科学的角度看生物表面活性剂和生物亲两性试剂的综述、前景和应用潜力
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-12-13 DOI: 10.1016/j.cocis.2024.101891
Niki Baccile , Jochen Kleinen
Biological surfactants are amphiphilic molecules obtained from biobased resources, like plants, sugars and oils, using a variety of physical, chemical, biochemical or biotechnological methods. More specifically, the word biosurfactant, or microbial biosurfactants, is classically used for those molecules, like sophorolipids, rhamnolipids or surfactin, produced by fermentation. Historically developed by microbiologists and originally used as natural emulsifiers, recent trends in fundamental and applied research depict a set of molecules with a rich, and somewhat unexpected, physicochemical behavior making it difficult to introduce them as such in existing formulations. A broad research activity is then developing worldwide both in academia and industry with the goal of better understanding this class of amphiphiles with the ultimate perspective of introducing them to the market in fields as varied as detergency, cosmetics, pest control and medicine.
生物表面活性剂是从植物、糖和油等生物资源中通过各种物理、化学、生化或生物技术方法获得的两亲性分子。更具体地说,生物表面活性剂或微生物生物表面活性剂通常用于那些通过发酵产生的分子,如槐脂、鼠李糖脂或表面素。历史上是由微生物学家开发的,最初用作天然乳化剂,最近的基础和应用研究趋势描述了一组具有丰富的,有些意想不到的物理化学行为的分子,这使得很难在现有配方中引入它们。一项广泛的研究活动正在全世界学术界和工业界开展,目的是更好地了解这类两亲植物,并最终将它们引入市场,用于洗涤剂、化妆品、害虫防治和医药等领域。
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引用次数: 0
The underestimated and important role of thiol moieties in predicting the fate of toxic metals in the environment 巯基部分在预测环境中有毒金属的命运方面被低估的重要作用
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-12-06 DOI: 10.1016/j.cocis.2024.101888
Charlotte Catrouillet , Marc F. Benedetti , Alexandre Gelabert , Eric van Hullebusch , Rémi Marsac
Studying the interactions between metals and thiol moieties in natural systems is challenging, although they are of major importance for some (ultra)trace elements (e.g. Hg, Cu, Pt). A major current bottleneck is the development of accurate preservation and detection methods. Based on our current knowledge, thiol moieties are abundant in reduced organic waters, where thiolation of natural organic matter (NOM) occurs, as well as in metal-enriched environments, where organisms secrete thiol moieties. Depending on their affinity and their redox potential, metals complexed to thiolated NOM can be reduced and even transformed into sulfur nanoparticles over time. Such mechanisms are not properly considered in currently used biogeochemical models, explaining why the fate of metals in the environment is not well predicted.
研究自然系统中金属与硫醇部分之间的相互作用是具有挑战性的,尽管它们对某些(超)微量元素(如汞,铜,铂)具有重要意义。目前的一个主要瓶颈是开发准确的保存和检测方法。根据我们目前的知识,硫醇部分在还原有机水中是丰富的,其中天然有机物(NOM)发生硫代化,以及在富含金属的环境中,生物分泌硫醇部分。随着时间的推移,取决于它们的亲和力和氧化还原电位,金属与硫化的NOM络合可以被还原,甚至转化为硫纳米颗粒。这种机制在目前使用的生物地球化学模型中没有得到适当的考虑,这解释了为什么金属在环境中的命运不能很好地预测。
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引用次数: 0
Recent progress in I-III-VI colloidal quantum dots-integrated solar cells I-III-VI胶体量子点集成太阳能电池研究进展
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-12-09 DOI: 10.1016/j.cocis.2024.101890
Zhonglin Du , Dongling Ma
Colloidal quantum dots (CQDs) have emerged as an important class of nanocrystal materials for solar cell applications due to their outstanding properties, including tunable band gap, high charge carrier mobility, remarkable light absorption range, solution-processability, scalability, etc. The Lead (Pb)/Cadmium (Cd)-free I-III-VI QDs, designed by the reasonable chemical substitution of Pb and Cd with non-toxic elements, are booming as an attractive alternative for practical applications. This review summarizes the recent progress in designing typical I-III-VI QDs and their application in various emerging solar cell applications. The performance improvement of various solar cells due to the integration of QDs having different roles and modified device structures is summarized. In addition, the fundamentals of the I-III-VI QDs, including their crystalline structure, optical properties, and synthesis mechanisms, are described. Finally, we provide perspectives on the current status, challenges, and future directions of I-III-VI QDs-integrated solar cells.
胶体量子点(CQDs)由于其优异的性能,包括可调带隙、高载流子迁移率、显著的光吸收范围、溶液可加工性、可扩展性等,已成为太阳能电池应用中重要的一类纳米晶体材料。利用无毒元素对铅和镉进行合理的化学替代,设计出无铅(Pb)/镉(Cd)的I-III-VI量子点,是一种极具应用前景的替代材料。本文综述了近年来典型的I-III-VI量子点的设计及其在各种新兴太阳能电池中的应用。综述了不同作用量子点的集成和器件结构的改进对各种太阳能电池性能的改善。此外,还描述了I-III-VI量子点的基本原理,包括它们的晶体结构、光学性质和合成机制。最后,对I-III-VI量子点集成太阳能电池的现状、挑战和未来发展方向进行了展望。
{"title":"Recent progress in I-III-VI colloidal quantum dots-integrated solar cells","authors":"Zhonglin Du ,&nbsp;Dongling Ma","doi":"10.1016/j.cocis.2024.101890","DOIUrl":"10.1016/j.cocis.2024.101890","url":null,"abstract":"<div><div>Colloidal quantum dots (CQDs) have emerged as an important class of nanocrystal materials for solar cell applications due to their outstanding properties, including tunable band gap, high charge carrier mobility, remarkable light absorption range, solution-processability, scalability, <em>etc</em>. The Lead (Pb)/Cadmium (Cd)-free I-III-VI QDs, designed by the reasonable chemical substitution of Pb and Cd with non-toxic elements, are booming as an attractive alternative for practical applications. This review summarizes the recent progress in designing typical I-III-VI QDs and their application in various emerging solar cell applications. The performance improvement of various solar cells due to the integration of QDs having different roles and modified device structures is summarized. In addition, the fundamentals of the I-III-VI QDs, including their crystalline structure, optical properties, and synthesis mechanisms, are described. Finally, we provide perspectives on the current status, challenges, and future directions of I-III-VI QDs-integrated solar cells.</div></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"75 ","pages":"Article 101890"},"PeriodicalIF":7.9,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143104797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding elasticity and swellability of polymer gels from a perspective of polymer/solvent interaction 从聚合物/溶剂相互作用的角度理解聚合物凝胶的弹性和溶胀性
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-11-01 DOI: 10.1016/j.cocis.2024.101872
Jian Tang, Quan Chen
Polymer gels are three-dimensional polymer networks swollen by solvents. They exhibit high elasticity and swellability and are widely used in many fields. The design, development, and application of these materials are all dependent on a precise understanding of molecular mechanisms of elasticity and swellability. The development of a model polymer gel system with a uniform structure and low degree of defects facilitates the test of these mechanisms. This review summarized the recent progress in understanding the local polymer/solvent interaction in determining the elasticity and swellability of the model polymer gels. A particular emphasis is placed on the relationship between the conformation of the precursor chains on a microscopic scale and the modulus and swelling ratio of polymer gels on a macroscopic scale under the influence of the polymer/solvent interaction. Knowledge of the relationship plays a vital role in the future development of novel functional polymer gel materials.
聚合物凝胶是被溶剂溶胀的三维聚合物网络。它们具有高弹性和高膨胀性,被广泛应用于许多领域。这些材料的设计、开发和应用都依赖于对弹性和溶胀性分子机理的精确理解。开发结构均匀、缺陷程度低的聚合物凝胶模型系统有助于测试这些机理。本综述总结了最近在理解决定模型聚合物凝胶弹性和溶胀性的局部聚合物/溶剂相互作用方面取得的进展。其中特别强调了在聚合物/溶剂相互作用的影响下,前体链在微观尺度上的构象与聚合物凝胶在宏观尺度上的模量和溶胀率之间的关系。对这一关系的了解对未来新型功能聚合物凝胶材料的开发起着至关重要的作用。
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引用次数: 0
Direct ink writing of particle-based multiphase materials: From rheology to functionality 颗粒基多相材料的直墨书写:从流变性到功能性
IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-02-01 Epub Date: 2024-12-12 DOI: 10.1016/j.cocis.2024.101889
Stijn De Smedt , Benedetta Attaianese , Ruth Cardinaels
Direct ink writing (DIW) allows producing complicated geometries by extruding material from a nozzle. The ink has to meet certain material requirements during and after printing for the object to be successfully produced. Meanwhile, the functionality requirements of the end-use application should be met. This paper attempts to provide the rheological basis and critical view to understand the material requirements for DIW inks and to help in making the bridge between the rheology and printability of particle-based multiphase DIW inks while meeting the functional demands of the end product. Colloidal suspensions and Pickering emulsions are often used as material classes for DIW. Some of the most important and noteworthy applications are described for both material classes. Thereafter, a more novel, particle-based multiphase system for DIW, namely capillary suspensions, is briefly discussed.
直接墨水书写(DIW)允许通过从喷嘴挤出材料来生产复杂的几何形状。油墨必须在印刷过程中和印刷后满足一定的材料要求,才能成功地生产出来。同时,应满足最终用途应用程序的功能需求。本文试图为了解DIW油墨的材料要求提供流变学基础和批判性观点,并有助于在满足最终产品功能需求的同时,在颗粒基多相DIW油墨的流变学和印刷性之间搭建桥梁。胶体悬浮液和皮克林乳剂通常用作DIW的材料类别。介绍了这两种材料的一些最重要和最值得注意的应用。然后,简要讨论了一种更新颖的基于颗粒的DIW多相系统,即毛细管悬浮液。
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引用次数: 0
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Current Opinion in Colloid & Interface Science
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