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Composition-Driven Structural and Thermo-Physical Evolution in In–Sb–Se Chalcogenide Glasses: A Theoretical Study in - sb - se硫系玻璃成分驱动结构和热物理演化的理论研究
IF 0.3 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-07-17 DOI: 10.1134/S1028335826600094
Diksha Sharma, Rita Sharma, Lakshay Dhiman

The present work investigates the influence of indium incorporation on the structural and thermo-physical characteristics of In–Sb–Se chalcogenide glass systems, InxSb30Se70 – x (x = 0–25), using a theoretical framework. A set of composition-dependent parameters including average coordination number, bond energy, network constraints, heat of atomization, deviation from stoichiometry, and lone-pair electron concentration were evaluated to understand the evolution of network connectivity and thermal stability. The results indicate that increasing indium content leads to enhanced network rigidity, as reflected by higher coordination numbers, increased bond strength, and reduced structural disorder. The decrease in lone-pair electrons and deviation from stoichiometry suggests improved cross-linking within the glassy network, contributing to enhanced thermal stability. In addition, a simple machine-learning-based regression model was employed as a supplementary validation tool to examine correlations between selected structural parameters and the glass transition temperature (Tg). The close agreement between theoretical predictions and regression-based estimates confirms the consistency and robustness of the adopted approach. The present study provides a systematic theoretical understanding of composition-driven trends in In–Sb–Se chalcogenide glasses and offers useful guidance for tailoring their thermo-physical properties.

本研究使用理论框架研究了铟掺入对In-Sb-Se硫系玻璃体系InxSb30Se70 - x (x = 0-25)的结构和热物理特性的影响。通过评价平均配位数、键能、网络约束、原子化热、化学计量偏差和孤对电子浓度等组成相关参数来了解网络连通性和热稳定性的演变。结果表明,铟含量的增加导致网络刚度的增强,表现为配位数的增加、键合强度的增加和结构无序性的降低。孤对电子的减少和化学计量的偏离表明,玻璃网络内的交联得到了改善,有助于增强热稳定性。此外,采用简单的基于机器学习的回归模型作为辅助验证工具,检查所选结构参数与玻璃化转变温度(Tg)之间的相关性。理论预测和基于回归的估计之间的密切一致证实了所采用方法的一致性和稳健性。本研究为in - sb - se硫系玻璃的成分驱动趋势提供了系统的理论认识,并为调整其热物理性质提供了有用的指导。
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引用次数: 0
Tailored Synthesis and Detailed Characterization of Ni–Mg Co-doped CuO Nanostructures for Photocatalytic Degradation Efficiency Ni-Mg共掺杂CuO纳米结构的合成及光催化降解效率的详细表征
IF 0.3 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-07-17 DOI: 10.1134/S1028335826600367
Sonia Attaf, Fouzia Abbas, Ouassila Benzaoui, Bouchra Slimani, Rosalba Fittipaldi, Chourouk Namoune, Rabeh Bensaha

In this study, we synthesized and investigated the influence of dopant nature on copper oxide nanoparticles (NPs) for four compositions: undoped CuO, Ni-doped CuO (Cu0.95Ni0.05O), Mg-doped CuO (Cu0.95Mg0.05O), and (Ni,Mg) co-doped CuO (Cu0.90Ni0.05Mg0.05O), using the sol–gel method. Samples were characterized through various characterization techniques and by photocatalytic performance. X-ray diffraction (XRD) analysis confirmed single-phase monoclinic CuO structure. (Ni,Mg) co-doping significantly reduced the average crystallite size from 20.95 to 6.24 nm. Scanning electron microscopy (SEM) demonstrated that the incorporation of Ni and Mg affected the morphology of the CuO NPS. Fourier-transform infrared (FTIR) spectra confirm the formation of CuO NPs. Moreover, (Ni,Mg) co-doping generated a synergistic electronic effect, where Ni narrowed and Mg widened the band gap, yielding an optimized band structure, improved light absorption in both the visible and UV ranges. This tunability is advantageous for photocatalytic applications, as the broader spectral response improves light harvesting and, consequently, photocatalytic efficiency.

本研究采用溶胶-凝胶法制备了未掺杂CuO、Ni掺杂CuO (Cu0.95Ni0.05O)、Mg掺杂CuO (Cu0.95Mg0.05O)和(Ni,Mg)共掺杂CuO (Cu0.90Ni0.05Mg0.05O)四种成分的氧化铜纳米粒子(NPs),并研究了掺杂性质对NPs的影响。通过各种表征技术和光催化性能对样品进行了表征。x射线衍射(XRD)分析证实了CuO的单相单斜结构。(Ni,Mg)共掺杂使晶粒平均尺寸从20.95 nm减小到6.24 nm。扫描电镜(SEM)结果表明,Ni和Mg的掺入影响了CuO NPS的形貌。傅里叶变换红外光谱(FTIR)证实了CuO NPs的形成。此外,(Ni,Mg)共掺杂产生了协同电子效应,其中Ni收窄了带隙,Mg变宽了带隙,产生了优化的带结构,提高了可见光和紫外范围内的光吸收。这种可调性对光催化应用是有利的,因为更宽的光谱响应提高了光收集,从而提高了光催化效率。
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引用次数: 0
Nonlinear Second Harmonic Generation of q-Gaussian Laser Beam in Cold Quantum Plasma with Relativistic and Ponderomotive Forces 冷量子等离子体中q-高斯激光束的非线性二次谐波产生
IF 0.3 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-07-17 DOI: 10.1134/S1028335826600057
Arnika Sharma, Anuj Vijay

The current study investigates nonlinear second harmonic generation of q-Gaussian laser beam in cold quantum plasma. We considered combined action of relativistic and ponderomotive (RP) forces. The electron effective mass varies under combined action of RP forces thereby leading to variation in background plasma density across the beam’s path and causing the beam to self-focus. An electron plasma wave (EPW) is excited at laser’s original frequency due density gradients established in plasma. The nonlinear interaction of EPW with fundamental beam produces second harmonic generation (SHG). In order to explore this process, we have used standard approximations such as WKB approximation and paraxial theory to derive 2nd order ODE denoting the beam waist dynamics with dimensionless propagation distance and efficiency of 2nd harmonic generation. We also explored influence of different laser and plasma parameters on beam’s focusing behavior and the overall SHG efficiency.

本文研究了冷量子等离子体中q-高斯激光束的非线性二次谐波产生。我们考虑了相对论力和重动力(RP)力的联合作用。电子有效质量在RP力的共同作用下发生变化,从而导致光束路径上背景等离子体密度的变化,并导致光束自聚焦。由于在等离子体中建立了密度梯度,电子等离子体波以激光的原始频率被激发。EPW与基束的非线性相互作用产生二次谐波。为了探索这一过程,我们使用WKB近似和傍轴理论等标准近似,推导了二阶ODE,表示具有无因次传播距离和二次谐波产生效率的束腰动力学。我们还探讨了不同的激光和等离子体参数对光束聚焦行为和整体SHG效率的影响。
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引用次数: 0
A Novel Approach for Fabrication of Functional Carbon–Ceramic Composites with High Resistance to Gas Plasma Treatment 一种制备高抗气体等离子体处理功能碳-陶瓷复合材料的新方法
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-05-15 DOI: 10.1134/S1028335826600240
I. V. Sukmanov, O. A. Butusova, V. A. Pogodin, A. N. Astapov

This work is aimed to develop a technology for fabrication of high-temperature carbon–ceramic composite materials. The approach includes the following processing stages: the fabrication of filled carbon-fiber blanks, their subsequent carbonization, high-temperature heat treatment, and pyrolytic compaction. A distinctive feature of the technology is the impregnation of particles of refractory component precursors into the interlayer space, that ensures in situ synthesis and subsequent sintering of the ceramic component of the matrix during the carbonization and high-temperature heat treatment stages. This approach has been successfully tested in the fabrication of carbon–ceramic composites in the Cf/C system—carbides and borides of transition metals of IV (Hf, Ti) and V (Nb) groups. The results of gas-dynamic tests of samples of the resulting composites under the influence of high-speed, high-enthalpy flows of oxidizing gases are presented. It is noted that the number of functional layers and their thickness allow to regulate the magnitude of the thermal load by changing the rate of oxidation, ablation and the duration of each mode.

本工作旨在开发一种制造高温碳陶瓷复合材料的技术。该方法包括以下加工阶段:填充碳纤维毛坯的制造,随后的碳化,高温热处理和热解压实。该技术的一个显著特点是将耐火成分前驱体颗粒浸渍到层间空间中,从而确保在炭化和高温热处理阶段原位合成和随后烧结基体的陶瓷成分。该方法已成功地在Cf/C体系碳陶瓷复合材料的制备中进行了测试,其中IV (Hf, Ti)和V (Nb)族过渡金属的碳化物和硼化物。给出了复合材料样品在氧化气体高速、高焓流作用下的气动力试验结果。值得注意的是,功能层的数量及其厚度允许通过改变氧化速率、烧蚀速率和每个模式的持续时间来调节热负荷的大小。
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引用次数: 0
The Effect of Dynamic Viscosity of Hydrocarbons Saturated with Supercritical CO2 on the Filtration Process of the Hydrocarbon–Supercritical-Fluid System in a Porous Medium 饱和超临界CO2的烃类动态粘度对多孔介质中烃类-超临界-流体体系过滤过程的影响
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-05-15 DOI: 10.1134/S1028335826700011
A. V. Radaev, A. N. Sabirzyanov, N. A. Vaseneva

Experimental studies of the process of displacement of industrial oil with a viscosity of 55.2 and 88.3 mPa s from a homogeneous porous medium at pressures in the range of 8–14 MPa and temperatures of 313.333 and 353 K. It is shown that an increase in the dynamic viscosity of hydrocarbons leads to a decrease in the amount of displaced hydrocarbon from the porous medium. It has been suggested that the reduction in the amount of hydrocarbon displaced is due to the low solubility of carbon dioxide in both of the tested hydrocarbons. The dynamic viscosity of industrial oil was calculated in the pressure range of 8–14 MPa on isotherms of 313, 333, and 353 K. It is shown that the dynamic viscosity at pressures of 12 and 14 MPa decreases by 100–150%, which leads to an increase in the mobility of hydrocarbons in a porous medium.

实验研究了在压力为8 ~ 14 mPa,温度为313.333和353 K的条件下,均质多孔介质中粘度为55.2和88.3 mPa的工业油的驱替过程。结果表明,烃类动态粘度的增加会导致烃类从多孔介质中驱替量的减少。有人认为,烃类置换量的减少是由于二氧化碳在两种测试烃类中的溶解度较低。在313、333和353 K等温线上,计算了工业油在8 ~ 14 MPa压力范围内的动态粘度。结果表明,在压力为12和14 MPa时,动态粘度降低了100-150%,导致烃类在多孔介质中的流动性增加。
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引用次数: 0
An Experimental Investigation of the Normal Total Emissivity of EP718 Alloy as a Function of the Surface Condition EP718合金法向总发射率随表面条件变化的实验研究
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-05-15 DOI: 10.1134/S1028335826700023
D. V. Kosenkov, V. V. Sagadeev

This paper presents the results of an experimental investigation of the normal total emissivity (εnt) of EP718 alloy in vacuum within the temperature range of 400–1400 K. The influence of three characteristic surface conditions was systematically studied: polished, as-received (mill-finished), and air-oxidized. It is shown that the surface condition is the determining factor. For the polished and as-received surfaces, good agreement with data for the foreign analogue Inconel 718 is demonstrated. For the oxidized surface, nonmonotonic dependence εnt(T) was observed, with a pronounced decrease at temperatures above 1200 K, which is attributed to the high-temperature degradation of the oxide layer in vacuum. The obtained data are of an estimative character and are of interest for the thermal modeling of gas-turbine engine components.

本文介绍了EP718合金在400 ~ 1400 K真空中法向总发射率(εnt)的实验研究结果。系统地研究了三种特征表面条件的影响:抛光,接收(铣削)和空气氧化。结果表明,表面条件是决定因素。对于抛光和接收表面,与国外模拟Inconel 718的数据吻合良好。对于氧化表面,εnt(T)存在非单调相关性,在1200 K以上温度下εnt(T)显著降低,这是由于氧化层在真空中高温降解所致。所获得的数据具有估计性质,对燃气涡轮发动机部件的热建模具有重要意义。
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引用次数: 0
RF Behavior and Non-Quasi-Static Modeling of Junctionless Tunnel Field Effect Transistor under Process Driven Variations 工艺驱动下无结隧道场效应晶体管的射频行为和非准静态建模
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-05-15 DOI: 10.1134/S1028335825600907
Yusra Siddiqui,  Vedvrat, Imran Ullah Khan

Junctionless field effect transistors heavily rely on control gate engineering to perform. Dielectric material types, scaling of gate oxide, gate metal work, among others all choose the performance of the entire device. This paper simulates and analyses a graphene nanoribbon double gate junctionless tunnel field effect transistor (DG-JL GNR-TFET) using a non-quasi-static small-signal model to investigate its radio frequency properties. The control gate engineering effect, dielectric choice, and oxide scaling has been evaluated in detail with regard to device performance. The experiment shows that as the thickness of the oxide is increased, the efficiency of tunneling increases and the cut-off frequency (fT) reaches a maximum of 1.01 × 1012 Hz when the oxide thickness is 1nm thick. Electrostatic control is further enhanced by high-k dielectrics with TiO2 (2 nm) giving the best trade-off, with current ratio of 2.61 × 1012, subthreshold swing of 20.75 mV/dec, transconductance of 0.36 mS and gate capacitance of 0.065 fF at 1 V gate and drain voltages. Work function variation reveals an inverse dependence of frequency on work function, with the highest value (5.23 × 1011 Hz) obtained at 4.1 eV. Comparative benchmarking against reported tunnel field effect transistors highlights the superior switching ratio and steep subthreshold swing of the proposed device, confirming its potential for low-power, high-efficiency radio frequency front-end circuits and emerging Internet of Everything applications.

无结场效应晶体管在很大程度上依赖于控制栅极工程。介电材料类型、栅氧化物的缩放、栅金属工作等都选择了整个器件的性能。本文采用非准静态小信号模型对石墨烯纳米带双栅无结隧道场效应晶体管(DG-JL GNR-TFET)进行了仿真分析,研究了其射频特性。对控制栅的工程效果、介电介质的选择和氧化垢对器件性能的影响进行了详细的评价。实验表明,随着氧化层厚度的增加,隧穿效率增加,截止频率(fT)在氧化层厚度为1nm时达到最大值1.01 × 1012 Hz。在1 V栅极和漏极电压下,高k电介质TiO2 (2 nm)的电流比为2.61 × 1012,亚阈值摆幅为20.75 mV/dec,跨导率为0.36 mS,门电容为0.065 fF,从而进一步增强了静电控制。功函数的变化表明频率与功函数呈反比关系,在4.1 eV时达到最大值(5.23 × 1011 Hz)。与已报道的隧道场效应晶体管的比较基准测试突出了该器件优越的开关比和陡峭的亚阈值摆动,证实了其在低功耗、高效率射频前端电路和新兴的万物互联应用中的潜力。
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引用次数: 0
Analytical Investigation of q-Gaussian Beam Propagation in Cold Quantum Plasma with Absorption Effects 具有吸收效应的冷量子等离子体中q-高斯光束传输的分析研究
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-05-14 DOI: 10.1134/S1028335826600045
Keshav Walia

The analytical investigation of q-Gaussian beam propagation in cold quantum plasma with absorption effects is carried out in current study. The nonlinear differential equation showing response of beam waist with dimensionless distance is obtained within framework of Wentzel–Kramers–Brillouin and paraxial theory approaches. The effect of absorption coefficient is also introduced in present study. The nonlinear differential equation is obtained numerically using standard Runge–Kutta method. The key parameters of laser-plasma including beam intensity, plasma density, q-parameter, beam radius and linear absorption coefficient are systematically varied for exploring beam dynamics of q-Gaussian laser profile. The findings of this study are contrasted with corresponding behavior in classical relativistic plasma for highlighting the distinct features arising due to quantum regime.

本文对具有吸收效应的q-高斯光束在冷量子等离子体中的传播进行了分析研究。在Wentzel-Kramers-Brillouin和傍轴理论的框架下,得到了梁腰响应随无因次距离变化的非线性微分方程。本文还介绍了吸收系数的影响。采用标准龙格-库塔法对非线性微分方程进行数值求解。系统地改变激光等离子体的关键参数,包括光束强度、等离子体密度、q参数、光束半径和线性吸收系数,以探索q-高斯激光轮廓的光束动力学。本研究结果与经典相对论等离子体的相应行为进行了对比,突出了量子机制引起的独特特征。
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引用次数: 0
Terahertz Generation in Collisional Plasma: A Comparative Study of Slanted Density Profiles Using Radially Polarized q-Gaussian Laser Beams 碰撞等离子体中的太赫兹产生:使用径向偏振q-高斯激光束的倾斜密度分布的比较研究
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-05-14 DOI: 10.1134/S1028335826600082
Himani Kokila, Vivek Sharma, Vishal Thakur

Laser-plasma interaction-based terahertz (THz) radiation sources are being actively studied due to their tunability and large output potential. In this research, we analyze the theoretical study of THz wave generation driven by two radially polarized q-Gaussian laser beams propagating through a slanting density collisional plasma. A model is formulated to study the effect of plasma density gradient on the nonlinear ponderomotive force. This force is responsible for creating nonlinear current density that emits THz. Factors such as variation in plasma density, density gradient (({{n}_{r}})), background plasma density (({{n}_{0}})), beam radial position ((r)), electron neutral collision frequency (({{nu }_{{{text{en}}}}})) and the q-parameter have been included in the model. A comparison analysis, along with 3D graphical results, indicates that the output of THz enhances in case of positive density gradient but the q-parameter govern the field amplitude. According to these findings, the adjustment of plasma density profile and beam structure allows higher quality and tunable THz generation. The findings provide valuable guidance to developing plasma-based THz sources with efficient and structured plasma waveguides.

基于激光等离子体相互作用的太赫兹(THz)辐射源由于其可调谐性和巨大的输出潜力而受到积极的研究。在本研究中,我们分析了两束径向偏振q-高斯激光束在斜密度碰撞等离子体中传播时产生太赫兹波的理论研究。建立了等离子体密度梯度对非线性质动势的影响模型。这种力负责产生非线性电流密度,发射太赫兹。模型中考虑了等离子体密度变化、密度梯度(({{n}_{r}}))、背景等离子体密度(({{n}_{0}}))、束流径向位置((r))、电子中性碰撞频率(({{nu }_{{{text{en}}}}}))和q参数等因素。对比分析和三维图形结果表明,当密度梯度为正时,太赫兹的输出增强,但q参数控制场幅值。根据这些发现,调整等离子体密度分布和光束结构可以产生更高质量和可调谐的太赫兹。这些发现为开发具有高效和结构化等离子体波导的等离子体太赫兹源提供了有价值的指导。
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引用次数: 0
Investigation of the Thermomechanical Properties of a Polylactic Acid/ZnO Biocomposite Film Distained for Food Packaging 食品包装用聚乳酸/ZnO生物复合膜的热机械性能研究
IF 0.5 4区 物理与天体物理 Q4 MECHANICS Pub Date : 2026-04-20 DOI: 10.1134/S1028335825600750
S. Hadjab, F. Boufelgha, R. Zellagui, N. Brihi, A. Rouabah

Studies have been conducted on how the structural, thermal, morphological, mechanical, and antibacterial properties of PLA polymer are affected by low filling concentrations of ZnO nanoparticles. This study proposes the fabrication of biodegradable PLA–ZnO films with ZnO filling percentages ranging from 2.5 to 40%, utilising a cost-effective process involving solvent casting combined with ultrasonication at room temperature. The films were characterised using XRD, FTIR, SEM, TGA testing, tensile testing, and antibacterial testing against E. coli and S. aureus. The integration of ZnO affects the structural semi-crystallisation of the PLA matrix and prefers an hkl crystallographic orientation as support. SEM images confirmed the efficient dispersion of nanoparticles in all films, which has a direct impact on thermal stability. Regarding mechanical properties, tests conducted according to the ATMD-882 standard demonstrated good properties even at the saturation point of 40%. Ultimately, this study demonstrates that biodegradable films exhibit effective antibacterial activity against E. coli and S. aureus, even at low filling ratios, thereby suggesting their potential applicability in the food packaging sector.

研究了低氧化锌填充浓度对PLA聚合物的结构、热、形态、力学和抗菌性能的影响。本研究提出了一种采用溶剂铸造和室温超声相结合的低成本工艺,制备可生物降解的PLA-ZnO薄膜,其ZnO填充率在2.5%至40%之间。采用XRD、FTIR、SEM、TGA测试、拉伸测试以及对大肠杆菌和金黄色葡萄球菌的抗菌测试对膜进行了表征。ZnO的集成影响了PLA基体的结构半结晶,并倾向于以hkl晶体取向作为支撑。SEM图像证实了纳米颗粒在所有薄膜中的有效分散,这对热稳定性有直接影响。在力学性能方面,根据ATMD-882标准进行的测试表明,即使在40%的饱和点下,性能也很好。最后,本研究表明,即使在低填充率下,生物可降解薄膜也能对大肠杆菌和金黄色葡萄球菌表现出有效的抗菌活性,从而表明其在食品包装领域的潜在适用性。
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引用次数: 0
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Doklady Physics
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