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Insight into the principles of photothermal superhydrophobic coatings, recent advances in anti-/de-icing, frontier applications and future challenges 深入了解光热超疏水涂层的原理,防/除冰的最新进展,前沿应用和未来挑战
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-10 DOI: 10.1016/j.cis.2026.103830
Zilong Liu , Qian Xu , Yueqi Zhu , Nian Xu , Huaqiang Chu , Jian Wang
Photothermal superhydrophobic coatings originate from the synergistic integration of photothermal performance and superhydrophobic properties. Their dual anti-icing and de-icing protection system is extremely valuable in basic research and technical innovation, which has shown broad application prospects in wind power, aerospace, transportation and other fields. Although photothermal superhydrophobic coatings are significantly superior to traditional de-icing methods in terms of energy efficiency and anti-icing effectiveness, they still pose considerable challenges in practical applications. The paper reviews the latest progress in photothermal superhydrophobic coatings for anti-/de-icing. It firstly explains the basic principles of superhydrophobic coatings, including contact angle hysteresis, photothermal conversion mechanisms and their influencing factors. Based on a functional approach, this paper details the latest research findings and technological breakthroughs in four areas of photothermal superhydrophobic coatings: anti-/de-icing, self-healing, transparent self-cleaning and all-weather anti-icing. Analyze its current applications in wind power, aerospace, power and communications, and transportation based on engineering application cases. Finally, the system reviews the challenges of coatings in terms of mechanical durability, large-scale preparation, environmental protection, transparency and all-weather adaptability. The future direction is proposed from multiple dimensions, including material innovation, process optimization, structural design, etc., providing theoretical guidance and technical reference for industrialization.
光热超疏水涂层是光热性能和超疏水性能协同结合的产物。其双重防冰除冰保护系统在基础研究和技术创新方面极具价值,在风电、航空航天、交通运输等领域显示出广阔的应用前景。尽管光热超疏水涂层在能源效率和防冰效果方面明显优于传统的除冰方法,但在实际应用中仍面临相当大的挑战。本文综述了光热防/除冰超疏水涂层的最新研究进展。首先阐述了超疏水涂层的基本原理,包括接触角滞后、光热转化机理及其影响因素;本文从功能的角度,详细介绍了光热超疏水涂层在防/除冰、自修复、透明自清洁和全天候防冰四个方面的最新研究成果和技术突破。结合工程应用案例,分析其在风电、航空航天、电力通信、交通等领域的应用现状。最后,系统回顾了涂料在机械耐久性、大规模制备、环境保护、透明度和全天候适应性方面面临的挑战。从材料创新、工艺优化、结构设计等多个维度提出未来发展方向,为产业化提供理论指导和技术参考。
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引用次数: 0
Trends in porous media laboratory imaging and open science practices 多孔介质实验室成像和开放科学实践的趋势
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.cis.2026.103831
Na Liu , Jakub Wiktor Both , Geir Ersland , Jan Martin Nordbotten , Martin A. Fernø
Understanding processes in geoscience porous media is fundamental to a broad spectrum of environmental and energy-related applications. These processes include multiphase fluid transport, interfacial dynamics, reactive transformations, and interactions with solids or microbial components in geological materials, all governed by wettability, capillarity, and reactive transport at fluid–fluid and fluid–solid interfaces. Laboratory-based multiscale imaging provides critical insights into these phenomena, enabling direct visualization and quantitative characterization from the nanometer to meter scale. It is essential for advancing predictive models and optimizing the design of subsurface and engineered porous systems. This review presents an integrated overview of planar imaging, surface topography and volumetric imaging techniques relevant to porous media research, emphasizing the type of information each method can provide, their applicability to porous media systems, and their inherent limitations. We highlight how imaging data are combined with quantitative analyses and modeling to bridge pore-scale mechanisms with continuum-scale behavior, and we critically discuss current challenges such as limited spatio-temporal resolution, sample representativity, and restricted data accessibility. We conduct an in-depth analysis on open-science trends in experimental and computational porous media research and find that, while open-access publishing has become widespread, the availability of imaging data and analysis code remains limited, often restricted to ‘upon request’. Finally, we underscore the importance of open sharing of imaging datasets to enable reproducibility, foster cross-disciplinary integration, and support the development of robust predictive frameworks for porous media systems.
了解地球科学多孔介质的过程是广泛的环境和能源相关应用的基础。这些过程包括多相流体输运、界面动力学、反应转化以及与地质材料中固体或微生物组分的相互作用,所有这些过程都受润湿性、毛细作用和流体-流体和流体-固体界面的反应输运所支配。基于实验室的多尺度成像提供了对这些现象的关键见解,实现了从纳米到米尺度的直接可视化和定量表征。这对于推进预测模型和优化地下和工程多孔系统的设计至关重要。本文综合介绍了与多孔介质研究相关的平面成像、表面形貌和体积成像技术,强调了每种方法可以提供的信息类型、它们在多孔介质系统中的适用性以及它们固有的局限性。我们强调了如何将成像数据与定量分析和建模相结合,以连接孔隙尺度机制与连续尺度行为,并批判性地讨论了当前的挑战,如有限的时空分辨率、样本代表性和受限的数据可访问性。我们对实验和计算多孔介质研究中的开放科学趋势进行了深入分析,发现虽然开放获取出版已经普及,但成像数据和分析代码的可用性仍然有限,通常仅限于“应要求”。最后,我们强调了开放共享成像数据集的重要性,以实现可重复性,促进跨学科整合,并支持开发强大的多孔介质系统预测框架。
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引用次数: 0
Macroscale solid superlubricity from the perspective of tribochemistry 摩擦学视角下的宏观固体超润滑
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-08 DOI: 10.1016/j.cis.2026.103812
Jing Shi , Li Tan , Hao Long , Junyan Zhang , Chengbing Wang
Superlubricity, featuring near-zero friction, has attracted much attention due to its effectiveness in addressing energy crises. The underlying mechanism of solid superlubricity is incommensurate contact. Nowadays, relying on incommensurability and weaken size effect by reducing the contact area is an effective strategy for constructing macroscale solid superlubricity. However, the lack of a more profound understanding of the entire process of constructing superlubric interfaces is not conducive to advancing the progress of practical applications. Tribochemistry serves as the main thread of the process, leading the structural evolution behavior between steady states. It is powered by friction behavior to grow the lubricating phase that constructs the superlubric interface through physical and chemical reactions. This review, from the perspective of tribochemistry, delves into the mechanisms of energy dissipation and the evolution of interface structures involved in various lubrication forms. It demonstrates that the macro-superlubricity benefits from the macroscopic expression (lubricating layers) of microscale lubricating phases. Furthermore, we also introduce the novel applications of superlubricity in advanced manufacturing technologies. Meanwhile, the groundbreaking advancements in macro-superlubricity research are systematically highlighted. This review not only effectively complements the commentary on macroscale solid superlubricity but also provides critical insights for extending solid superlubricity towards practical macroscale applications.
超润滑以其接近零摩擦的特性,因其在解决能源危机方面的有效性而受到广泛关注。固体超润滑的根本机理是不适应接触。目前,依靠不可通约性和通过减小接触面积来减弱尺寸效应是构建宏观固体超润滑的有效策略。然而,对超流体界面构建的整个过程缺乏更深刻的认识,不利于推进超流体界面实际应用的进展。摩擦化学是这一过程的主线,主导着稳定状态之间的结构演化行为。它是由摩擦行为驱动的,通过物理和化学反应来形成润滑相,从而构建超润滑界面。本文从摩擦化学的角度探讨了不同润滑形式下的能量耗散机制和界面结构的演化。结果表明,微观润滑相的宏观表现(润滑层)有利于宏观超润滑。此外,我们还介绍了超润滑在先进制造技术中的新应用。同时,系统地介绍了宏观超润滑研究的突破性进展。这一综述不仅有效地补充了宏观固体超润滑的研究成果,而且为将固体超润滑扩展到实际的宏观应用提供了重要的见解。
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引用次数: 0
Emerging synthetic strategies, tunable properties, and multifunctional applications of metal-doped carbon dots: A review 金属掺杂碳点的新合成策略、可调性能和多功能应用综述
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-07 DOI: 10.1016/j.cis.2026.103826
Elisa Herrera , Antonio Gil , Manuel Algarra
Because of its unique characteristics and numerous prospective uses, metal-doped carbon dots (M@CDs) are gaining more interest. Through orbital interactions between metal and carbon atoms, metal integration alters the electrical structure, nanostructure, and chemical makeup of carbon dots (CDs). These materials are extremely adaptable for a variety of applications since the addition of metal ions results in noticeable changes in optical, electrical, magnetic, and chemical behavior. The synthetic methods for creating M@CDs are outlined in this review, which also looks at the physicochemical characteristics of metal ions and provides examples of their use in biomedicine, sensing, imaging, and catalysis. Additionally, it describes the difficulties that M@CDs synthesis is currently facing and provides a prognosis for future advancements, paying special emphasis to new breakthroughs in multimodal biosensing that are aided by machine learning techniques.
由于其独特的特性和许多潜在的用途,金属掺杂碳点(M@CDs)越来越受到人们的关注。通过金属和碳原子之间的轨道相互作用,金属集成改变了碳点(cd)的电结构、纳米结构和化学组成。这些材料非常适用于各种应用,因为添加金属离子会导致光学,电学,磁性和化学行为的显著变化。本文概述了制造M@CDs的合成方法,并介绍了金属离子的物理化学特性,并举例说明了金属离子在生物医学、传感、成像和催化等方面的应用。此外,它还描述了M@CDs合成目前面临的困难,并对未来的进展进行了预测,特别强调了在机器学习技术的帮助下,多模态生物传感的新突破。
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引用次数: 0
Interfacial CO2 adsorption in geological carbon cycle 地质碳循环中界面CO2吸附
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-06 DOI: 10.1016/j.cis.2026.103807
Chuanjie Ren , Gensheng Li , Kaiqiang Zhang
Geological carbon cycle (GCC) directly impacts the global carbon cycle and climate change, where CO2 adsorption is one most critical factor, governs the GCC's efficiency and security. However, the fundamental mechanisms of CO2 adsorption and its effects on interfacial properties remain inadequately understood due to the inherent complexities of mineral compositions, pore structures, and wettability heterogeneities. To address these challenges, this review systematically explores the theoretical foundations of CO2 adsorption, providing a mechanistic elucidation of CO2 adsorption and its effects on interfacial properties. It integrates insights from mathematical modeling, molecular simulations, and experimental methodologies to elucidate the mechanisms of CO2 sorption and its competitive behavior with other fluid components such as CH4 and H2O in geological formations. We critically assess CO2 adsorption behaviors at diverse interfaces, including solid-fluid interfaces (organic, inorganic, and composite models) and fluid-fluid interfaces (e.g., CO2-water), and discuss influencing factors, such as pore shape/size, temperature, pressure, moisture, wettability, and external electric fields. Furthermore, the review specifically evaluates the key physicochemical mechanisms underlying CO2-interface interactions and its implications for interfacial properties, including wettability alteration, interfacial tension changes and adsorption-induced deformation. Meanwhile, we provide a comprehensive understanding of adsorption scenarios within the GCC. Finally, we outline current research challenges and identify prospects to advance the fundamental understanding of how CO2 adsorption influences mineral interfacial properties and the GCC processes, thereby contributing to global climate governance and carbon neutrality efforts.
地质碳循环直接影响全球碳循环和气候变化,其中CO2吸附是地质碳循环效率和安全性的关键因素之一。然而,由于矿物组成、孔隙结构和润湿性非均质性的内在复杂性,CO2吸附的基本机制及其对界面性质的影响仍未得到充分的了解。为了应对这些挑战,本文系统地探讨了CO2吸附的理论基础,提供了CO2吸附的机理及其对界面性质的影响。它整合了数学建模、分子模拟和实验方法的见解,以阐明二氧化碳吸附的机制及其与地质构造中其他流体组分(如CH4和H2O)的竞争行为。我们批判性地评估了CO2在不同界面上的吸附行为,包括固体-流体界面(有机、无机和复合模型)和流体-流体界面(例如CO2-水),并讨论了影响因素,如孔隙形状/大小、温度、压力、湿度、润湿性和外电场。此外,本文还特别评估了二氧化碳-界面相互作用的关键物理化学机制及其对界面性质的影响,包括润湿性改变、界面张力变化和吸附引起的变形。同时,我们提供了对GCC内部吸附情景的全面了解。最后,我们概述了当前的研究挑战,并确定了前景,以推进对二氧化碳吸附如何影响矿物界面特性和GCC过程的基本理解,从而为全球气候治理和碳中和努力做出贡献。
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引用次数: 0
Gravity-resisting directional climbing of magnetic-assembled microwheels on the vertical wall 磁力装配微轮在垂直壁面上的抗重力定向爬升
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-05-01 Epub Date: 2026-01-22 DOI: 10.1016/j.cis.2026.103789
Honger Yue , Xiaocong Chang , Dekai Zhou , Longqiu Li
Microscale wall-climbing robots hold transformative potential for biomedical applications, however, their further miniaturization is hampered by the inability to achieve efficient surface adhesion at the microscale. Here, we present a rotating magnetic field-driven strategy for a magnetic microwheel to achieve gravity-resisting directional climbing on vertical walls, including biological tissue surfaces. By modulating the rotating magnetic field strength, orientation, wedge angle between the microwheel and the vertical wall, stable hydrodynamic interactions are induced, generating controllable wet friction force to counteract gravity. Experiments demonstrate that the climbing direction of microwheels can be dynamically adjusted on demand by regulating the magnetic field strength, wedge angle, and the angle between the magnetic field plane and the z-axis, enabling precise locomotion on vertical, overhanging, and biological tissue surfaces. Reversing the magnetic field and symmetrically adjusting the wedge angle along the z-axis further allows programmable directional switching. This approach circumvents the limitations of traditional negative-pressure adhesion mechanisms at microscales, offering a novel paradigm for integrating actuation and motion control in miniature wall-climbing robots. The strategy significantly expands the application scope of wall-climbing robots in biomedical scenarios, such as targeted drug delivery and minimally invasive surgery, while providing insights for designing multifunctional microrobots with adaptive locomotion capabilities.
微型爬壁机器人在生物医学应用方面具有革命性的潜力,然而,由于无法在微型尺度上实现有效的表面粘附,它们的进一步小型化受到阻碍。在这里,我们提出了一种旋转磁场驱动的磁性微轮策略,以实现垂直壁面(包括生物组织表面)的抗重力定向攀爬。通过调节旋转磁场强度、方向、微轮与垂直壁面之间的楔角,诱导稳定的流体动力相互作用,产生可控的湿摩擦力来抵消重力。实验表明,通过调节磁场强度、楔角和磁场平面与z轴夹角,可以动态调整微轮的爬升方向,实现在垂直、悬垂和生物组织表面的精确运动。反向磁场和沿z轴对称调整楔角进一步允许可编程的方向开关。该方法克服了传统负压附着机制在微观尺度上的局限性,为微型爬壁机器人的驱动和运动控制集成提供了一种新的范例。该策略显著扩展了爬壁机器人在生物医学领域的应用范围,如靶向给药和微创手术,同时为设计具有自适应运动能力的多功能微型机器人提供了见解。
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引用次数: 0
Electrospun nanofibrous membranes for self-powered wearable air filtration systems 用于自供电可穿戴空气过滤系统的电纺纳米纤维膜
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-05-01 Epub Date: 2026-01-21 DOI: 10.1016/j.cis.2026.103786
Miaomiao Zhu , Xiaoxue Hu , Siqi Chen , Wenxuan Xu , Zhi Wang , Chenyao Hu , Jichao Zhang , Ranhua Xiong , Chaobo Huang
With the growth of society and industrialization, air pollution has intensified, disturbing the ecological balance and presenting considerable risks to human health. The development of intelligent wearable protective systems is a major breakthrough in real-time health monitoring and prevention, greatly improving personal health management outcomes. An optimal smart air filtration system must demonstrate reliable filtration efficiency, minimal air resistance, and incorporate features for health monitoring and interaction with users. As a result, it is essential to create innovative materials for air filtration that can effectively trap particulate matter (PM). The adaptability, high surface area, interconnected porosity, and configurable morphology of electrospun nanofibers make them a highly promising platform for developing high-performance air filtration media. The conversion of ambient mechanical vibrations into electrical power by piezoelectric and triboelectric nanogenerators (PENGs and TENGs) has emerged as a practical strategy for effective energy harvesting. Integrating self-powered technologies with fibrous air filtration materials to efficiently eliminate fine particulate matter provides a new and sustainable approach to air purification. This review systematically summarizes recent advances in electrospun nanofibrous membranes for self-powered, intelligent, wearable air filtration systems. It begins with an analysis of the fundamental mechanisms of air filtration, the criteria for performance evaluation, and the principles of electrospinning technology. Subsequently, the practical application performance of these filtration systems is critically examined. Finally, the review outlines prospective research directions and discusses the remaining challenges confronting self-powered air filtration systems.
随着社会和工业化的发展,大气污染加剧,扰乱了生态平衡,给人类健康带来了相当大的风险。智能可穿戴防护系统的开发是实时健康监测和预防的重大突破,极大地提高了个人健康管理的效果。最佳的智能空气过滤系统必须具有可靠的过滤效率,最小的空气阻力,并结合健康监测和与用户交互的功能。因此,创造能够有效捕获颗粒物(PM)的空气过滤创新材料至关重要。静电纺纳米纤维的适应性、高表面积、多孔性和可配置形态使其成为开发高性能空气过滤介质的一个很有前途的平台。利用压电和摩擦电纳米发电机(PENGs和TENGs)将环境机械振动转化为电能已经成为一种有效的能量收集的实用策略。将自供电技术与纤维空气过滤材料相结合,有效地消除细颗粒物,为空气净化提供了一种新的可持续方法。本文系统地综述了用于自供电、智能、可穿戴空气过滤系统的电纺纳米纤维膜的最新进展。它首先分析了空气过滤的基本机制,性能评估标准和静电纺丝技术的原理。随后,这些过滤系统的实际应用性能进行了严格的审查。最后,综述概述了未来的研究方向,并讨论了自供电空气过滤系统面临的剩余挑战。
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引用次数: 0
Protein/virus-imprinted self-assembled monolayers for real-time selective detection 用于实时选择性检测的蛋白质/病毒印迹自组装单层
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-05-01 Epub Date: 2026-01-27 DOI: 10.1016/j.cis.2026.103793
Wanlan Yang , Ru Han , Xuezhong Du
The imprinting of proteins and viruses remains among the most formidable challenges. This article reviews protein/virus-imprinted self-assembled monolayers (SAMs) fabricated in aqueous media containing alkanethiols and protein/virus templates on smooth and rough gold surfaces by self-assembly of alkanethiols around protein/virus templates via AuS bonds, without polymerization initiators. Subsequently, complementary cavities that match the shapes of templates were formed in the SAMs with selective binding sites through non-covalent interactions and dynamic covalent bonds, as well as the assistance of niches of rough gold surfaces. The technique of protein/virus-imprinted SAMs offers several great advantages: both organic solvents and polymerization initiators are avoided, preventing denaturation of proteins/viruses; the imprinted cavities reside in the SAMs, allowing rapid ingress and egress of proteins/viruses; the SAMs are constructed directly on the transducer surface, enabling signal transduction and real-time monitoring of binding events. The accuracy of potentiometric imprinted SAM sensors is demonstrated to be comparable to that of enzyme-linked immunosorbent assay. Current challenges in the rational choice of thiols and the precise engineering of surface roughness are also outlined. Collectively, the strategy of tailoring protein/virus-imprinted SAMs on gold surfaces opens a new avenue for creating smart materials and fabricating biomacromolecule sensors.
蛋白质和病毒的印记仍然是最艰巨的挑战之一。本文综述了在含有烷硫醇和蛋白质/病毒模板的水介质中,在光滑和粗糙的金表面上制备的蛋白质/病毒印迹自组装单层膜(SAMs),该膜是由烷硫醇通过au键在蛋白质/病毒模板周围自组装而成,不需要聚合引发剂。随后,通过非共价相互作用和动态共价键,以及粗糙金表面壁龛的辅助,在具有选择性结合位点的sam中形成了与模板形状匹配的互补腔。蛋白质/病毒印迹SAMs技术具有几个巨大的优点:避免了有机溶剂和聚合引发剂,防止了蛋白质/病毒的变性;印迹空腔驻留在sam中,允许蛋白质/病毒快速进出;SAMs直接构建在传感器表面,实现信号转导和绑定事件的实时监测。电位印迹SAM传感器的准确性被证明可与酶联免疫吸附测定相媲美。本文还概述了目前在合理选择硫醇和精确工程表面粗糙度方面面临的挑战。总之,在金表面上裁剪蛋白质/病毒印迹的sam的策略为创建智能材料和制造生物大分子传感器开辟了新的途径。
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引用次数: 0
Recent advances in protein modification strategies to enhance their gel formation capability and stability: Principles, mechanisms, and techniques 提高蛋白质凝胶形成能力和稳定性的蛋白质修饰策略的最新进展:原理、机制和技术
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-05-01 Epub Date: 2026-01-21 DOI: 10.1016/j.cis.2026.103790
Behnaz Hashemi , Elham Assadpour , Seid Mahdi Jafari
Proteins are becoming more and more popular as environmental and human health concerns grow, as is the demand for sustainable food sources. Among the many functional characteristics of proteins are their ability for emulsifying, gelling, and foaming. Depending on the protein content, pH, ion type, and strength, a dense three-dimensional gel network structure is produced by the denatured and aggregated proteins. The structure of proteins for gel formation can be tailored using a variety of modification strategies, including both conventional and emerging techniques. Additionally, applying different treatment conditions might change the gelation characteristics of proteins to varying degrees. At the moment, it is difficult to unlock the potential substitution of proteins since their structural properties and gelation mechanisms vary greatly from one another, and because the underlying mechanisms of proteins under different modification techniques are not fully understood. Information about the structure and processes of protein gels is provided in this review. We also explained how some processing techniques change the structure of proteins to improve gel formation and stability, as well as the chemistry behind them. Future research can examine efficient modification techniques for binary proteins to enhance their gelation ability.
随着对环境和人类健康问题的关注以及对可持续食物来源的需求的增长,蛋白质正变得越来越受欢迎。蛋白质的许多功能特征包括它们的乳化、胶凝和起泡能力。根据蛋白质含量、pH值、离子类型和强度的不同,变性和聚集的蛋白质会产生致密的三维凝胶网络结构。凝胶形成的蛋白质结构可以使用多种修饰策略来定制,包括传统和新兴技术。此外,应用不同的处理条件可能会不同程度地改变蛋白质的凝胶特性。目前,由于蛋白质的结构性质和凝胶机制彼此差异很大,并且由于不同修饰技术下蛋白质的潜在机制尚未完全了解,因此很难解锁蛋白质的潜在替代。本综述提供了有关蛋白质凝胶结构和过程的信息。我们还解释了一些加工技术如何改变蛋白质的结构,以改善凝胶的形成和稳定性,以及它们背后的化学原理。未来的研究可以探索有效的修饰技术来提高二元蛋白的凝胶能力。
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引用次数: 0
Plant-based delivery systems for bioactive compounds: Mechanisms of release and functional food applications 基于植物的生物活性化合物释放系统:释放机制和功能性食品应用
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-04-01 Epub Date: 2026-01-20 DOI: 10.1016/j.cis.2026.103787
Mohammad Tarahi , Manisha Singh , Asgar Farahnaky , Mehran Ghasemlou , Mina Dokouhaki
The increasing awareness of the relationship between diet and health has driven a growing demand for functional foods enriched with bioactive compounds. These compounds, including polyphenols, carotenoids, vitamins, minerals, peptides, and unsaturated fatty acids, provide countless health benefits beyond basic nutrition, including antioxidant, anti-inflammatory, and antimicrobial properties. However, their direct use in food matrices is often limited due to challenges related to instability, poor solubility, and insufficient bioavailability. The past decade has witnessed extensive exploration of plant-based delivery systems as effective carriers for bioactive compounds due to their biocompatibility, biodegradability, low toxicity, and sustainable sourcing. Despite the enormous efforts and booming growth of scientific publications, our understanding of the precise release mechanisms of plant-based delivery systems within complex food matrices is limited. This review presents a unified and comprehensive description of plant-based delivery systems, dissecting their structural composition, formation mechanisms, and functional characteristics. We also explore how different plant-based carrier modalities, such as micro- and nanoparticles, emulsions, hydrogels, solid lipid nanoparticles (SLNs), nanostructured lipid carriers (NLCs), and vesicular systems, can be engineered to enhance the stability, solubility, and targeted release of bioactive substances. Additionally, this review comparatively examines the mechanisms underpinning controlled release, including diffusion, swelling, enzymatic degradation, and stimuli-responsive triggers. Lastly, we highlight key hurdles that hampered the practical implementation of plant-based delivery systems and propose some future directions to overcome them. The mechanistic insight of this paper is envisioned to enhance the health benefits of bioactive compounds and support sustainability in the food and healthcare industries.
随着人们对饮食与健康之间关系的认识不断提高,对富含生物活性化合物的功能性食品的需求不断增长。这些化合物,包括多酚、类胡萝卜素、维生素、矿物质、多肽和不饱和脂肪酸,除了提供基本营养外,还提供无数的健康益处,包括抗氧化、抗炎和抗菌特性。然而,由于不稳定性、溶解度差和生物利用度不足等挑战,它们在食品基质中的直接使用往往受到限制。由于植物的生物相容性、可生物降解性、低毒性和可持续来源,在过去的十年中,人们对植物为基础的传递系统作为生物活性化合物的有效载体进行了广泛的探索。尽管付出了巨大的努力和科学出版物的蓬勃发展,但我们对复杂食物基质中植物基输送系统的精确释放机制的理解是有限的。本文综述了基于植物的给药系统的统一和全面的描述,剖析了它们的结构组成、形成机制和功能特征。我们还探讨了如何设计不同的植物载体形式,如微纳米颗粒、乳液、水凝胶、固体脂质纳米颗粒(sln)、纳米结构脂质载体(nlc)和囊泡系统,以提高生物活性物质的稳定性、溶解度和靶向释放。此外,本综述比较研究了控制释放的机制,包括扩散、肿胀、酶降解和刺激反应触发。最后,我们强调了阻碍植物基给药系统实际实施的主要障碍,并提出了一些未来克服这些障碍的方向。这篇论文的机制洞察力是为了提高生物活性化合物的健康效益,并支持食品和医疗保健行业的可持续性。
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引用次数: 0
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Advances in Colloid and Interface Science
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