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Advancements in electrorheological fluid: From structural engineering to practical application 电流变流体的进展:从结构工程到实际应用。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-11-29 DOI: 10.1016/j.cis.2025.103736
Sai Chen , Yaoxuan Shi , Ke Zhang , Hyoung Jin Choi , Jiupeng Zhao , Yao Li
An electrorheological (ER) fluid is a smart material with variable structural and rheological properties in response to an electric field. This review reports a comprehensive overview of ER materials and their various microstructures in multi-dimensions (0D, 1D, 2D, and 3D), which are designed to improve yield stress and stability, including hybrid, core-shell, porous, hollow, and anisotropic architectures. Recent advancements in ER materials selection and structural design strategies have been provided to develop high-performance ER fluid, especially in carbon-based ER materials and their nanocomposites. Additionally, several mechanisms of the ER effect were elucidated to provide fundamental insights into the polarization process. Importantly, we showcase the evolution of ER fluids and the ER devices in vibration damping, human-machine interfaces, microfluidics, and soft robotics. These applications drive innovations in next-generation intelligent systems. Finally, we discuss the existing challenges and prospects of ER fluid to highlight trends in ER smart materials.
电流变流体是一种在电场作用下具有可变结构和流变特性的智能材料。本文从多个维度(0D、1D、2D和3D)全面综述了电流变换器材料及其各种微结构,这些微结构旨在提高屈服应力和稳定性,包括混合结构、核壳结构、多孔结构、空心结构和各向异性结构。近年来,在ER材料的选择和结构设计策略方面取得的进展为开发高性能ER流体,特别是碳基ER材料及其纳米复合材料提供了条件。此外,本文还阐明了内质网效应的几种机制,为极化过程提供了基本的见解。重要的是,我们展示了电流变流体和电流变器件在减振、人机界面、微流体和软机器人方面的发展。这些应用推动了下一代智能系统的创新。最后,我们讨论了电流变流体存在的挑战和前景,以突出电流变智能材料的发展趋势。
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引用次数: 0
Catalysis for micro/nanorobots 微/纳米机器人催化
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-11-11 DOI: 10.1016/j.cis.2025.103715
Jiaqi Zhao , Jiao Jiang , Laisheng Li , Yuepeng Cai , Renfeng Dong
Catalytic reactions play a vital role in the chemical industry and daily life. They can increase the rate of chemical reactions, enhance the selectivity of responses, and reduce the energy consumption of chemical reactions. They can be used in the chemical industry, environmental protection, energy production, biochemistry, and other fields. Catalysis, an important basic chemical reaction, also plays a significant role in micro/nanorobots. Catalysis can not only convert chemical energy or other energy such as light energy into mechanical energy of micro/nanorobots, giving micro/nanorobots excellent motion performance but also enables micro/nanorobots to show excellent application potential in the field of environmental governance and detection, especially in the degradation of organic pollutants. Based on this, this paper takes the catalytic mechanism as the main line, combines the two levels of drive and application, and summarizes a series of catalytic micro/nanorobots design strategies in detail. Based on the different catalytic mechanisms, catalytic micro/nanorobots are systematically classified and introduced. Finally, the current challenges and future development trends of catalytic micro/nanorobots are carefully discussed. Hopefully, this review can further deepen the integration of catalysis and micro/nanorobots, promoting more advanced catalytic micro/nanorobots fabrication.
催化反应在化学工业和日常生活中起着至关重要的作用。它们可以提高化学反应的速率,增强反应的选择性,降低化学反应的能耗。可用于化工、环保、能源生产、生物化学等领域。催化是一种重要的基础化学反应,在微纳米机器人中也起着重要的作用。催化作用不仅可以将化学能或光能等其他能量转化为微/纳米机器人的机械能,赋予微/纳米机器人优异的运动性能,也使微/纳米机器人在环境治理和检测领域,特别是在有机污染物的降解方面显示出优异的应用潜力。基于此,本文以催化机理为主线,结合驱动和应用两个层面,详细总结了一系列催化微纳机器人的设计策略。基于不同的催化机理,对催化微纳米机器人进行了系统的分类和介绍。最后,对催化微纳米机器人目前面临的挑战和未来的发展趋势进行了详细的讨论。希望本文的综述能够进一步深化催化与微纳机器人的融合,促进更先进的催化微纳机器人的制造。
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引用次数: 0
Advancements and prospects for emulsion collectors in low-rank/oxidized coal flotation separation 乳化液捕收剂在低氧化煤浮选分离中的进展与展望。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-11-29 DOI: 10.1016/j.cis.2025.103735
Zhe Li , Bobo Zhou , Yibo Kong , Zhenchao Ma , Xuesong Yang , Lei Wang , Yangchao Xia , Xinyi Zhao , Yaowen Xing , Xiahui Gui
Emulsion, including oil-in-water (O/W) and water-in-oil (W/O) emulsions, has garnered significant attention for coal flotation separation due to its potential to enhancing dynamic processes. However, with the consumption of high-quality coal resources and the implementation of the worldwide carbon reduction strategy, large-scale separation of low-quality coal (low-rank/oxidized coal) resources have become an important choice to ensure energy supplement and green development of coal industry. This review introduces the background and importance of emulsion collector technology in low-rank/oxidized coal flotation and analyzes its fundamental principles, including collector-particle-bubble interactions involving multi-scale interfacial mechanics. Then, the review discusses research progress in various emulsion collectors, such as traditional coarse emulsion, microemulsion, nanoemulsion, high-internal phase emulsion and Pickering emulsion, from high/low energy emulsification selection, emulsion formulation optimization and oil-water interfacial behavior aspects. Specifically, the emulsion collectors can effectively enhance the dispersibility of traditional oily collectors and decrease their dosages, as well as improve the attachment efficiency and hydrophobicity of coal surface, thereby enhancing the flotation separation effects. The complicated physicochemical enhancing mechanisms between emulsion collectors, coal particles and flotation bubbles are systematically described and warrant further in-depth investigation. This review concludes with a summary of the prospects of emulsion technology in improving low-rank coal flotation efficiency, reducing agent consumption and mitigating environmental impacts. It proposes future research directions, including enhanced emulsion structure-activity relationship analysis, targeted emulsifiers design, flotation dynamic process optimization, and large-scale application, to promote commercialization and sustainable development.
乳状液包括油包水(O/W)和油包水(W/O)乳状液,由于其具有增强动态过程的潜力,在煤浮选分离中受到了广泛的关注。然而,随着优质煤炭资源的消耗和世界范围内碳减排战略的实施,低品质煤(低阶/氧化煤)资源的大规模分离已成为保证煤炭工业能源补充和绿色发展的重要选择。本文介绍了乳化液捕收剂技术在低氧化煤浮选中的应用背景和重要性,分析了其基本原理,包括捕收剂-颗粒-气泡的多尺度界面力学相互作用。然后,从高低能乳化选择、乳液配方优化和油水界面行为等方面,综述了传统粗乳液、微乳液、纳米乳液、高内相乳液和皮克林乳液等乳液捕收剂的研究进展。其中,乳化液捕收剂能有效提高传统油性捕收剂的分散性,减少其用量,提高煤表面的附着效率和疏水性,从而提高浮选分离效果。系统描述了乳化液捕收剂、煤颗粒和浮选气泡之间复杂的物理化学增强机理,值得进一步深入研究。最后,对乳化液技术在提高低阶煤浮选效率、降低药剂用量、减轻环境影响等方面的应用前景进行了展望。提出了加强乳化液构效关系分析、针对性乳化剂设计、浮选动态流程优化、规模化应用等未来研究方向,以促进商业化和可持续发展。
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引用次数: 0
Interfacial interactions of resin-based plugging agents for formation plugging in oil and gas fields: A review 树脂基封堵剂在油气田地层封堵中的界面相互作用研究进展。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-04 DOI: 10.1016/j.cis.2025.103741
Yingrui Bai , Youming Lang , Jinsheng Sun , Kaihe Lv , Jingbin Yang , Yuan Liu , Yuecheng Zhu
Based on interface science, research and application analysis are carried out on the interface action mechanism of resin-based plugging agents in the field of formation plugging. This paper outlines the classification, structural characterization, and performance evaluation of resin-based plugging agents. It reviews the research progress and current applications of thermosetting, swelling filling, temperature-sensitive adhesive, and composite resins in the plugging engineering field, elucidating their interfacial mechanisms, which include: dynamic crosslinking curing at the fluid-formation interface, adaptive swelling-filling at the interface of plugging agents, interfacial adhesion enhancement induced by thermal response, and multiphase composite synergism at complex interfaces. The paper also proposes future directions and application prospects for resin plugging agents. Current technologies face challenges such as interfacial adaptability under extreme environments in ultra-deep formations, ecological safety of interface interactions, and accuracy of intelligent interfacial response. Future research should focus on controllable crosslinking for thermosetting resins to optimize interfacial curing, intelligent response for swelling filling resins to enhance interface adaptation, interface strengthening for temperature-sensitive adhesive resin (TSAR) to improve adhesion stability, and multiphase synergy with eco-design for composite systems to regulate complex interfacial behaviors, providing efficient and environmentally friendly solutions for malignant lost circulation control.
以界面科学为基础,对树脂基封堵剂在地层封堵领域的界面作用机理进行了研究和应用分析。本文概述了树脂基堵漏剂的分类、结构表征和性能评价。综述了热固性、膨胀填充、温度敏感胶粘剂和复合树脂在封堵工程领域的研究进展和应用现状,阐述了它们的界面机理,包括:成液界面的动态交联固化、封堵剂界面的自适应膨胀填充、热响应引起的界面粘附增强以及复杂界面的多相复合协同作用。提出了树脂堵漏剂的发展方向和应用前景。目前的技术面临着超深层地层极端环境下的界面适应性、界面相互作用的生态安全性以及智能界面响应的准确性等挑战。未来的研究应集中在热固性树脂的可控交联以优化界面固化,膨胀填充树脂的智能响应以增强界面适应性,温度敏感胶粘剂树脂(TSAR)的界面强化以提高粘接稳定性,复合材料体系的多相协同与生态设计以调节复杂的界面行为。为恶性漏失控制提供高效环保的解决方案。
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引用次数: 0
Receptor-targeted metal-organic frameworks: Recent progress in synthesis, modifications, and applications in targeted drug delivery 受体靶向金属有机框架:合成、修饰和靶向给药应用的最新进展。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-06 DOI: 10.1016/j.cis.2025.103744
Hossein Poursadegh , Siamak Javanbakht , Jeremiah J. Gassensmith , Shengqian Ma , Seyed Mohammad Davachi
Metal-organic frameworks (MOFs) have emerged as pivotal materials in contemporary scientific research, offering vast potential for the development of portable and sophisticated systems. This has opened new avenues for exploration across various fields and enabled a broad spectrum of novel applications. Over the past decade, MOFs have rapidly evolved in drug delivery systems (DDS), showcasing significant advancements in the creation of novel targeted platforms. Notably, receptor-targeted MOFs have introduced innovative architectures with adaptable features, particularly in biologically relevant scaffolds, thereby suggesting alternatives for cancer therapy. This review delves into recent developments in receptor-targeted MOFs, focusing on their synthesis, chemical modification, and applications in targeted anticancer drug delivery, highlighting their potential to drive future innovations in biomedical fields.
金属有机框架(mof)已成为当代科学研究中的关键材料,为便携式和复杂系统的发展提供了巨大的潜力。这为各个领域的探索开辟了新的途径,并实现了广泛的新应用。在过去的十年中,mof在给药系统(DDS)中迅速发展,在创建新的靶向平台方面取得了重大进展。值得注意的是,受体靶向mof引入了具有适应性特征的创新结构,特别是在生物相关支架中,从而为癌症治疗提供了替代方案。本文综述了受体靶向mof的最新进展,重点介绍了它们的合成、化学修饰和在靶向抗癌药物传递中的应用,强调了它们在生物医学领域推动未来创新的潜力。
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引用次数: 0
Non-homogeneous complex fluids for conformance control and displacement: A transformative enhanced oil recovery technology 用于稠度控制和驱替的非均质复杂流体:一种变革性的提高采收率技术。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-08 DOI: 10.1016/j.cis.2025.103748
Weiyao Zhu , Yubao Gao , Qipeng Ma , Wengang Bu , Fuyong Wang , Ming Yue
The efficient exploitation of low-permeability tight reservoirs is essential to mitigating the global energy crisis. However, the development of such resources remains technically challenging owing to low fluid mobility, pronounced heterogeneity, and the limited effectiveness of conventional chemical flooding techniques. This review introduces the concept of nano−/micro-engineered non-homogeneous complex fluids (NHCFs)—tailored fluid systems designed to modulate interfacial behavior in porous media—as a transformative approach for Quaternary reservoir recovery. By integrating insights from colloid science, interfacial thermodynamics, and multiscale transport phenomena, we elucidate the underlying mechanisms of NHCFs, including wettability alteration, targeted interfacial regulation, and capillary–permeability coupling. This work synthesizes recent advances in experimental, mechanistic, and theoretical studies of NHCFs for enhanced oil recovery (EOR), establishing critical links between pore-scale interfacial processes and reservoir-scale flow dynamics. Furthermore, we propose redefining Quaternary recovery as a form of precision interfacial engineering aimed at mobilizing trapped oil in low-flow regions. Finally, the review addresses emerging directions in advanced interfacial control, intelligent multiscale regulation of NHCFs, superfluid-like flow enhancement, and unified seepage simulation frameworks, outlining a pathway for the development of next-generation EOR technologies.
低渗透致密储层的高效开发是缓解全球能源危机的关键。然而,由于流体流动性低、非均质性明显以及常规化学驱技术的有效性有限,此类资源的开发在技术上仍然具有挑战性。本文介绍了纳米/微工程非均质复杂流体(NHCFs)的概念,这是一种定制的流体系统,旨在调节多孔介质中的界面行为,是第四系油藏开采的一种变革性方法。通过整合胶体科学、界面热力学和多尺度输运现象的见解,我们阐明了nhcf的潜在机制,包括润湿性改变、靶向界面调节和毛细血管-渗透率耦合。本研究综合了NHCFs用于提高采收率(EOR)的实验、机理和理论研究的最新进展,建立了孔隙尺度界面过程和油藏尺度流动动力学之间的关键联系。此外,我们建议将第四系采油重新定义为一种旨在动员低流区困油的精密界面工程。最后,综述了先进界面控制、nhcf智能多尺度调节、类超流体增强和统一渗流模拟框架等新兴方向,概述了下一代EOR技术的发展路径。
{"title":"Non-homogeneous complex fluids for conformance control and displacement: A transformative enhanced oil recovery technology","authors":"Weiyao Zhu ,&nbsp;Yubao Gao ,&nbsp;Qipeng Ma ,&nbsp;Wengang Bu ,&nbsp;Fuyong Wang ,&nbsp;Ming Yue","doi":"10.1016/j.cis.2025.103748","DOIUrl":"10.1016/j.cis.2025.103748","url":null,"abstract":"<div><div>The efficient exploitation of low-permeability tight reservoirs is essential to mitigating the global energy crisis. However, the development of such resources remains technically challenging owing to low fluid mobility, pronounced heterogeneity, and the limited effectiveness of conventional chemical flooding techniques. This review introduces the concept of nano−/micro-engineered non-homogeneous complex fluids (NHCFs)—tailored fluid systems designed to modulate interfacial behavior in porous media—as a transformative approach for Quaternary reservoir recovery. By integrating insights from colloid science, interfacial thermodynamics, and multiscale transport phenomena, we elucidate the underlying mechanisms of NHCFs, including wettability alteration, targeted interfacial regulation, and capillary–permeability coupling. This work synthesizes recent advances in experimental, mechanistic, and theoretical studies of NHCFs for enhanced oil recovery (EOR), establishing critical links between pore-scale interfacial processes and reservoir-scale flow dynamics. Furthermore, we propose redefining Quaternary recovery as a form of precision interfacial engineering aimed at mobilizing trapped oil in low-flow regions. Finally, the review addresses emerging directions in advanced interfacial control, intelligent multiscale regulation of NHCFs, superfluid-like flow enhancement, and unified seepage simulation frameworks, outlining a pathway for the development of next-generation EOR technologies.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"348 ","pages":"Article 103748"},"PeriodicalIF":19.3,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145758621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gelatin-based electrospun nanofibers in food packaging: Overcoming obstacles and looking forward to the future 明胶基静电纺纳米纤维在食品包装中的应用:克服障碍,展望未来。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-05 DOI: 10.1016/j.cis.2025.103742
Ali Khoshkalampour , Behnam Bahramian , Reza Abedi-Firoozjah , Milad Tavassoli , Shaghayegh Ahmadi , Amir Hossein Nasri , Sepidar Seyyedi-Mansour , Swarup Roy , Seid Mahdi Jafari
Gelatin (GE) is a versatile biopolymer with many valuable properties, particularly in the context of food packaging (FPack). Its biodegradability, biocompatibility, and ability to form porous structures make it ideal for various applications. This review examines the applications of electrospun GE-based nanofibers (EGFs) and their recent advances in FPack. The majority of EGFs are determined to be biodegradable and biocompatible, with the ability to form a highly porous structure with outstanding characteristics, making them appropriate for a broad range of applications, including FPack. However, native GE has limitations, such as sensitivity to moisture, which can restrict its use in certain applications. To address these limitations, researchers are exploring ways to enhance the properties of GE-based materials. EGFs are produced with a variety of natural and synthetic ingredients to increase their physical, mechanical, elastic, water resistance, vapor barrier, UV-blocking, and thermal stability properties. Furthermore, EGFs have antimicrobial and antioxidant properties that help to extend the shelf life of many food products. The prospective uses, challenges, and limitations of EGFs in FPack are also addressed. Overall, EGFs show promise as a sustainable and effective packaging material, but further research is needed to optimize their properties and ensure their safety for use in FPack.
明胶(GE)是一种多功能生物聚合物,具有许多有价值的特性,特别是在食品包装(FPack)的背景下。它的生物可降解性、生物相容性和形成多孔结构的能力使其成为各种应用的理想材料。本文综述了电纺ge基纳米纤维(EGFs)在FPack中的应用及其最新进展。大多数egf被确定为可生物降解和生物相容性,具有形成具有突出特性的高多孔结构的能力,使其适用于包括FPack在内的广泛应用。然而,原生GE有其局限性,比如对水分的敏感性,这可能会限制其在某些应用中的使用。为了解决这些限制,研究人员正在探索增强ge基材料性能的方法。egf是由多种天然和合成成分制成的,以提高其物理、机械、弹性、耐水性、蒸汽阻隔性、紫外线阻隔性和热稳定性。此外,EGFs具有抗菌和抗氧化特性,有助于延长许多食品的保质期。还讨论了FPack中egf的潜在用途、挑战和局限性。总体而言,egf有望成为一种可持续和有效的包装材料,但需要进一步的研究来优化其性能并确保其在FPack中使用的安全性。
{"title":"Gelatin-based electrospun nanofibers in food packaging: Overcoming obstacles and looking forward to the future","authors":"Ali Khoshkalampour ,&nbsp;Behnam Bahramian ,&nbsp;Reza Abedi-Firoozjah ,&nbsp;Milad Tavassoli ,&nbsp;Shaghayegh Ahmadi ,&nbsp;Amir Hossein Nasri ,&nbsp;Sepidar Seyyedi-Mansour ,&nbsp;Swarup Roy ,&nbsp;Seid Mahdi Jafari","doi":"10.1016/j.cis.2025.103742","DOIUrl":"10.1016/j.cis.2025.103742","url":null,"abstract":"<div><div>Gelatin (GE) is a versatile biopolymer with many valuable properties, particularly in the context of food packaging (F<sub>Pack</sub>). Its biodegradability, biocompatibility, and ability to form porous structures make it ideal for various applications. This review examines the applications of electrospun GE-based nanofibers (EGFs) and their recent advances in F<sub>Pack</sub>. The majority of EGFs are determined to be biodegradable and biocompatible, with the ability to form a highly porous structure with outstanding characteristics, making them appropriate for a broad range of applications, including F<sub>Pack</sub>. However, native GE has limitations, such as sensitivity to moisture, which can restrict its use in certain applications. To address these limitations, researchers are exploring ways to enhance the properties of GE-based materials. EGFs are produced with a variety of natural and synthetic ingredients to increase their physical, mechanical, elastic, water resistance, vapor barrier, UV-blocking, and thermal stability properties. Furthermore, EGFs have antimicrobial and antioxidant properties that help to extend the shelf life of many food products. The prospective uses, challenges, and limitations of EGFs in F<sub>Pack</sub> are also addressed. Overall, EGFs show promise as a sustainable and effective packaging material, but further research is needed to optimize their properties and ensure their safety for use in F<sub>Pack</sub>.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"348 ","pages":"Article 103742"},"PeriodicalIF":19.3,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145746205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phospholipid composition changes in bacterial membranes: A molecular mechanism of antibiotic resistance 细菌膜磷脂组成的变化:抗生素耐药性的分子机制。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-01 DOI: 10.1016/j.cis.2025.103738
Aleksandra Godlewska, Katarzyna Pawlak, Dominik Jańczewski
The bacterial cell membrane is a structurally essential and relatively accessible target for several antimicrobial agents, including daptomycin, polymyxins, antimicrobial peptides, and polymers. These compounds are often effective against multidrug-resistant bacteria and are considered last resort treatments. While initially considered less prone to resistance development, accumulating evidence shows that bacteria can adapt through various mechanisms – often involving alterations in membrane composition and biophysical properties. Reported resistance mechanisms include changes in phospholipid composition, lipid A structure, membrane fluidity, surface charge, and microdomain organization. Advances in analytical methodologies – including liquid and gas chromatography, capillary electrophoresis, mass spectrometry, and fluorescence-based techniques—have enabled increasingly precise characterization of these adaptations. In this review, we outline membrane remodeling strategies associated with resistance in both Gram-positive and Gram-negative bacteria and provide an overview of analytical methods commonly employed to study these changes. These insights highlight the growing relevance of membrane-level adaptations in antimicrobial resistance and underscore the need for further research using modern lipidomic and biophysical tools.
细菌细胞膜是一些抗菌剂的结构必需和相对容易获得的靶点,包括达托霉素、多粘菌素、抗菌肽和聚合物。这些化合物通常对耐多药细菌有效,被认为是最后的治疗手段。虽然最初被认为不太容易产生耐药性,但越来越多的证据表明,细菌可以通过各种机制适应——通常涉及改变膜的组成和生物物理特性。已报道的抗性机制包括磷脂组成、脂质A结构、膜流动性、表面电荷和微域组织的变化。分析方法的进步——包括液相和气相色谱、毛细管电泳、质谱分析和基于荧光的技术——使得对这些适应性的描述越来越精确。在这篇综述中,我们概述了与革兰氏阳性和革兰氏阴性细菌耐药相关的膜重塑策略,并概述了研究这些变化的常用分析方法。这些见解强调了膜水平适应在抗菌素耐药性中的日益增长的相关性,并强调了使用现代脂质组学和生物物理工具进行进一步研究的必要性。
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引用次数: 0
Interfacial engineering of superlattice coatings: Structural modulation, mechanical properties, and adaptation to high-temperature environments 超晶格涂层的界面工程:结构调制、力学性能和对高温环境的适应
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-11-19 DOI: 10.1016/j.cis.2025.103719
Shani Yang , Tao Guo , Xueyan Yan , Wenxin Ti , Fangjie Shi , Zhentan Zhang , Yuteng Zhang , Kewei Gao , Xiaolu Pang
Superlattice coatings consist of alternating nanoscale layers of metals, ceramics, or intermetallics. They have emerged as promising protective materials for extreme environments in advanced manufacturing, aerospace, and nuclear systems. Their periodic architectures offer synergistic enhancements in hardness, toughness, and thermal stability, surpassing conventional monolithic coatings. At the core of these properties lies interface engineering, which governs interlayer bonding, stress distribution, microstructural evolution, and high-temperature degradation. This review critically examines interface-dominated mechanisms underlying structural formation, growth dynamics, mechanical behavior, and environmental stability. Emphasis is placed on interfacial parameters such as lattice mismatch, interfacial energy, and atomic diffusion. These parameters play key roles in texture development, phase boundary design, and oxidation resistance. Despite recent advances, several challenges persist, including incomplete structure-property correlations, the lack of unified models linking processing to interface architecture, and limited integration with emerging functionalities. Future efforts should prioritize multiscale design platforms combining advanced characterization, modeling, and data-driven strategies to achieve precise interface control and multifunctionality in next-generation coatings.
超晶格涂层由交替的纳米级金属、陶瓷或金属间化合物层组成。它们已成为先进制造业、航空航天和核系统中极端环境的有前途的保护材料。它们的周期性结构提供了硬度、韧性和热稳定性的协同增强,超越了传统的单片涂层。这些性能的核心在于界面工程,它控制着层间键合、应力分布、微观结构演变和高温降解。本文对结构形成、生长动力学、机械行为和环境稳定性的界面主导机制进行了批判性的研究。重点放在界面参数,如晶格失配,界面能,和原子扩散。这些参数在织构发育、相边界设计和抗氧化性中起着关键作用。尽管最近取得了进展,但仍然存在一些挑战,包括不完整的结构-属性相关性,缺乏将处理与接口架构连接起来的统一模型,以及与新兴功能的有限集成。未来的工作应优先考虑结合先进表征、建模和数据驱动策略的多尺度设计平台,以实现下一代涂料的精确界面控制和多功能。
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引用次数: 0
Electrospun nanofibers for the adsorption and separation of pollutants from wastewater: New opportunities and recent advances 静电纺纳米纤维对废水中污染物的吸附和分离:新机遇和最新进展。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-10 DOI: 10.1016/j.cis.2025.103749
Maryam Majlesi , Elham Assadpour , Milad Tavassoli , Seid Mahdi Jafari
Due to the high concentration of various toxic and hazardous pollutants, industrial wastewaters have posed increasing threats. Water reclamation has recently received attention by using one-dimensional nanostructured materials such as electrospun nanofibrous membranes (ENMs). ENMs exhibit numerous advantageous properties, including a high surface area, substantial porosity, robust mechanical strength, and the ability to control surface morpHology. ENMs are promising candidates for efficient and environmentally sustainable water purification solutions. This review examines the recent advances in the use of ENMs for the treatment of contaminated water, in which the types of nanofibers that can be used to remove pollutants present in industrial wastewater (WW) are separately described. We aim to provide a comprehensive understanding of the topic and encourage stakeholders and researchers to use ENMs in industrial WW treatment, which will help create a reliable water source for future generations.
由于工业废水中各种有毒有害污染物的高浓度,对环境的威胁越来越大。利用电纺纳米纤维膜等一维纳米结构材料进行水回收是近年来研究的热点。enm具有许多优点,包括高表面积、高孔隙率、强大的机械强度和控制表面形貌的能力。enm是高效和环境可持续的水净化解决方案的有希望的候选者。本文综述了纳米纤维用于污水处理的最新进展,其中分别描述了可用于去除工业废水中污染物的纳米纤维的类型。我们的目标是提供对该主题的全面理解,并鼓励利益相关者和研究人员在工业废水处理中使用enm,这将有助于为子孙后代创造可靠的水源。
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引用次数: 0
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